1-(4-hydroxy-phenyl)-4-[1-(4-hydroxy-phenyl)-1-methyl-ethyl]-1-methyl-cyclohexane | 1965-08-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-hydroxy-phenyl)-4-[1-(4-hydroxy-phenyl)-1-methyl-ethyl]-1-methyl-cyclohexane
• 英文别名: 1-(4-Hydroxy-phenyl)-4-[1-(4-hydroxy-phenyl)-1-methyl-aethyl]-1-methyl-cyclohexan；1.8-Bis-(4-hydroxy-phenyl)-p-menthan；4-{2-[4-(4-Hydroxyphenyl)-4-methylcyclohexyl]propan-2-yl}phenol；4-[4-[2-(4-hydroxyphenyl)propan-2-yl]-1-methylcyclohexyl]phenol
• CAS: 1965-08-8
• 化学式: C₂₂H₂₈O₂
• 分子量: 324.463
• InChiKey: SPWZOJAIQZNNDX-UHFFFAOYSA-N

物化性质

• 熔点：
  89-90 °C(Solv: benzene (71-43-2))
• 沸点：
  481.7±28.0 °C(Predicted)
• 密度：
  1.088±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(4-hydroxy-phenyl)-4-[1-(4-hydroxy-phenyl)-1-methyl-ethyl]-1-methyl-cyclohexane 、 乙酸酐 在 sodium acetate 作用下， 生成 1-(4-acetoxy-phenyl)-4-[1-(4-acetoxy-phenyl)-1-methyl-ethyl]-1-methyl-cyclohexane
  参考文献：
  名称：

  Zinke; Hoenel, Journal fur praktische Chemie (Leipzig 1954), 1940, vol. <2> 156, p. 97,101

  摘要：

  DOI：
• 作为产物：
  描述：

  苯酚 、 alkaline earth salt of/the/ methylsulfuric acid 在 fired clay 作用下， 生成 1-(4-hydroxy-phenyl)-4-[1-(4-hydroxy-phenyl)-1-methyl-ethyl]-1-methyl-cyclohexane
  参考文献：
  名称：

  Wakabayashi; Matsubara, Nippon Kagaku Zasshi, 1959, vol. 80, p. 1179

  摘要：

  DOI：

文献信息

• Optically active compound and photosensitive resin composition
  申请人：——

  公开号：US20030211421A1

  公开（公告）日：2003-11-13

  A photoactive compound is used in combination with a photosensitizer, represented by the following formula (1): A −[( J ) m −( X-Pro )] n (1) wherein A represents a hydrophobic unit comprising at least one kind of hydrophobic groups selected from a hydrocarbon group and a heterocyclic group, J represents a connecting group, X-Pro represents a hydrophilic group protected by a protective group Pro which is removable by light exposure, m represents 0 or 1, and n represents an integer of not less than 1. The protective group Pro may be removable by light exposure in association with the photosensitizer (especially, a photo acid generator), or may be a hydrophobic protective group. The hydrophilic group may be a hydroxyl group or a carboxyl group. The photoactive compound has high sensitivity to a light source of short wavelength beams, for resist application, therefore, the photoactive compound is advantageously used for forming a pattern with high resolution.

  一种光活性化合物与光敏剂结合使用，由以下公式（1）表示： A −[( J ) m −( X-Pro )] n (1) 其中，A代表至少包括一种从烃基和杂环基中选择的疏水基的疏水单元，J代表连接基团，X-Pro代表由光照可去除的保护基团Pro保护的亲水基团，m代表0或1，n代表不少于1的整数。 保护基团Pro可以与光敏剂（特别是光酸发生剂）一起通过光照可去除，也可以是疏水保护基团。亲水基团可以是羟基或羧基。光活性化合物对短波长光源具有很高的敏感性，用于光刻应用，因此，该光活性化合物有利于形成具有高分辨率的图案。
• Method for depolymerizing aromatic polycarbonate
  申请人：——

  公开号：US20040054238A1

  公开（公告）日：2004-03-18

  An aromatic polycarbonate depolymerization method comprising reacting an aromatic polycarbonate with water, an aliphatic alcohol having 1 to 6 carbon atoms or a phenol which may be substituted by a hydrocarbon group having 1 to 10 carbon atoms in the critical fluid of carbon dioxide or with the critical fluid of an aliphatic alcohol having 1 to 6 carbon atoms or a phenol which may be substituted by a hydrocarbon group having 1 to 10 carbon atoms. With this depolymerization method, the aromatic polycarbonate is depolymerized at a high reaction rate and effective components formed by depolyemrization can be recovered at a high rate. Therefore, the effective components are recovered from the scrapped or used aromatic polycarbonate by this method and recycled.

  一种芳香族聚碳酸酯解聚方法，包括在二氧化碳的临界流体中，将芳香族聚碳酸酯与水、具有1至6个碳原子的脂肪醇或可由具有1至10个碳原子的烃基取代的酚，或与具有1至6个碳原子的脂肪醇或可由具有1至10个碳原子的烃基取代的酚的临界流体反应。使用该解聚方法，芳香族聚碳酸酯可以高速解聚，解聚后的有效组分可以高效地回收。因此，通过该方法可以从废弃或使用过的芳香族聚碳酸酯中回收有效组分并进行再循环利用。
• POLYCARBONATE-BASE POLYMER, PRODUCTION PROCESS, RESIN COATING FLUID PREPARED THEREFROM, AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0837085A1

  公开（公告）日：1998-04-22

  A polymer comprising mainly repeating units (1) and/or repeating units (2), containing optionally terminal groups (3) and/or repeating units (4), and having a reduced viscosity [ηsp/c] of 0.2 to 10.0 dl/g as measured in a 0.5 g/dl solution thereof in methylene chloride at 20°C; a resin coating fluid containing the polymer, a charge-transfer substance and a solvent; and an electrophotographic photoreceptor containing the polymer as a binder resin in a photosensitive layer, wherein Rf1 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to the two oxygen atoms of the carbonate linkage in the general formula (1) without any intervening arylene group; and Rf2 represents a group that is composed of at least carbon atoms and fluorine atoms and bonded directly to one of the oxygen atoms of the carbonate linkage in the general formula (3) without any intervening arylene group.

  一种主要由重复单元（1）和/或重复单元（2）组成的聚合物，含有任选的末端基团（3）和/或重复单元（4），在 0.其中 Rf1 代表至少由碳原子和氟原子组成并直接与通式（1）中碳酸酯连接的两个氧原子键合的基团，而没有任何芳基介入；Rf2 代表一个至少由碳原子和氟原子组成的基团，直接与通式（3）中碳酸酯链节的一个氧原子键合，中间不含任何芳烯基。
• POLYCARBONATE, AND MOLDING AND ELECTROPHOTOGRAPHIC PHOTORECEPTOR PREPARED THEREFROM
  申请人：IDEMITSU KOSAN COMPANY LIMITED

  公开号：EP0896975A1

  公开（公告）日：1999-02-17

  A polycarbonate containing repeating units (1) represented by the general formula (1), a polycarbonate molding produced by molding the polycarbonate, and an electrophotographic photoreceptor having a photosensitive layer which has a surface layer containing the polycarbonate: wherein R is an aliphatic unsaturation-free monovalent hydrocarbon group, R1 is a halogen atom, an alkyl group, an alkoxy group or an aryl group, X is an alkylene group or an alkyleneoxyalkylene group, X' is an alkylene group of 2 or more carbon atoms, an alkyleneoxyalkylene group or oxygen atom, a is an integer of 0 to 4, na is 0 or 1, nb is 1 or 2, nc is 1 or 2, provided na+nb+nc=3, n1, n2, n3 and n4 are 0 or an integer of 1 or more, provided n1+n2+n3+n4 is an integer of 0 to 450.

  一种含有由通式(1)表示的重复单元(1)的聚碳酸酯，一种通过模塑该聚碳酸酯而制得的聚碳酸酯模塑件，以及一种具有感光层的电子照相感光器，该感光器具有含有该聚碳酸酯的表层： 其中 R 是脂肪族无饱和度单价烃基，R1 是卤素原子、烷基、烷氧基或芳基，X 是亚烷基或亚烷氧基烷基，X'是 2 个或 2 个以上碳原子的亚烷基、a 是 0 至 4 的整数，na 是 0 或 1，nb 是 1 或 2，nc 是 1 或 2，条件是 na+nb+nc=3，n1、n2、n3 和 n4 是 0 或 1 或 1 以上的整数，条件是 n1+n2+n3+n4 是 0 至 450 的整数。
• PROCESSES FOR PRODUCING RAW POLYCARBONATE RESIN MATERIAL AND PRODUCING POLYCARBONATE RESIN
  申请人：IDEMITSU PETROCHEMICAL CO., LTD.

  公开号：EP1178068A1

  公开（公告）日：2002-02-06

  The invention relates to an inexpensive and simple method for producing a starting material for polycarbonate resin and for producing polycarbonate resin. In the method for producing a starting material for polycarbonate resin production through interfacial polymerization, (I) a molten bisphenol compound is mixed and dissolved in an aqueous alkali solution at 20 to 80°C, or (II) it is, without being solidified, directly mixed with water to be in liquid at a temperature not higher than the melting point of the bisphenol compound, and then dissolved in an aqueous alkali solution.

  本发明涉及一种生产聚碳酸酯树脂起始材料和生产聚碳酸酯树脂的廉价而简单的方法。在通过界面聚合生产聚碳酸酯树脂起始原料的方法中，(I) 将熔融双酚化合物混合并溶解在 20 至 80°C 的碱水溶液中，或 (II) 在不高于双酚化合物熔点的温度下将其与水直接混合成液态，然后溶解在碱水溶液中。