2-[1-(2-tert-butylphenylimino)ethyl]-6-acetylpyridine | 395656-39-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[1-(2-tert-butylphenylimino)ethyl]-6-acetylpyridine
• 英文别名: 2-[1-(2-t-butylphenylimino)ethyl]-6-acetylpyridine
• CAS: 395656-39-0
• 化学式: C₁₉H₂₂N₂O
• 分子量: 294.396
• InChiKey: SABYQVCUNYPPQD-DEDYPNTBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.72
• 重原子数：
  22.0
• 可旋转键数：
  3.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  42.32
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  4-eicosanoxy-3,5-diphenylaniline 、 2-[1-(2-tert-butylphenylimino)ethyl]-6-acetylpyridine 以 甲苯 为溶剂， 反应 24.0h， 以44%的产率得到2-[1-(2-tert-butylphenylimino)ethyl]-6-[1-(4-eicosanoxy-3,5-diphenylphenylimino)ethyl]pyridine
  参考文献：
  名称：

  Process for preparring linear alpha olefins

  摘要：

  一种从具有n个碳原子的线性α-烯烃制备具有2n个碳原子的线性α-烯烃的方法，包括以下步骤：(a)在线性α-烯烃存在下通过二聚化催化剂使具有n个碳原子的线性α-烯烃二聚化，产生具有2n个碳原子的线性内部烯烃；(b)(i)在异构化/置换催化剂存在下，将步骤(a)产生的具有2n个碳原子的线性内部烯烃与三烷基铝化合物反应，以引起线性内部烯烃的异构化并将烷基从所述三烷基铝化合物中置换出来，形成一种烷基铝化合物，其中至少一个结合到铝的烷基是从所述线性内部烯烃的异构化中衍生出的线性烷基；(b)(ii)将所述烷基铝化合物与α-烯烃反应，可选地在置换催化剂存在下，以将所述线性烷基从所述烷基铝化合物中置换出来，形成具有2n个碳原子的线性α-烯烃。

  公开号：

  US20060014989A1

文献信息

• [EN] TRANSITION METAL COMPLEXES<br/>[FR] TRANSITION METAL COMPLEXES
  申请人：SHELL INT RESEARCH

  公开号：WO2005090371A1

  公开（公告）日：2005-09-29

  A transition metal complex which is a bis-arylimine pyridine MXn complex, comprising a bis-arylimine pyridine ligand having the formula (I), wherein R1-R5, R7-R9, R12 and R14 are each, independently, hydrogen, optionally substituted hydrocarbyl, an inert functional group, or any two of R1-R3 and R7-R9 vicinal to one another taken together may form a ring, and R6 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R7 or R4 to form a ring, R10 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R9 or R4 to form a ring, R11 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R12 or R5 to form a ring, R15 is hydrogen, optionally substituted hydrocarbyl, an inert functional group, or taken together with R14 or R5 to form a ring, provided that R13 and at least one of R12 and R14 are independently selected from optionally substituted C1-C30 alkyl, optionally substituted C4-C30 alkyloxy, halogen and optionally substituted C5-C20 aryl, or R13 taken together with R12 or R14 form a ring, or R12 taken together with R11 form a ring and R14 taken together with R15 form a ring, and provided that at least one of R12, R13 and R14 is optionally substituted C4-C30 alkyloxy; M is a transition metal atom in particular selected from Ti, V, Cr, Mn, Fe, Co, Ni, Pd, Rh, Ru, Mo, Nb, Zr, Hf, Ta, W, Re, Os, Ir or Pt; n matches the formal oxidation state of the transition metal atom M; and X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-­polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co­)oligomerization, polymerization and dimerization reactions.

  一种过渡金属配合物，为双芳胺吡啶MXn配合物，包括具有化学式(I)的双芳胺吡啶配体，其中R1-R5、R7-R9、R12和R14分别为独立的氢、可选择取代的烃基、惰性官能团，或R1-R3和R7-R9中的任意两个邻位取代基可以形成环，R6为氢、可选择取代的烃基、惰性官能团，或与R7或R4一起形成环，R10为氢、可选择取代的烃基、惰性官能团，或与R9或R4一起形成环，R11为氢、可选择取代的烃基、惰性官能团，或与R12或R5一起形成环，R15为氢、可选择取代的烃基、惰性官能团，或与R14或R5一起形成环，其中R13和至少一个R12和R14独立地选自可选择取代的C1-C30烷基、可选择取代的C4-C30烷氧基、卤素和可选择取代的C5-C20芳基，或R13与R12或R14一起形成环，或R12与R11一起形成环，R14与R15一起形成环，且至少一个R12、R13和R14为可选择取代的C4-C30烷氧基；M为过渡金属原子，特别选自Ti、V、Cr、Mn、Fe、Co、Ni、Pd、Rh、Ru、Mo、Nb、Zr、Hf、Ta、W、Re、Os、Ir或Pt；n与过渡金属原子M的形式氧化态相匹配；X为卤素、可选择取代的烃基、烷氧基、酰胺或氢化物。本发明的过渡金属配合物及其与非配位阴离子的复合物和含有此类配合物的催化系统在非极性介质和化学惰性非极性溶剂中具有良好的溶解性，特别是芳香烃类溶剂。该催化系统可用于广泛的(共)寡聚化、聚合和二聚化反应。
• Process for the co-oligomerisation of ethylene and alpha olefins
  申请人：——

  公开号：US20020128409A1

  公开（公告）日：2002-09-12

  A process for production of higher linear alpha olefins and/or alkyl-branched alpha olefins, which comprises the co-oligomerisation of one or more alpha olefins with ethylene in the presence of a metal catalyst system employing one or more bis-aryliminepyridine MX a complexes and/or one or more [bis-aryliminepyridine MY p .L b + ][NC − ] q complexes; and said process is carried out at an ethylene pressure of less than 2.5 MPa.

  一种生产较高线性α烯烃和/或烷基支链α烯烃的方法，包括在一种金属催化剂体系的存在下，通过将一种或多种α烯烃与乙烯共聚合，采用一种或多种双芳基亚胺吡啶MXa络合物和/或一种或多种[双芳基亚胺吡啶MYp.Lb+][NC−]q络合物，且该过程在乙烯压力小于2.5 MPa下进行。
• Transition metal complexes
  申请人：De Boer Maria Eric Johannes

  公开号：US20050215792A1

  公开（公告）日：2005-09-29

  A transition metal complex which is a bis-arylimine pyridine MX n complex or a [bis-arylimine pyridine MX p + ][NC − ] q complex comprising a bis-arylimine pyridine ligand and M is a transition metal atom; n matches the formal oxidation state of the transition metal atom M; X is halide, optionally substituted hydrocarbyl, alkoxide, amide, or hydride; NC− is a non-coordinating anion; and p+q matches the formal oxidation state of the transition metal atom M. The transition metal complexes of the present invention, their complexes with non-coordinating anions and catalyst systems containing such complexes have good solubility in non-polar media and chemically inert non-polar solvents especially aromatic hydrocarbon solvents. The catalyst systems can be used for a wide range of (co-)oligomerization, polymerization and dimerization reactions.

  这是一种过渡金属配合物，其为双芳基亚胺吡啶MXn配合物或[bis-芳基亚胺吡啶MXp+][NC−]q配合物，包括一个双芳基亚胺吡啶配体和M为一种过渡金属原子；n匹配过渡金属原子M的形式氧化态；X为卤素，可选取代的烃基，醇酸盐，酰胺或氢化物；NC−为非配位阴离子；p+q匹配过渡金属原子M的形式氧化态。本发明的过渡金属配合物及其与非配位阴离子的配合物和含有这种配合物的催化体系在非极性介质和化学惰性的非极性溶剂，尤其是芳香烃溶剂中具有良好的溶解性。该催化体系可用于广泛的(共)寡聚、聚合和二聚反应。
• Bis-imine pyridine complex of lanthanides catalytic system comprising said bis-imine pyridine complex and process for the (co)polymerization of conjugated dienes
  申请人：Versalis S.P.A.

  公开号：US10766979B2

  公开（公告）日：2020-09-08

  A bis-imine pyridine complex of lanthanides having general formula (I): Said bis-imine pyridine complex of lanthanides having general formula (I) can be advantageously used in a catalytic system for the (co)polymerization of conjugated dienes.

  具有通式 (I) 的镧系元素双亚胺吡啶络合物： 具有通式 (I) 的镧系元素双亚胺吡啶络合物可用于共轭二烯（共）聚合的催化系统中。
• PROCESS FOR THE CO-OLIGOMERISATION OF ETHYLENE AND ALPHA OLEFINS
  申请人：SHELL INTERNATIONALE RESEARCHMAATSCHAPPIJ B.V.

  公开号：EP1322576A2

  公开（公告）日：2003-07-02