o,o'-Dimethoxy-diazoaminobenzol | 33227-84-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: o,o'-Dimethoxy-diazoaminobenzol
• 英文别名: 2-methoxy-N-[(2-methoxyphenyl)diazenyl]aniline
• CAS: 33227-84-8
• 化学式: C₁₄H₁₅N₃O₂
• 分子量: 257.292
• InChiKey: PUHMFUUKPGNMJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  55.2
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  o,o'-Dimethoxy-diazoaminobenzol 、 mercury(II) thiocyanate 以 甲醇 为溶剂， 以53%的产率得到[Hg(II)([1,3-di(2-methoxy)benzene]triazene(1-))SCN]
  参考文献：
  名称：

  Syntheses, structures, thermal behavior and solution studies of two types of Hg(II) complexes with [1,3-di(2-methoxy)benzene]triazene

  摘要：

  The reaction of [1,3-di(2-methoxy)benzene]triazene, [HL], with Hg(CH3COO)(2) and Hg(SCN)(2) in methanol as solvent, resulted in the formation of [HgL2] (1) and [HgL(SCN)] (2), respectively. These compounds were characterized by means of X-ray diffraction, FT-IR spectroscopy, CHN and TGA-DTA analysis. In the lattice of the compound 1, the mono-nuclear complexes were connected to dimer structure by intermolecular non-classical C-H center dot center dot center dot O hydrogen bonds. Also, weak Hg-eta(2)-arene p-interactions link the dimers into 1D supramolecular chains. The compound 2 is a 2D coordination polymer induced by C-H center dot center dot center dot pi stacking interactions between 1D chains produced by weak Hg-eta(3)-eta(3)-arene pi-interactions. The results of studies of the stoichiometry and formation of complexes of 1 and 2 in methanol solution were found to be in support of their solid state stoichiometry. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.04.041
• 作为产物：
  描述：

  邻甲氧基苯胺 在 盐酸 、 sodium nitrite 作用下， 以 水 为溶剂， 反应 1.0h， 以72%的产率得到o,o'-Dimethoxy-diazoaminobenzol
  参考文献：
  名称：

  1,3-二芳基三氮烯：一类新型的厌食药。

  摘要：

  已经合成了一系列取代的1，3-二芳基三氮烯并测试了其厌食活性。该系列的几名成员有效。一种化合物1,3-双[2-氰基-5-（三氟甲基）苯基]三嗪特别活泼，可导致大鼠，狗和松鼠的体重减轻。它没有明显的中枢神经系统活动，并且与以前报道的具有生物活性的三氮烯相比，在给药30天内相对无毒。

  DOI：

  10.1021/jm00360a015

文献信息

• Triazenides as Suitable Ligands in the Synthesis of Palladium Compounds in Three Different Oxidation States: I, II, and III
  作者：Susana Ibañez、Larisa Oresmaa、Francisco Estevan、Pipsa Hirva、Mercedes Sanaú、M Angeles Úbeda

  DOI：10.1021/om500702j

  日期：2014.10.13

  orthometalated dinuclear triazenide palladium(II) compounds of the general formula Pd2[(C6H4)PPh2]2[R–N–N–N–R]2 (R = C6H5, 3a; o-BrC6H4, o-3b; o-MeOC6H4, o-3c; o-MeC6H4, o-3d ; p-BrC6H4, p-3b; p-MeOC6H4, p-3c; p-MeC6H4, p-3d) have been synthesized and structurally characterized. The characteristics of these compounds were compared with the isoelectronic formamidinate derivatives. These triazenide compounds have

  新邻位的双核triazenide钯（II）的通式的化合物的Pd 2 [（C 6 H ^ 4）PPH 2 ] 2 [R-N-N-N-R] 2（R = C 6 H ^ 5，图3a ; ø - BRC 6 ħ 4，ö -图3b ; ø -MeOC 6 ħ 4，ö - 3C ; ø -MeC 6 ħ 4，ö - 3D ; p -BrC6 ħ 4，p -图3b ; p -MeOC 6 ħ 4，p - 3C ; p -MeC 6 ħ 4，p - 3D）已被合成和结构表征。这些化合物的特征与等电子甲脒衍生物进行了比较。这些triazenide化合物已成为合适的起始产品中的新不那么常见的双核钯（I）的化合物和新的不寻常的钯（III）的人的合成。在过量的配位体triazenide的存在，化合物ö -图3b和ø -图3c进行了缩小处理得到的双核钯（I）的化合物，钯2 [R-N-N-N-R] 2（R = ö -BrC
• Structural and solution studies of a novel tetranuclear silver(I) cluster of [1,3-di(2-methoxy)benzene]triazene
  作者：Mahmood Payehghadr、Mohammad Kazem Rofouei、Ali Morsali、Mojtaba Shamsipur

  DOI：10.1016/j.ica.2006.09.015

  日期：2007.4

  The synthesis, characterization, crystal structure, H-1 NMR, spectrophotometric and conductometric studies of a new tetranuclear silver(l) complex of [1,3-di(2-methoxy)benzene]triazene are reported. Reaction of the ligand with silver acetate resulted in the formation of a tetranuclear cluster with a four-member Ag-Ag ring core, composed of four triazenide ligands and four metals. The results of studies of the stoichiometry and formation and of complex in tetrahydrofuran solution were found to be in support of its solid state structure. (C) 2006 Elsevier B.V. All rights reserved.
• 66. The azo-group as a chelating group. Part II. The structure of the diazoamino-compounds
  作者：Louis Hunter

  DOI：10.1039/jr9370000320

  日期：——
• Synthesis, characterization and electrocatalytic properties of a tetranuclear triazenido-copper(I) complex
  作者：Dan Xue、Su-Ping Luo、Yu-Ying Chen、Ze-Xin Zhang、Shu-Zhong Zhan

  DOI：10.1016/j.poly.2017.04.035

  日期：2017.8

  A new molecular catalyst based on a tetra-nuclear copper(I), [Cu-4(I)(L)(4)]1 is prepared by the reaction of the triazenido ligand, [1,3-bis(2-methoxy)benzene]triazene (HL) with CuCI. X-ray structural studies show that four copper atoms are triazenido-bridged with four independent Cu center dot center dot center dot Cu distances of 2.5881(7)-2.6048 (7) angstrom. Complex 1 can act as an electrocatalyst for hydrogen generation with 170.66 mol of hydrogen per mole of catalyst per hour (mol h(-1)) from acetic acid at an overpotential (OP) of 991.6 mV and 1034.31 mol 11(-1) from a neutral aqueous buffer (pH 7.0) at an OP of 837.6 mV, respectively. To test that the triazenido ligand, HL, plays a role in the electrocatalytic system, electrocatalytic activities of HL, CuCI and 1 are each investigated, and a possible catalytic mechanism for hydrogen generation catalyzed by 1 is provided. (C) 2017 Elsevier Ltd. All rights reserved.
• Binuclear Palladium(I) and Palladium(II) Complexes of <i>ortho</i>-Functionalized 1,3-Bis(aryl)triazenido Ligands
  作者：Juan José Nuricumbo-Escobar、Carlos Campos-Alvarado、Gustavo Ríos-Moreno、David Morales-Morales、Patrick J. Walsh、Miguel Parra-Hake

  DOI：10.1021/ic700516p

  日期：2007.7.1

  Three new bis(aryl)triazene ligands, Ar-NNNH-Ar' [Ar = o-C6H4-CO2Me, Ar' = p-C6H4-CH3 (2); Ar = Ar' = o-C6H4-CO2Me (3); Ar = o-C6H4-SMe, Ar' = p-C6H4-CH3) (4)], have been synthesized. The reaction of 1-4 with PdCl2(NCCH3)(2) in the presence of a base afforded a series of binuclear diamagnetic palladium complexes. In these reactions, ligands 1-3 afforded the palladium(I) complexes [Pd-I(o-MeO2C-C6H4-NNN-o-C6H4-CO2Me)](2) (5, monoclinic, space group P2(1)/c, a = 8.6070(10) angstrom, b = 14.3220(10) angstrom, c = 12.7310(10) angstrom, beta = 100.2950(10)degrees, Z = 2), [Pd-I(o-MeO-C6H4-NNN-o-C6H4-OMe)](2) (6, triclinic, space group P1, a = 6.6288(5) angstrom, b = 10.2631(10) angstrom, c = 11.0246(11) angstrom, alpha = 85.579(6)degrees, beta = 80.885(6)degrees, gamma = 74.607(6)degrees, Z = 1), and [Pd-I(o-MeO2C-C6H4-NNN-p-C6H4-CH3)](2) (7, tetragonal, space group I41/a, a = 20.866(3) angstrom, b = 20.866(3) angstrom, c = 13.156(2) angstrom, Z = 8). In contrast, the reaction of ligand 4 with PdCl2(NCCH3)(2) resulted in the formation of a palladium(II) dimer, [Pd-II(o-MeS-C6H4-NNN-p-C6H4-CH3)Cl](2) (8, orthorhombic, space group P2(1)2(1)2, a = 10.4058(5) angstrom, b = 16.2488(8) angstrom, c = 9.9500(5) angstrom, Z = 2).