3,3'-bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-diaminodiphenyl ether | 883747-51-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,3'-bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-diaminodiphenyl ether
• 英文别名: 1,1'-[Oxybis(4-amino-1,3-phenylene)]bis[2,2,2-trifluoro-1-(trifluoromethyl)ethanol]；2-[2-amino-5-[4-amino-3-(1,1,1,3,3,3-hexafluoro-2-hydroxypropan-2-yl)phenoxy]phenyl]-1,1,1,3,3,3-hexafluoropropan-2-ol
• CAS: 883747-51-1
• 化学式: C₁₈H₁₂F₁₂N₂O₃
• 分子量: 532.286
• InChiKey: JXKLVSGTIUALQH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  35
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  102
• 氢给体数：
  4
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  4,4'-二氨基二苯醚 、 六氟丙酮 在 六氟异丙醇 、 三氟乙酸 作用下， 反应 24.0h， 以88.7%的产率得到3,3'-bis(1-hydroxy-1-trifluoromethyl-2,2,2-trifluoroethyl)-4,4'-diaminodiphenyl ether
  参考文献：
  名称：

  含フッ素芳香族ジアミンの製造方法

  摘要：

  抑制芳香族二胺中的亚胺类副产物，提供一种高选择性和高收率地制备含氟芳香族二胺的方法，其中将六氟异丙醇基（-C（CF3）2OH）与芳香环中的芳香族二胺结合。通过在1,1,1,3,3,3-六氟-2-丙醇中使芳香族二胺和六氟丙酮反应，得到结合有六氟异丙醇基的含氟芳香族二胺的制备方法。芳香族二胺和含氟芳香族二胺可以是芳香族多环化合物或芳香族单环化合物。

  公开号：

  JP2019199459A

文献信息

• NOVEL FLUORINE-CONTAINING DICARBOXYLIC ACIDS AND THEIR NOVEL POLYMER COMPOUNDS
  申请人：Narizuka Satoru

  公开号：US20090030173A1

  公开（公告）日：2009-01-29

  Disclosed is a fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.

  本发明公开了一种含氟的二羧酸，其化学式表示为（1），其中n表示1-4的整数，两个羧基不相邻于芳环上。通过将含氟二羧酸与共聚单体（例如，二氨基二醇）反应，可以获得线性聚合物化合物。通过热环化，这种线性聚合物化合物可以转化为具有优异特性的另一种聚合物化合物。
• Fluorine-Containing Polymerizable Monomer and Polymer Compound Using Same
  申请人：Saegusa Hiroshi

  公开号：US20080234460A1

  公开（公告）日：2008-09-25

  Disclosed is a fluorine-containing polymerizable monomer represented by the formula [1] below. (In the formula, A represents a single bond, an oxygen atom, a sulfur atom, CO, CH 2 , SO, SO 2 , C(CH 3 ) 2 , NHCO, C(CF 3 ) 2 , a phenyl or an alicyclic ring; a and b independently represent an integer of 0-2; and 1≦a+b≦4.) Such a fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer exhibiting water repellency, oil repellency, low water absorbency, heat re-sistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index, low dielectric properties and the like. Consequently, the fluorine-containing polymeriz-able monomer can be applied to the field of advanced polymer materials.

  公开了一种含氟可聚合单体，其化学式如下所示[1]。（在公式中，A代表单键，氧原子，硫原子，CO，CH2，SO，SO2，C（CH3）2，NHCO，C（CF3）2，苯基或脂环烷基; a和b分别表示0-2的整数; 1≦a+b≦4。）这种含氟可聚合单体可以用作有效的可聚合单体，表现出耐水性，耐油性，低吸水性，耐热性，耐候性，耐腐蚀性，透明度，光敏性，低折射率，低介电性等特性。因此，这种含氟可聚合单体可以应用于先进聚合材料领域。
• Fluorine-Containing Dicarboxylic Acids and Their Novel Polymer Compounds
  申请人：NARIZUKA Satoru

  公开号：US20110282026A1

  公开（公告）日：2011-11-17

  A fluorine-containing dicarboxylic acid represented by formula (1), wherein n represents an integer of 1-4, and the two carboxylic groups are not adjacent to each other on the aromatic ring. It is possible to obtain a linear polymer compound by reacting the fluorine-containing dicarboxylic acid with a comonomer (e.g., diaminodiol). By thermal cyclization, this linear polymer compound can be converted into another polymer compound having superior characteristics.

  公式(1)表示的是含氟二羧酸，其中n代表1-4的整数，且两个羧基不相邻于芳香环上。通过将含氟二羧酸与共聚物（例如二氨基二醇）反应，可以得到线性聚合物化合物。通过热环化，这种线性聚合物化合物可以转化为具有卓越特性的另一种聚合物化合物。
• Fluorinated Dicarboxylic Acid Derivative and Polymer Obtained Therefrom
  申请人：Isono Yoshimi

  公开号：US20110301305A1

  公开（公告）日：2011-12-08

  According to the present invention, a polymer is obtained by polycondensation of a fluorinated dicarboxylic acid derivative of the general formula (M-1) or an acid anhydride of the fluorinated dicarboxylic acid with a polyfunctional compound having two to four reactive groups corresponding in reactivity to carbonyl moieties of the fluorinated dicarboxylic acid derivative or acid anhydride. [Chem. 134] AOCF 2 C-Q-CF 2 COA′  (M-1) In the above formula, Q represents a divalent organic group having a substituted or unsubstituted aromatic ring; and A and A′ each independently represent an organic group. This polymer exhibits a sufficiently low dielectric constant for use as a semiconductor protection film and has the capability of forming a film at a relatively low temperature of 250° C. or lower.

  根据本发明，通过将通式(M-1)的含氟二羧酸衍生物或含氟二羧酸酸酐与具有与含氟二羧酸衍生物或酸酐的羰基部分相对应的两到四个反应性基团的多官能化合物进行聚合缩合反应，可以得到一种聚合物。[Chem. 134]AOCF2C-Q-CF2COA′  (M-1)在上述公式中，Q代表具有取代或未取代芳香环的二价有机基团; A和A'各自独立地表示有机基团。该聚合物表现出足够低的介电常数，可用作半导体保护膜，并具有在相对较低的温度下（250℃或更低）形成膜的能力。
• FLUORINE-CONTAINING POLYMERIZABLE MONOMER AND POLYMER COMPOUND USING SAME
  申请人：CENTRAL GLASS COMPANY, LIMITED

  公开号：EP1783158A1

  公开（公告）日：2007-05-09

  The present invention relates to a fluorine-containing polymerizable monomer represented by the formula [1], wherein A represents a single bond, oxygen atom, sulfur atom, CO, CH2, SO, SO2, C(CH3)2, NHCO, C(CF3)2, phenyl, or aliphatic ring; each of "a" and "b" independently represents an integer of 0-2; and 1≤a+b≤4. This fluorine-containing polymerizable monomer can be used as an effective polymerizable monomer, which can exhibit water repellency, oil repellency, low water absorptive property, heat resistance, weather resistance, corrosion resistance, transparency, photosensitivity, low refractive index property, low dielectric property, etc., and can be used for advanced polymer material fields.

  本发明涉及一种由式[1]表示的含氟可聚合单体、 其中 A 代表单键、氧原子、硫原子、CO、CH2、SO、SO2、C(CH3)2、NHCO、C(CF3)2、苯基或脂肪族环；"a "和 "b "各自独立地代表 0-2 的整数；且 1≤a+b≤4。这种含氟可聚合单体可作为一种有效的可聚合单体，具有憎水性、憎油性、低吸水性、耐热性、耐候性、耐腐蚀性、透明性、光敏性、低折射率特性、低介电特性等，可用于先进的高分子材料领域。