N,N'-di(3,5-dimethylphenyl)benzene-1,2-diamine | 1068437-89-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-di(3,5-dimethylphenyl)benzene-1,2-diamine
• 英文别名: N,N'-bis(3,5-dimethylphenyl)-o-phenylenediamine；1-N,2-N-bis(3,5-dimethylphenyl)benzene-1,2-diamine
• CAS: 1068437-89-7
• 化学式: C₂₂H₂₄N₂
• 分子量: 316.446
• InChiKey: WYGDOQRDFMFLTD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-氨基-3,5-二甲苯 、 邻二氯苯 在 bis(η3-allyl-μ-chloropalladium(II)) 、 potassium tert-butylate 、 1,3-双-(2,6-二异丙基苯基)咪唑鎓氯化物 作用下， 以 1,4-二氧六环 为溶剂， 反应 2.0h， 以98%的产率得到N,N'-di(3,5-dimethylphenyl)benzene-1,2-diamine
  参考文献：
  名称：

  An Efficient Palladium-Catalysed Amination of Aryl Chlorides in Presence of 1,3-bis-(2,6-Diisopropylphenyl)Imidazolinium Chloride

  摘要：

  1,3- 双（2,6-二异丙基苯基）氯化咪唑啉（SIPr-HCl）是一种 N-杂环碳烯的前体，研究人员将其作为 C-N 偶联反应中的原配体。结果发现，在温和的条件下，SIPr-HCl 与钯催化剂结合可有效地对芳基氯化物进行胺化反应。

  DOI：

  10.3184/030823410x12680525004303

文献信息

• Lubricating compositions containing ashless catalytic antioxidant additives
  申请人：Patil Abhimanyu O.

  公开号：US20080248985A1

  公开（公告）日：2008-10-09

  The invention comprises lubricating compositions and hydraulic fluids containing substituted N,N′-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids.

  本发明涉及一种润滑组合物和液压油，包含取代的N，N'-二芳基-邻苯二胺化合物，这些化合物在润滑剂和液压油中具有良好的氧化抑制水平。
• NOVEL TRIARYLAMINE POLYMER, PROCESS FOR PRODUCING THE SAME, AND USE THEREOF
  申请人：Tosoh Corporation

  公开号：EP1528074A1

  公开（公告）日：2005-05-04

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6 and Ar7 which are independent of one another, is an unsubstituted or substituted C6-60 aromatic group, Ar1 and Ar2 are the same or different, Ar3 and Ar4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided:

  本发明的目的是提供一种新型三芳基胺聚合物，该聚合物具有优异的溶解性和成膜性，并具有更好的热稳定性；提供一种简单的生产工艺；以及提供一种使用该聚合物的电子元件。 本发明提供了由下式（1）代表的三芳基胺聚合物（其中，Ar1、Ar2、Ar3、Ar4、Ar5、Ar6 和 Ar7 中的每一个彼此独立，是未取代或取代的 C6-60 芳族基团，Ar1 和 Ar2 相同或不同，Ar3 和 Ar4 相同或不同，且 m 是至少 1 的整数）、其生产工艺以及使用该聚合物的电子元件：
• Novel triarylamine polymer, process for its production and its use
  申请人：TOSOH CORPORATION

  公开号：EP2327739A1

  公开（公告）日：2011-06-01

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar1, Ar2, Ar3, Ar4, Ar5, Ar6 and Ar7 which are independent of one another, is an unsubstituted or substituted C6-60 aromatic group, Ar1 and Ar2 are the same or different, Ar3 and Ar4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided:

  本发明的目的是提供一种新型三芳基胺聚合物，该聚合物具有优异的溶解性和成膜性，并具有更好的热稳定性；提供一种简单的生产工艺；以及提供一种使用该聚合物的电子元件。 本发明提供了由下式（1）代表的三芳基胺聚合物（其中，Ar1、Ar2、Ar3、Ar4、Ar5、Ar6 和 Ar7 中的每一个彼此独立，是未取代或取代的 C6-60 芳族基团，Ar1 和 Ar2 相同或不同，Ar3 和 Ar4 相同或不同，且 m 是至少 1 的整数）、其生产工艺以及使用该聚合物的电子元件：
• LUBRICATING COMPOSITIONS CONTAINING ASHLESS CATALYTIC ANTIOXIDANT ADDITIVES
  申请人：ExxonMobil Research and Engineering Company

  公开号：EP2139977A2

  公开（公告）日：2010-01-06
• Novel triarylamine polymer, process for producing the same, and use thereof
  申请人：——

  公开号：US20040262574A1

  公开（公告）日：2004-12-30

  It is an object of the present invention to provide a novel triarylamine polymer which is excellent in solubility and film-forming property and has improved thermal stability; a simple process for its production; and an electronic element employing it. A triarylamine polymer represented by the following formula (1) (wherein each of Ar 1 , Ar 2 , Ar 3 , Ar 4 , Ar 5 , Ar 6 and Ar 7 which are independent of one another, is an unsubstituted or substituted C 6-60 aromatic group, Ar 1 and Ar 2 are the same or different, Ar 3 and Ar 4 are the same or different, and m is an integer of at least 1), a process for its production, and an electronic element employing it, are provided: 1