Phenyl-m-tolyl-(4-vinyl-phenyl)-amine | 220716-63-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Phenyl-m-tolyl-(4-vinyl-phenyl)-amine
• 英文别名: N-(4-ethenylphenyl)-3-methyl-N-phenylaniline
• CAS: 220716-63-2
• 化学式: C₂₁H₁₉N
• 分子量: 285.389
• InChiKey: LYIDUSRYEXBLRN-UHFFFAOYSA-N

物化性质

• 沸点：
  437.7±34.0 °C(Predicted)
• 密度：
  1.085±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1,4-二溴苯 在 1,1'-双(二苯基膦)二茂铁 、 四(三苯基膦)钯 、 tris(dibenzylideneacetone)dipalladium (0) 、 2,6-二叔丁基-4-甲基苯酚 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 生成 Phenyl-m-tolyl-(4-vinyl-phenyl)-amine
  参考文献：
  名称：

  Designing Interfaces That Function to Facilitate Charge Injection in Organic Light-Emitting Diodes

  摘要：

  Layer-by-layer (LbL) assembly of triarylamine (TAA)-containing polymers has been applied for anode functionalizations in organic light-emitting diodes (OLEDs). Surface work function of the ITO electrodes was significantly altered with the functionalizations, and the values changed depending on electron affinity of the substituents (X) on the TAA units. When the functionalized ITO electrodes were utilized for the conventional TPD/Alq OLED, the multilayers of P1 (X = 4-OMe) and P2 (X = none) were found to promote better energy matching at the ITO/TPD interface to reduce the hole injection barrier. Furthermore, the multilayers having heterodeposited structure of several TAA polymers provided stepped and graded electronic profiles to facilitate hole mobility from ITO to TPD, so that the resulting OLED devices can exhibit appreciably reduced turn-on voltage and higher luminous intensities.

  DOI：

  10.1021/ja052170n

文献信息

• Hole-transporting polymers
  申请人：——

  公开号：US20010017155A1

  公开（公告）日：2001-08-30

  Polymers comprising triarylamine substituent monomers. The polymers are products of anionic or radical polymerization of monovinylated triarylamine monomers or of ROMP polymerization of monomers comprising a triarylamine component, a linker component, and a cyclic olefin that is capable of undergoing a ring-opening polymerization reaction. The resulting polymers possess hole-transporting properties and are useful as hole transport layers in light-emitting diodes or as components of photorefractive materials.

  包含三芳胺取代单体的聚合物。这些聚合物是单乙烯化三芳胺单体的阴离子或自由基聚合或由包含三芳胺组分、连接组分和能够进行环开启聚合反应的环烯烃的ROMP聚合单体聚合而成。所得到的聚合物具有传输空穴的性质，可用作发光二极管中的空穴传输层或作为光折变材料的组分。
• Diarylamino group-containing copolymer, organic electroluminescent device, and method of producing hole transport layer for organic electroluminescent device
  申请人：Kato Shinji

  公开号：US20050008893A1

  公开（公告）日：2005-01-13

  An organic electroluminescent device is provided which has a high degree of adhesion between an anode and a hole transport layer, the device emitting light of high luminance even when driven by low applied voltages. Copolymers useful in hole transport layers in organic electroluminescent devices are also provided. Methods of producing hole transport layers for organic electroluminescent devices which can emit light of high luminance even when driven by low applied voltages are also provided, the hole transport layers having high degrees of adhesion with anode. A copolymer comprises a monomer unit including in its structure an electron-donating N,N-diaryl-substituted amino group such as an N,N-diphenylaminophenyl group, or a group having an N,N-diaryl-substituted amino moiety, and a monomer unit having at least one functional group. Also, a hole transport layer, which has excellent thickness accuracy, has an extremely smooth surface, and is very thin, can be formed of this copolymer or a copolymer having the same hole transport functional group. An organic electroluminescent device, which emits light of high luminance even when driven by low applied voltages, can be obtained by using this hole transport layer.

  提供了一种有机电致发光器件，其阳极和空穴传输层之间具有高度的粘附性，即使在低电压驱动下也能发出高亮度的光。还提供了在有机电致发光器件中用于空穴传输层的共聚物。还提供了制备空穴传输层的方法，该方法可以在低电压驱动下发出高亮度的光，空穴传输层与阳极具有高度的粘附性。共聚物包括一个单体单元，其结构中包括一个电子给体的N，N-二芳基取代氨基，例如N，N-二苯基氨基苯基基团，或具有N，N-二芳基取代氨基基团的基团，以及至少具有一个功能基团的单体单元。此共聚物或具有相同空穴传输功能基团的共聚物可以形成具有优异厚度精度、极其光滑表面且非常薄的空穴传输层。通过使用此空穴传输层，可以获得发出高亮度光的有机电致发光器件，即使在低电压驱动下也能发光。
• US7101630B2
  申请人：——

  公开号：US7101630B2

  公开（公告）日：2006-09-05
• Designing Interfaces That Function to Facilitate Charge Injection in Organic Light-Emitting Diodes
  作者：Shinji Kato

  DOI：10.1021/ja052170n

  日期：2005.8.24

  Layer-by-layer (LbL) assembly of triarylamine (TAA)-containing polymers has been applied for anode functionalizations in organic light-emitting diodes (OLEDs). Surface work function of the ITO electrodes was significantly altered with the functionalizations, and the values changed depending on electron affinity of the substituents (X) on the TAA units. When the functionalized ITO electrodes were utilized for the conventional TPD/Alq OLED, the multilayers of P1 (X = 4-OMe) and P2 (X = none) were found to promote better energy matching at the ITO/TPD interface to reduce the hole injection barrier. Furthermore, the multilayers having heterodeposited structure of several TAA polymers provided stepped and graded electronic profiles to facilitate hole mobility from ITO to TPD, so that the resulting OLED devices can exhibit appreciably reduced turn-on voltage and higher luminous intensities.