3-methylsulphinyl-5-chloro-1,2,4-thiadiazole | 173161-36-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 芳基卤化物
• 英文名称: 3-methylsulphinyl-5-chloro-1,2,4-thiadiazole
• 英文别名: 5-chloro-3-methylsulfinyl-1,2,4-thiadiazole
• CAS: 173161-36-9
• 化学式: C₃H₃ClN₂OS₂
• 分子量: 182.655
• InChiKey: INUGJGGMWGOGCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  9
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  90.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  硫代吗啉 、 3-methylsulphinyl-5-chloro-1,2,4-thiadiazole 、 5-氯-3-甲基磺酰基-1,2,4-噻二唑 以 氯仿 为溶剂， 反应 1.0h， 生成 3-methylsulfinyl-5-thiomorpholino-1,2,4-thiadiazole 、 3-methylsulfonyl-5-(thiomorpholino)-1,2,4-thiadiazole
  参考文献：
  名称：

  [EN] 1,2,4-THIADIAZOLE COMPOUNDS AND PESTS CONTROLLING COMPOSITION CONTAINING THE SAME
  [FR] COMPOSES 1,2,4-THIADIAZOLE ET COMPOSITION DE LUTTE ANTIPARASITAIRE CONTENANT CES COMPOSES

  摘要：

  公开号：

  WO2005037805A3
• 作为产物：
  描述：

  5-氯-3-(甲硫基)-1,2,4-噻二唑 、 硫酸 在 双氧水 作用下， 以 甲醇 为溶剂， 生成 3-methylsulphinyl-5-chloro-1,2,4-thiadiazole
  参考文献：
  名称：

  Alkyl sulphinyl and alkyl sulphonyl-1,2,4-thiadiazolyloxy acetamides and

  摘要：

  该发明涉及一种新型的配方（I）的烷基磺酰基和烷基磺基-1,2,4-噻二唑氧基乙酰胺，其中n为1或2，R.sup.1为氢或可能被取代的烷基、烯基、炔基或芳基烷基，R.sup.2为可能被取代的烷基、烯基、炔基、环烷基、环烯烷基、芳基烷基、芳基、烷氧基、烯氧基或炔氧基，或者R.sup.1和R.sup.2与它们连接的氮原子一起形成一个可能被取代的饱和或不饱和氮杂环，该环可能含有其他杂原子，并且可能与苯基相邻结合，R.sup.3为可能被取代的烷基、芳基或芳基烷基，以及用于生产该新型化合物的工艺和新型中间体产物，以及它们作为除草剂的用途。

  公开号：

  US05827800A1

文献信息

• 1,2,4-Thiadazole compounds and use thereof
  申请人：Hara Hideki

  公开号：US20070004722A1

  公开（公告）日：2007-01-04

  The present invention relates to a 1,2,4-thiadiazole compound of the formula (I) represented by the formula (1): wherein R 1? represents C3-C7 alkynyl and X represents C4-C7 straight alkylene optionally substituted with one to four of R 2?, C4-C7 straight alkenylene optionally substituted with one to four of R 2?, ethylene-oxy-ethylene optionally substituted with one to four of R 4?, or ethylene-thio-ethylene optionally substituted with one to four of R 4?, R 2? represents a halogen atom, trifluoromethyl or C1-C4 alkyl, and R4 represents a fluorine atom or C1-C3 alkyl. The 1,2,4-thiadiazole compound has an excellent pests controlling activity, and can effectively control an pests such as insect pests, acarine pests and the like.

  本发明涉及一种由式（1）表示的式（I）的1,2,4-噻二唑化合物，其中R1?代表C3-C7炔基，X代表C4-C7直链烷基，可选地用一到四个R2?，C4-C7直链烯基，可选地用一到四个R2?，乙二醇基乙二醇，可选地用一到四个R4?，或者乙硫基乙二醇，可选地用一到四个R4?取代，R2?代表卤素原子、三氟甲基或C1-C4烷基，R4代表氟原子或C1-C3烷基。该1,2,4-噻二唑化合物具有优异的害虫控制活性，可以有效地控制昆虫害虫、螨虫等害虫。
• 1,2,4-Thiadiazole compounds and pests controlling composition containing the same
  申请人：Sumitomo Chemical Company Limited

  公开号：US07371746B2

  公开（公告）日：2008-05-13

  The present invention relates to a 1,2,4-thiadiazole compound of the formula (I) represented by the formula (1): wherein R1? represents C3-C7 alkynyl and X represents C4-C7 straight alkylene optionally substituted with one to four of R2?, C4-C7 straight alkenylene optionally substituted with one to four of R2?, ethylene-oxy-ethylene optionally substituted with one to four of R4?, or ethylene-thio-ethylene optionally substituted with one to four of R4?, R2? represents a halogen atom, trifluoromethyl or C1-C4 alkyl, and R4 represents a fluorine atom or C1-C3 alkyl. The 1,2,4-thiadiazole compound has an excellent pests controlling activity, and can effectively control an pests such as insect pests, acarine pests and the like

  本发明涉及一种1,2,4-噻二唑化合物，其化学式（I）由式（1）表示：其中R1?表示C3-C7炔基，X表示C4-C7直链烷基，可选择地用R2?的1-4个取代基取代，或C4-C7直链烯基，可选择地用R2?的1-4个取代基取代，乙二醇基乙二醚，可选择地用R4?的1-4个取代基取代，或乙二醇基硫乙烷，可选择地用R4?的1-4个取代基取代，R2?表示卤素原子，三氟甲基或C1-C4烷基，R4表示氟原子或C1-C3烷基。该1,2,4-噻二唑化合物具有优异的害虫控制活性，可以有效地控制害虫，如昆虫害虫，螨虫等。
• Alkyl sulphinyl and alkyl sulphonyl-1,2,4-thiadiazolyloxy acetamides and
  申请人：Bayer Aktiengesellschaft

  公开号：US05827800A1

  公开（公告）日：1998-10-27

  The invention relates to novel alkyl sulphinyl and alkyl sulphonyl-1,2,4-thiadiazolyloxy acetamides of formula (I) ##STR1## in which n is the numbers 1 or 2, R.sup.1 is hydrogen or possibly substituted alkyl, alkenyl, alkinyl or aralkyl, R.sup.2 is possibly substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, aralkyl, aryl, alkoxy, alkenyloxy or alkinyloxy, or R.sup.1 and R.sup.2 together with the nitrogen atom to which they are bound form a possibly substituted, saturated or unsaturated nitrogen heterocycle which may contain other hetero atoms and to which a benzo group may be annellated, and R.sup.3 is possibly substituted alkyl, aryl or arylalkyl, and also processes and novel intermediate products for producing the novel compounds and their use as herbicides.

  该发明涉及一种新型的配方（I）的烷基磺酰基和烷基磺基-1,2,4-噻二唑氧基乙酰胺，其中n为1或2，R.sup.1为氢或可能被取代的烷基、烯基、炔基或芳基烷基，R.sup.2为可能被取代的烷基、烯基、炔基、环烷基、环烯烷基、芳基烷基、芳基、烷氧基、烯氧基或炔氧基，或者R.sup.1和R.sup.2与它们连接的氮原子一起形成一个可能被取代的饱和或不饱和氮杂环，该环可能含有其他杂原子，并且可能与苯基相邻结合，R.sup.3为可能被取代的烷基、芳基或芳基烷基，以及用于生产该新型化合物的工艺和新型中间体产物，以及它们作为除草剂的用途。
• [EN] 1,2,4-THIADIAZOLE COMPOUNDS AND PESTS CONTROLLING COMPOSITION CONTAINING THE SAME<br/>[FR] COMPOSES 1,2,4-THIADIAZOLE ET COMPOSITION DE LUTTE ANTIPARASITAIRE CONTENANT CES COMPOSES
  申请人：SUMITOMO CHEMICAL CO

  公开号：WO2005037805A3

  公开（公告）日：2007-11-22