O-methyl [(2-(2-fluorophenoxy)acetoxy)(phenyl)methyl]methylphosphinate | 904702-72-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: O-methyl [(2-(2-fluorophenoxy)acetoxy)(phenyl)methyl]methylphosphinate
• 英文别名: [[Methoxy(methyl)phosphoryl]-phenylmethyl] 2-(2-fluorophenoxy)acetate；[[methoxy(methyl)phosphoryl]-phenylmethyl] 2-(2-fluorophenoxy)acetate
• CAS: 904702-72-3
• 化学式: C₁₇H₁₈FO₅P
• 分子量: 352.299
• InChiKey: UCMKLACYFPGCQX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  61.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  (2-氟苯氧基)乙酸 在 氯化亚砜 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 O-methyl [(2-(2-fluorophenoxy)acetoxy)(phenyl)methyl]methylphosphinate
  参考文献：
  名称：

  Synthesis and Herbicidal Activity of [(Substituted Phenoxyacetoxy) (Substituted Phenyl)Methyl](Methyl) Phosphinates Containing Fluorine

  摘要：

  A series of [(substituted phenoxyacetoxy)(substituted phenyl)methyl](methyl)phos- phinates containing fluorine were designed and synthesized. All the synthesized compounds were identified by elemental analysis, IR, H-1 NMR, mass spectrometry. O-methyl [(2-fluorophenoxyacetoxy)(2,4-dichlorophenyl)methyl](methyl)phosphinate was further analyzed by X-ray single-crystal diffraction. Their herbicidal activity against a set of weed species was examined. Some of the compounds showed potential herbicidal activity, which provided some indications for further studies on structure modification. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.

  DOI：

  10.1080/10426507.2012.710680

文献信息

• Synthesis and Herbicidal Activity of [(Substituted Phenoxyacetoxy) (Substituted Phenyl)Methyl](Methyl) Phosphinates Containing Fluorine
  作者：Xiaoyan Deng、Guihong Liao、Qingwu Long、Yujiao Gao、Hao Peng、Hongwu He

  DOI：10.1080/10426507.2012.710680

  日期：2013.6.1

  A series of [(substituted phenoxyacetoxy)(substituted phenyl)methyl](methyl)phos- phinates containing fluorine were designed and synthesized. All the synthesized compounds were identified by elemental analysis, IR, H-1 NMR, mass spectrometry. O-methyl [(2-fluorophenoxyacetoxy)(2,4-dichlorophenyl)methyl](methyl)phosphinate was further analyzed by X-ray single-crystal diffraction. Their herbicidal activity against a set of weed species was examined. Some of the compounds showed potential herbicidal activity, which provided some indications for further studies on structure modification. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file.