4-phenylbuten-3-en-1-ol | 1081976-48-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-phenylbuten-3-en-1-ol
• 英文别名: vinyl alcohol-b-styrene；4-Phenylbuta-1,3-dien-1-ol；4-phenylbuta-1,3-dien-1-ol
• CAS: 1081976-48-8
• 化学式: C₁₀H₁₀O
• 分子量: 146.189
• InChiKey: IRNRLOWLUNXWBG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-phenylbuten-3-en-1-ol 在 tetrapyridine silver(II) peroxodisulfate 作用下， 以 乙腈 为溶剂， 反应 1.0h， 以90%的产率得到肉桂醛
  参考文献：
  名称：

  Regeneration of Aromatic Carbonyl Compounds from the Corresponding Oximes Using Tetrapyridine Silver(II) Peroxydisulfate in Acetonitrile and Aqueous Media

  摘要：

  The results of the recovery of both aldehyde and ketone carbonyl functionalities from the oxime derivatives in aromatic carbonyl compounds using tetrapyridine silver(II) peroxydisulfate [Ag(py)4S2O8] as a stable, mild, and efficient oxidizing agent is reported. Yields in excess of 85% were achieved at room temperature in both acetonitrile and aqueous media, making the method versatile and suitable for a wide range of aromatic carbonyl oximes.

  DOI：

  10.1080/00397910903013705

文献信息

• Regeneration of Aromatic Carbonyl Compounds from the Corresponding Oximes Using Tetrapyridine Silver(II) Peroxydisulfate in Acetonitrile and Aqueous Media
  作者：Mohammad Hakimi、Noorallah Feizi、Hassan Hassani、Hooshang Vahedi、P. S. Thomas

  DOI：10.1080/00397910903013705

  日期：2010.2.12

  The results of the recovery of both aldehyde and ketone carbonyl functionalities from the oxime derivatives in aromatic carbonyl compounds using tetrapyridine silver(II) peroxydisulfate [Ag(py)4S2O8] as a stable, mild, and efficient oxidizing agent is reported. Yields in excess of 85% were achieved at room temperature in both acetonitrile and aqueous media, making the method versatile and suitable for a wide range of aromatic carbonyl oximes.