1,2,4,8-Diepoxy-p-menthane | 30576-84-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 1,2,4,8-Diepoxy-p-menthane
• 英文别名: 1,3',3'-trimethylspiro[7-oxabicyclo[4.1.0]heptane-4,2'-oxirane]
• CAS: 30576-84-2
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: DHJQSGYSWNSFIL-UHFFFAOYSA-N

物化性质

• 沸点：
  208.3±8.0 °C(Predicted)
• 密度：
  1.10±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2,4,8-Diepoxy-p-menthane 在 硫酸 、 pyridinium chlorochromate 作用下， 以 四氢呋喃 、 二氯甲烷 、 水 为溶剂， 反应 25.0h， 生成 racemic 4-hydroxy-2-oxo-1,8-cineole
  参考文献：
  名称：

  Carman, Raymond M.; Rayner, Anthony C., Australian Journal of Chemistry, 1994, vol. 47, # 11, p. 2087 - 2098

  摘要：

  DOI：
• 作为产物：
  描述：

  萜品油烯 在 甲基三氧化铼(VII) 吡啶 、 双氧水 作用下， 以 二氯甲烷 为溶剂， 反应 2.0h， 以99%的产率得到1,2,4,8-Diepoxy-p-menthane
  参考文献：
  名称：

  Comparison of amine additives most effective in the new methyltrioxorhenium-catalyzed epoxidation process

  摘要：

  Three different heterocyclic amine additives, pyridine, 3-cyanopyridine and pyrazole are compared in the methyltrioxorhenium (MTO) catalyzed epoxidation of olefins using aqueous hydrogen peroxide. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)00661-9

文献信息

• Polymerizable Actinic Radiation Curable Composition, Polymerization Method, Actinic Radiation Curable Ink and Image Formation Method, and Ink Jet Recording Apparatus and Epoxy Compound
  申请人：Sasa Nobumasa

  公开号：US20080107821A1

  公开（公告）日：2008-05-08

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of —O—, —S—, —SO—, —SO 2 —, —CBr 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —; R 1 to R 18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合光致酸固化组合物，包括一种光酸发生化合物和一种由式（1）表示的环氧化合物：其中X代表从羟基、硫基、磺酸基、磺酸酯基、溴代基、三溴甲基代基和三氟甲基代基中选择的二价基团；R1至R18各自独立地表示氢原子、卤素原子、具有1-8个碳原子的碳氢基团，其中碳氢基团可能含有氧原子或卤素原子，或具有1-8个碳原子的取代或未取代的烷氧基团。
• Ink composition and inkjet recording method
  申请人：Fujifilm Corporation

  公开号：EP2169018A2

  公开（公告）日：2010-03-31

  An ink composition is provided that includes (A) a pigment other than titanium oxide, (B) a cationically polymerizable compound, and (C) a photo-acid generator, the pigment (A) having a content of 3.5 to 20 wt %, the cationically polymerizable compound (B) containing only an oxirane compound and/or an oxetane compound, the oxirane compound and/or the oxetane compound containing a low-viscosity compound having a viscosity at 25°C of no greater than 12 mPa·s, and the low-viscosity compound having a total content of 65 to 100 wt % relative to the total weight of the cationically polymerizable compound (B). There is also provided an ink composition that includes (A') titanium oxide, (B) a cationically polymerizable compound, and (C) a photo-acid generator, the titanium oxide (A') having a content of 35 to 45 wt %, the cationically polymerizable compound (B) containing an oxirane compound, oxetane compound, or vinyl ether compound having a viscosity at 25°C of no greater than 12 mPa·s, and the oxirane compound, oxetane compound, and vinyl ether compound having a viscosity at 25°C of no greater than 12 mPa·s having a total content of 65 to 100 wt % relative to the total weight of the cationically polymerizable compound (B). There is also provided an inkjet recording method that includes (a1) a step of discharging the ink composition above onto a recording medium and (b1) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation.

  提供了一种油墨组合物，其中包括 (A) 除氧化钛以外的颜料，(B) 阳离子可聚合化合物，和 (C) 光酸发生器，颜料 (A) 的含量为 3.5至20重量％，阳离子可聚合化合物(B)仅含有环氧乙烷化合物和/或氧杂环丁烷化合物，环氧乙烷化合物和/或氧杂环丁烷化合物含有低粘度化合物，其在25°C时的粘度不大于12 mPa-s，相对于阳离子可聚合化合物(B)的总重量，低粘度化合物的总含量为65至100重量％。还提供了一种油墨组合物，其中包括 (A')氧化钛、(B) 可阳离子聚合的化合物和 (C) 光酸发生器，氧化钛 (A') 的含量为 35 至 45 wt %，可阳离子聚合的化合物 (B) 含有环氧乙烷化合物、氧杂环丁烷化合物或乙烯基醚化合物，其含量为 35 至 45 wt %、或乙烯基醚化合物，其在 25°C 时的粘度不大于 12 mPa-s，且环氧乙烷化合物、氧杂环丁烷化合物和乙烯基醚化合物在 25°C 时的粘度不大于 12 mPa-s，其总含量相对于阳离子可聚合化合物 (B) 的总重量为 65 至 100 wt %。还提供了一种喷墨记录方法，包括(a1)将上述墨水组合物排放到记录介质上的步骤和(b1)通过用阳极辐射照射排放的墨水组合物来固化墨水组合物的步骤。
• Oxetane polymers and methods of preparation thereof
  申请人：RENSSELAER POLYTECHNIC INSTITUTE

  公开号：US10377855B2

  公开（公告）日：2019-08-13

  The invention is directed to processes for preparation of oxetane polymers, wherein an epoxide accelerant is reacted with one or more equivalents of a 3-monosubstituted oxetane or a 3,3-disubstituted oxetane, wherein the epoxide accelerant is selected from the group consisting of 2,2-substituted epoxide, 2,2,3-substituted epoxide, 2,2,3,3-substituted epoxide, and mixtures thereof. Also disclosed are oxetane polymers prepared by the processes of the invention.

  本发明涉及制备氧杂环丁烷聚合物的工艺，其中环氧化物促进剂与一种或多种当量的3-单取代氧杂环丁烷或3,3-二取代氧杂环丁烷反应，其中环氧化物促进剂选自由2,2-取代环氧化物、2,2,3-取代环氧化物、2,2,3,3-取代环氧化物及其混合物组成的组。还公开了通过本发明工艺制备的氧杂环丁烷聚合物。
• Cationic polymerizable composition, and recorded material, image forming process, ink set, and inkjet recording method using the same
  申请人：Sato Takehiko

  公开号：US20080187679A1

  公开（公告）日：2008-08-07

  The invention provides a cationic polymerizable composition comprising at least one oxetane compound containing an unsubstituted methyl group and at least one oxirane compound containing an unsubstituted methyl group.
• INK COMPOSITION AND INKJET RECORDING METHOD
  申请人：ARAKI Kenjiro

  公开号：US20100080925A1

  公开（公告）日：2010-04-01

  An ink composition is provided that includes (A) a pigment other than titanium oxide, (B) a cationically polymerizable compound, and (C) a photo-acid generator, the pigment (A) having a content of 3.5 to 20 wt %, the cationically polymerizable compound (B) containing only an oxirane compound and/or an oxetane compound, the oxirane compound and/or the oxetane compound containing a low-viscosity compound having a viscosity at 25° C. of no greater than 12 mPa·s, and the low-viscosity compound having a total content of 65 to 100 wt % relative to the total weight of the cationically polymerizable compound (B). There is also provided an inkjet recording method that includes (a 1 ) a step of discharging the ink composition above onto a recording medium and (b 1 ) a step of curing the ink composition by irradiating the discharged ink composition with actinic radiation.