(phenylsulfinylmethyl) tri-n-butyltin | 54086-42-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (phenylsulfinylmethyl) tri-n-butyltin
• CAS: 54086-42-9
• 化学式: C₁₉H₃₄OSSn
• 分子量: 429.254
• InChiKey: XMJORUWIZYTNJM-UHFFFAOYSA-N

物化性质

• 沸点：
  463.3±47.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.18
• 重原子数：
  22
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (phenylsulfinylmethyl) tri-n-butyltin 在 三氟甲磺酸酐 作用下， 生成 双(苯硫基)甲烷
  参考文献：
  名称：

  Tin-Pummerer Rearrangement in the Synthesis of O,S-Acetal Derivatives.

  摘要：

  alpha-Thioalkyl esters and carbonates have been prepared by a tin-Pummerer rearrangement in reactions of alpha-stannylated sulfoxides with acid chlorides or chloroformates, respectively. Acid chlorides have a higher reactivity than chloroformates in this reaction.

  DOI：

  10.3891/acta.chem.scand.51-1092
• 作为产物：
  描述：

  甲基苯基亚砜 、 1,1,1-三丁基-N,N-二甲基锡烷胺 以65%的产率得到(phenylsulfinylmethyl) tri-n-butyltin
  参考文献：
  名称：

  (Organosulfinylmethyl)tri-organotin acaricidal compositions and methods

  摘要：

  本发明涉及一种新型的（有机硫氧甲基）三有机锡化合物及其制备方法。这些有机锡化合物对应于以下一般式：##EQU1##其中，R是1至14个碳原子的烷基、芳基或取代芳基基团，每个R'是1至10个碳原子的烷基。本发明的有机锡化合物具有杀虫、杀螨和除草性能，可用于制备有效防治这些害虫的杀虫剂组合物。

  公开号：

  US03987191A1

文献信息

• Cleavage of Carbon--Sulfur Bonds in the Synthesis of alpha-Haloalkyl Carbonates.
  作者：Jostein Hatlelid、Tore Benneche、Kjell Undheim、Neucírio Ricardo de Azevedo、Pedro Henrique Ferri、Kristian Rønning Pedersen、Muhammed Nour Homsi、Frank K. H. Kuske、Monika Haugg、Nathalie Trabesinger-Rüf、Elmar G. Weinhold

  DOI：10.3891/acta.chem.scand.50-1041

  日期：——

  alpha-Chloroalkyl and alpha-bromoalkyl carbonates have been prepared by cleavage of alpha-arylthioalkyl carbonates with sulfuryl chloride or bromine, respectively. The alpha-arylthioalkyl carbonates are prepared by reaction of the hemithioacetal 1 with chloroformates or by a destannylative tin-Pummerer rearrangement of alpha-stannyl sulfoxides.
• Tin–magnesium transmetallation reactions
  作者：Rushdi I Yousef、Tobias Rüffer、Harry Schmidt、Dirk Steinborn

  DOI：10.1016/s0022-328x(02)01430-4

  日期：2002.8

  Sulfur-functionalized methyltin compounds nBu(3)SnCH(2)S(O)(i)R (i = 0, 1, 2; R = Me, Ph) underwent transmetallation with Grignard compounds MgR'X (R' = Me, nBu, Ph; X = Cl, Br, I) and diorganomagnesium compounds MgR'R" (R'/R" = Me/Me, nBu-sBu) to provide Sn(nBu)(3)R and Mg[CH2S(O)(i)R]X and Mg[CH2S(O)(i)R]R", respectively. Analogously, the reaction of nBu(3)SnCH(2)P(O)Ph-2 with Mg(nBu)Br afforded quantitatively Mg[CH2P(O)Ph-2]Br and Sn(nBu)(4). Transmetallations between it Bu3SnCH2YMe2 (Y = N, P) and MgMe2 proceeded only in the presence of catalytic amounts (10-20 mol%) of Lin Bu yielding Mg(CH2YMe2)Me and Sn(nBu)(3)Me/Sn(nBu)(4). (C) 2002 Elsevier Science B.V. All rights reserved.
• Tin-Pummerer Rearrangement in the Synthesis of O,S-Acetal Derivatives.
  作者：Jostein Hatlelid、Tore Benneche、Kjell Undheim、Frode Rise、Michael P. Hartshorn、Manuela Merchán、Ward T. Robinson、Björn O. Roos、Claire Vallance、Bryan R. Wood

  DOI：10.3891/acta.chem.scand.51-1092

  日期：——

  alpha-Thioalkyl esters and carbonates have been prepared by a tin-Pummerer rearrangement in reactions of alpha-stannylated sulfoxides with acid chlorides or chloroformates, respectively. Acid chlorides have a higher reactivity than chloroformates in this reaction.
• (Organosulfinylmethyl)tri-organotin acaricidal compositions and methods
  申请人：The Procter & Gamble Company

  公开号：US03987191A1

  公开（公告）日：1976-10-19

  Disclosed are novel(organosulfinylmethyl) triorganotin compounds and a process for preparing same. These organotin compounds correspond to the general formula: ##EQU1## where R is a 1 to 14 carbon atom alkyl, aryl or substituted aryl group and each R' is an alkyl group of 1 to 10 carbon atoms. The organotin compounds of the invention have insecticidal, acaricidal and herbicidal properties and are employed in the formulation of pesticidal compositions effective for combating these pests.

  本发明涉及一种新型的（有机硫氧甲基）三有机锡化合物及其制备方法。这些有机锡化合物对应于以下一般式：##EQU1##其中，R是1至14个碳原子的烷基、芳基或取代芳基基团，每个R'是1至10个碳原子的烷基。本发明的有机锡化合物具有杀虫、杀螨和除草性能，可用于制备有效防治这些害虫的杀虫剂组合物。