(2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine | 202405-48-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine
• 英文别名: 6-phenyl-2-[(2,6-diisopropylphenyl)imino]pyridine；N-[2,6-di(propan-2-yl)phenyl]-1-(6-phenylpyridin-2-yl)ethanimine
• CAS: 202405-48-9
• 化学式: C₂₅H₂₈N₂
• 分子量: 356.511
• InChiKey: YXGVWKAMYOIAHA-UHFFFAOYSA-N

物化性质

• 沸点：
  492.9±45.0 °C(Predicted)
• 密度：
  1.00±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  25.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine 、 cobalt(II) chloride 以 四氢呋喃 为溶剂， 反应 6.0h， 以80.5%的产率得到(2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine cobalt(II) dichloride
  参考文献：
  名称：

  带有吡啶-亚氨基配体和庞大的芳基取代基的钴配合物：合成，表征和1,3-丁二烯聚合行为

  摘要：

  一系列带有吡啶-亚氨基配体的Co（II）配合物[2-Ar 1 -6-（CMe = NAr 2）C 5 H 3 N] CoCl 2（Ar 1  = C 6 H 5，Ar 2  = 2,6 -我-Pr 2 ç 6 ħ 3（图3a）;氩1  = 2'-C 10 ħ 7中，Ar 2  = 2,6-我-Pr 2 ç 6 ħ 3（图3B）;氩1  = 2'-C 10小时7，Ar 2  ＝ C 6 H 5（3c）；Ar 1  ＝ 2′-C 10 H 7，Ar 2  ＝ 4-ClC 6 H 4（3d）；Ar 2＝ 4-ClC 6 H 4（3d）。Ar 1  ＝ 4′-C 6 H 5 -C 6 H 4，Ar 2  ＝2，6 - i- Pr 2 C 6 H 3（3e）；Ar 1  = 4′-C 6 H 5 –C 6 H 4，氩2  = C 6 H 5（3f）; 合成并表征了具有庞大芳基的Ar 1  = 4'-C

  DOI：

  10.1016/j.jorganchem.2015.05.004
• 作为产物：
  描述：

  2-乙酰基-6-溴吡啶 在 四(三苯基膦)钯 、 甲酸 、 potassium carbonate 作用下， 以 乙醇 、 甲苯 为溶剂， 反应 24.0h， 生成 (2,6-diisopropyl-phenyl)-[1-(6-phen-1-yl-pyridin-2-yl)-ethylidene]-amine
  参考文献：
  名称：

  带有吡啶-亚氨基配体和庞大的芳基取代基的钴配合物：合成，表征和1,3-丁二烯聚合行为

  摘要：

  一系列带有吡啶-亚氨基配体的Co（II）配合物[2-Ar 1 -6-（CMe = NAr 2）C 5 H 3 N] CoCl 2（Ar 1  = C 6 H 5，Ar 2  = 2,6 -我-Pr 2 ç 6 ħ 3（图3a）;氩1  = 2'-C 10 ħ 7中，Ar 2  = 2,6-我-Pr 2 ç 6 ħ 3（图3B）;氩1  = 2'-C 10小时7，Ar 2  ＝ C 6 H 5（3c）；Ar 1  ＝ 2′-C 10 H 7，Ar 2  ＝ 4-ClC 6 H 4（3d）；Ar 2＝ 4-ClC 6 H 4（3d）。Ar 1  ＝ 4′-C 6 H 5 -C 6 H 4，Ar 2  ＝2，6 - i- Pr 2 C 6 H 3（3e）；Ar 1  = 4′-C 6 H 5 –C 6 H 4，氩2  = C 6 H 5（3f）; 合成并表征了具有庞大芳基的Ar 1  = 4'-C

  DOI：

  10.1016/j.jorganchem.2015.05.004

文献信息

• Synthesis, Characterization, and Reactivity of Neutral and Cationic Pd–C,N,N Pincer Complexes
  作者：Claudio Bianchini、Géraldine Lenoble、Werner Oberhauser、Sébastien Parisel、Fabrizio Zanobini

  DOI：10.1002/ejic.200500479

  日期：2005.12

  the neutral Pd–C,N,N pincer complexes Pd(OAc)(κ3-C,N,N-L) (1) and PdCl(κ3-C,N,N-L) (2), respectively. In the presence of NaBAr′4 [Ar′ = 3,5-(CF3)2C6H3], 2 reacts in CH2Cl2 with MeCN, PPh3, or PH[o-MeO(C6H4)]2 to give the cationic palladium(II) pincer complexes [Pd(CH3CN)(κ3-C,N,N-L)]BAr′4 (3), [Pd(PPh3)(κ3-C,N,N-L)]BAr′4 (4) and Pd[PH(o-MeOC6H4)2](κ3-C,N,N-L)}BAr′4 (5), respectively. Complexes 1–5

  亚氨基膦配体 6-苯基-2-[(2,6-二异丙基苯基)亚氨基]吡啶 (HL) 与 Pd(OAc)2 和 PdCl2(PhCN)2 在苯中的邻位钯化产生中性 Pd-C,N ,N 钳形复合物 Pd(OAc)(κ3-C,N,NL) (1) 和 PdCl(κ3-C,N,NL) (2)，分别。在 NaBAr'4 [Ar' = 3,5-(CF3)2C6H3] 存在下，2 在 CH2Cl2 中与 MeCN、PPh3 或 PH[o-MeO(C6H4)]2 反应生成阳离子钯 (II) 钳络合物 [Pd(CH3CN)(κ3-C,N,NL)]BAr'4 (3), [Pd(PPh3)(κ3-C,N,NL)]BAr'4 (4) 和 Pd[PH( o-MeOC6H4)2](κ3-C,N,NL)}BAr'4 (5)。配合物 1-5 已通过多核 NMR 和 IR 光谱表征。1 和 2 的固态结构已通过单晶 X 射线衍射技术确定。中性化合物
• Copper(I)−α-Ketocarboxylate Complexes:  Characterization and O₂ Reactions That Yield Copper−Oxygen Intermediates Capable of Hydroxylating Arenes
  作者：Sungjun Hong、Stefan M. Huber、Laura Gagliardi、Christopher C. Cramer、William B. Tolman

  DOI：10.1021/ja0760426

  日期：2007.11.1

  A series of copper(I)-alpha-ketocarboxylate complexes have been prepared and shown to exhibit variable coordination modes of the alpha-ketocarboxylate ligand. Reaction with O-2 induces decarboxylation of this ligand, and the derived copper-oxygen intermediate(s) has been intercepted, resulting in hydroxylation of an arene substituent on the supporting N-donor ligand. Theoretical calculations have provided intriguing mechanistic notions for the process, notably implicating hydroxylation pathways that involve novel [Cu-I-OOC(O) R] and [Cu-II-O-center dot <-> CUIII=O2-](+) species.
• Yttrium‐Amidopyridinate Complexes: Synthesis and Characterization of Yttrium‐Alkyl and Yttrium‐Hydrido Derivatives
  作者：Lapo Luconi、Dmitrii M. Lyubov、Claudio Bianchini、Andrea Rossin、Cristina Faggi、Georgii K. Fukin、Anton V. Cherkasov、Andrei S. Shavyrin、Alexander A. Trifonov、Giuliano Giambastiani

  DOI：10.1002/ejic.200900934

  日期：2010.2

  AbstractAryl‐ or heteroaryl‐substituted aminopyridine ligands (N2HAr) react with an equimolar amount of [Y(CH2SiMe3)3(thf)2] to give yttrium(III)‐monoalkyl complexes. The process involves the deprotonation of N2HAr by a yttrium alkyl followed by a rapid and quantitative intramolecular sp2‐CH bond activation of the aryl or heteroaryl pyridine substituents. As a result, new Y complexes distinguished by rare examples of CH bond activations have been isolated and completely characterized. Selective σ‐bond metathesis reactions take place on the residual Y–alkyl bonds upon treatment with PhSiH3. Unusual binuclear metallacyclic yttrium(III)‐hydrido complexes have been obtained and characterized by NMR spectroscopy and X‐ray diffraction analysis.
• Selective Oligomerization of Ethylene to Linear α-Olefins by Tetrahedral Cobalt(II) Complexes with 6-(Organyl)-2-(imino)pyridyl Ligands:  Influence of the Heteroatom in the Organyl Group on the Catalytic Activity
  作者：Claudio Bianchini、Giuseppe Mantovani、Andrea Meli、Fabio Migliacci、Franco Laschi

  DOI：10.1021/om030227d

  日期：2003.6.1

  The oligomerization of ethylene to alpha-olefins has been obtained by MAO activation of tetrahedral Co-II complexes of iminopyridines substituted in the 6-position of the pyridine ring by thiophen-2-yl, furan-2-yl, or phenyl groups. An intriguing heteroatom effect has been noticed on both activity and selectivity, together with a change in the Co-II spin state upon activation of the dichloride precursors with MAO.
• Cobalt complexes bearing pyridine-imino ligands with bulky aryl substituents: Synthesis, characterization, and 1,3-butadiene polymerization behaviors
  作者：Jun Guo、Chunyu Zhang、Jifu Bi、Hexin Zhang、Chenxi Bai、Yanming Hu、Xuequan Zhang

  DOI：10.1016/j.jorganchem.2015.05.004

  日期：2015.12

  Ar2 = 4-ClC6H4 (3g)) with bulky aryl groups were synthesized and characterized. Determined by single-crystal X-ray diffraction, 3a, 3b, and 3e adopted distorted tetrahedron configurations. Activated by ethylaluminum sesquichloride (EASC), these complexes exhibited high cis-1,4 selectivity for 1,3-butadiene polymerization. The steric and electronic properties of substituent of the ligand remarkably influenced

  一系列带有吡啶-亚氨基配体的Co（II）配合物[2-Ar 1 -6-（CMe = NAr 2）C 5 H 3 N] CoCl 2（Ar 1  = C 6 H 5，Ar 2  = 2,6 -我-Pr 2 ç 6 ħ 3（图3a）;氩1  = 2'-C 10 ħ 7中，Ar 2  = 2,6-我-Pr 2 ç 6 ħ 3（图3B）;氩1  = 2'-C 10小时7，Ar 2  ＝ C 6 H 5（3c）；Ar 1  ＝ 2′-C 10 H 7，Ar 2  ＝ 4-ClC 6 H 4（3d）；Ar 2＝ 4-ClC 6 H 4（3d）。Ar 1  ＝ 4′-C 6 H 5 -C 6 H 4，Ar 2  ＝2，6 - i- Pr 2 C 6 H 3（3e）；Ar 1  = 4′-C 6 H 5 –C 6 H 4，氩2  = C 6 H 5（3f）; 合成并表征了具有庞大芳基的Ar 1  = 4'-C