phenolatemagnesium chloride | 32664-68-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: phenolatemagnesium chloride
• 英文别名: phenoxy magnesium chloride；Phenoxymagnesium Chloride；magnesium;chloride;phenoxide
• CAS: 32664-68-9
• 化学式: C₆H₅O*Cl*Mg
• 分子量: 152.863
• InChiKey: YJCTUQFSSZSZPO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -2.62
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  aluminum (III) chloride 、 phenolatemagnesium chloride 以 四氢呋喃 为溶剂， 反应 5.0h， 生成 (phenolatemagnesium chloride)2AlCl3
  参考文献：
  名称：

  A novel electrolyte system without a Grignard reagent for rechargeable magnesium batteries

  摘要：

  制备了一种新的苯酚基镁离子导电电解质。该电解质具有对空气不敏感的特性和优异的电化学性能，因此在先进的可充电镁电池系统中大有可为。

  DOI：

  10.1039/c2cc35857c
• 作为产物：
  描述：

  乙基氯化镁 、 苯酚 以 四氢呋喃 为溶剂， 反应 8.0h， 生成 phenolatemagnesium chloride
  参考文献：
  名称：

  Enhanced oxidative stability of non-Grignard magnesium electrolytes through ligand modification

  摘要：

  从市售苯酚开始，合成了一系列具有各种对位取代基的非格氏镁电解质。更多的抽电子取代基将电解质的阳极稳定性提高了 400 mV。p-CF3 取代的苯酚对 Mg2+/0 的稳定性最高，达到 2.9 V，并可与雪佛龙相 Mo6S8 镁离子阴极进行可逆循环。

  DOI：

  10.1039/c3cc47277a

文献信息

• Hydrocarbyloxy magnesium halides
  申请人：Lithium Corporation of America

  公开号：US04792640A1

  公开（公告）日：1988-12-20

  This invention concerns solid organometallic hydrocarbyloxymagnesium halides of the formula ROMgX wherein RO is a hydrocarbyloxy group of 1 to 20 carbon atoms and X is halide, and a two step process for making these halides comprising: (a) reacting an activated magnesium metal with an alkyl halide of the formula R'X, in which R' is compound containing 1 to 20 carbon atoms, in a dry inert hydrocarbon media, under a dry inert atmosphere to produce a compound of the formula R'MgX in which R' and X have the meanings ascribed to them herein; and, (b) and reacting the R'MgX compound with an oxygen containing compound, containing 1 to 20 carbon atoms, selected from the group consisting of alcohols, ketones, aldehydes and esters to produce the compound ROMgX. When the oxygen containing compound is 2-alkyl substituted, the products are hydrocarbon soluble.

  本发明涉及一种化学物质，即式为ROMgX的固体有机金属烃氧基镁卤化物，其中RO是1至20个碳原子的烃氧基基团，X是卤素。制备这些卤化物的两步法包括：（a）在干燥的惰性烃介质中，在干燥的惰性气氛下，将活性镁金属与化合物R'X反应，其中R'是含有1至20个碳原子的化合物，以产生式为R'MgX的化合物，其中R'和X的含义如本文所述；（b）将R'MgX化合物与含有1至20个碳原子的含氧化合物反应，所述含氧化合物选择自醇，酮，醛和酯的群体，以产生ROMgX化合物。当含氧化合物为2-烷基取代时，产物是可溶于烃的。
• Olefin coordination polymerization catalyst and use thereof
  申请人：PetroChina Company Limited

  公开号：US10927195B2

  公开（公告）日：2021-02-23

  The present invention provides an olefin coordination polymerization catalyst and use thereof. The composition of the raw materials of the olefin coordination polymerization catalyst comprises: a main catalyst and a cocatalyst, wherein a molar ratio of the transition metal halide in the main catalyst to the cocatalyst is 1:10-500; and the composition of the raw materials of the main catalyst comprises a magnesium compound, a transition metal halide, an alcohol having 2 to 15 carbon atoms, and a star-shaped organosiloxane compound in a molar ratio of 1:1-40:0.01-10:0.001-10; and the cocatalyst comprises an organoaluminum compound. The above olefin coordination polymerization catalyst is used as a catalyst for ethylene polymerization, propylene polymerization, and copolymerization of ethylene or propylene with an α-olefin. The olefin polymerization catalyst of the present invention has good catalytic activity.

  本发明提供了一种烯烃配位聚合催化剂及其用途。该烯烃配位聚合催化剂的原料组成包括：主催化剂和助催化剂，其中主催化剂中过渡金属卤化物与助催化剂的摩尔比为1:10-500；主催化剂的原料组成包括镁化合物、过渡金属卤化物、具有2至15个碳原子的醇和星形有机硅氧烷化合物，其摩尔比为1:1-40:0.01-10:0.001-10；而助催化剂包括一种有机铝化合物。上述烯烃配位聚合催化剂可用作乙烯聚合、丙烯聚合以及乙烯或丙烯与 α-烯烃共聚的催化剂。本发明的烯烃聚合催化剂具有良好的催化活性。
• Composite carrier of catalysts for propylene polymerization, a catalyst component and a catalyst comprising the same
  申请人：CHINA PETROLEUM & CHEMICAL CORPORATION

  公开号：US20040229748A1

  公开（公告）日：2004-11-18

  The present invention is to provide a composite carrier, which is spheric particles obtainable by contacting magnesium halide with one or more electron donor compounds to form a solution, then mixing the solution with silica material having an average particle size of less than 10 microns to form a mixture, and drying the mixture through spray drying process. The present invention is also to provide a catalyst component comprising said composite carrier. When the catalyst component is used together with a cocatalyst component in propylene polymerization, it exhibits higher polymerization activity and stereospecificity, and can be used to prepare high impact resistant ethylene-propylene copolymer having high ethylene content.

  本发明旨在提供一种复合载体，它是通过将卤化镁与一种或多种电子供体化合物接触形成溶液，然后将该溶液与平均粒径小于 10 微米的二氧化硅材料混合形成混合物，并通过喷雾干燥工艺干燥该混合物而获得的球形颗粒。本发明还提供一种包含上述复合载体的催化剂组分。当催化剂组分与助催化剂组分一起用于丙烯聚合时，可表现出更高的聚合活性和立体特异性，并可用于制备具有高乙烯含量的高抗冲击性乙烯-丙烯共聚物。
• TRANSITION METAL COMPLEX, PREPARATION METHOD FOR SAID TRANSITION METAL COMPLEX, TRIMERIZATION CATALYST, PREPARATION METHOD FOR 1-HEXENE, PREPARATION METHOD FOR ETHYLENE POLYMER, SUBSTITUTED CYCLOPENTADIENE COMPOUND, AND PREPARATION METHOD FOR SAID SUBSTITUTED CYCLOPENTADIENE COMPOUND
  申请人：Sumitomo Chemical Co., Ltd

  公开号：EP2484685B1

  公开（公告）日：2017-11-01
• COMPLEX SUPPORT SUITABLE FOR PROPYLENE POLYMERIZATION CATALYST, A CATALYST COMPONENT AND CATALYST CONTAINING THE SAME
  申请人：China Petroleum & Chemical Corporation

  公开号：EP1609805B1

  公开（公告）日：2012-10-17