2-dichlorophosphoryloxy-benzoyl chloride | 6099-41-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-dichlorophosphoryloxy-benzoyl chloride
• 英文别名: 2-Dichlorphosphinyloxy-benzoylchlorid；Dichlorophosphorsaeure-(2-chlorcarbonyl-phenylester)；2-Dichlorphosphinyloxy-benzoesaeure-chlorid；2-Dichlorphosphoryloxy-benzoylchlorid；Phosphorsaeure-(2-chlorformyl-phenylester)-dichlorid；(2-Chlorformyl-phenyl)-phosphorsaeure-dichlorid；2-(Chlorocarbonyl)phenyl phosphorodichloridate；2-dichlorophosphoryloxybenzoyl chloride
• CAS: 6099-41-8
• 化学式: C₇H₄Cl₃O₃P
• 分子量: 273.44
• InChiKey: YSOXJTIJJTYMOP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-dichlorophosphoryloxy-benzoyl chloride 生成 磷柳酸
  参考文献：
  名称：

  Chasanowitsch, Chemische Berichte, 1887, vol. 20, p. 1165

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 氯 作用下， 生成 2-dichlorophosphoryloxy-benzoyl chloride
  参考文献：
  名称：

  Anschuetz; Emery, Justus Liebigs Annalen der Chemie, 1887, vol. 239, p. 311

  摘要：

  DOI：

文献信息

• Anschuetz,R.; Moore, Justus Liebigs Annalen der Chemie, 1887, vol. 239, p. 336,341
  作者：Anschuetz,R.、Moore

  DOI：——

  日期：——
• Anschuetz; Emery, Justus Liebigs Annalen der Chemie, 1889, vol. 253, p. 118
  作者：Anschuetz、Emery

  DOI：——

  日期：——
• Kolbe; Lautemann, Justus Liebigs Annalen der Chemie, 1860, vol. 115, p. 194
  作者：Kolbe、Lautemann

  DOI：——

  日期：——
• Anschuetz,R.; Moore, Justus Liebigs Annalen der Chemie, 1887, vol. 239, p. 319
  作者：Anschuetz,R.、Moore

  DOI：——

  日期：——
• Starch Accumulation Is Associated with Adventitious Root Formation in Hypocotyl Cuttings of Pinus radiata
  作者：Mingshan Li、David W.M. Leung

  DOI：10.1007/s003440000020

  日期：2000.12

  This study of the internal physiology of adventitious root formation in Pinus radiata was performed without the potential complications from microbial contamination and nutritional stress. Hypocotyl cuttings of radiata pine were cultured in half strength MS nutrient medium supplemented with IBA (indole-3-butyric acid), IBA + kinetin, kinetin, or without phytohormones (control). Averages of 8.35 and 0.08 roots per cutting were formed in IBA and in growth regulator-free treatments, respectively. No roots were formed in IBA + kinetin, kinetin, or sucrose-free treatments at day 30 after excision of hypocotyls. Changes in fresh weight, sugar, and starch content were measured at established developmental stages associated with adventitious root formation. Sucrose-supplemented medium was required for higher levels of sugar, starch, and root formation in rooting region of IBA-treated hypocotyls. Starch accumulation, in particular, seems to have potential as a biochemical marker before root primordium emergence in light of the following observations in the IBA treatment. Starch began to build up preferentially in cells involved in or in close proximity to potential sites of new root primordium formation (that is, the cells on the inside of the cortex and the pith) before any visible organized root primordia and then began to disappear during root primordium formation. The substantial starch accumulation associated with IBA treatment was not observed in the IBA + kinetin, kinetin alone, growth regula tor-free, sucrose-free treatments (nonrooting treatments) or in the nonrooting region of hypocotyls treated with IBA.