benzyl(trimethyl)ammonium formate | 58989-82-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: benzyl(trimethyl)ammonium formate
• 英文别名: Benzyl(trimethyl)azanium;formate
• CAS: 58989-82-5
• 化学式: CHO₂*C₁₀H₁₆N
• 分子量: 195.261
• InChiKey: IIAZMNFNSAERNY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.26
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  培高利特 、 benzyl(trimethyl)ammonium formate 在 2,4-滴二甲胺盐 作用下， 以 甲醇 为溶剂， 生成 8β-(methyloxymethyl)-6-propylergoline
  参考文献：
  名称：

  6-N-Propyl-8-methoxymethyl or methylmercaptomethylergolines and related

  摘要：

  6-正丙基（乙基或烯丙基）-8-β-甲氧基-（甲磺酰基、甲砜基或甲硫基）甲基麦角碱，8-麦角酚或9-麦角酚，可用作催乳素抑制剂并用于帕金森病的治疗。

  公开号：

  US04166182A1
• 作为产物：
  描述：

  甲酸 、 苄基三甲基氢氧化铵 以 甲醇 为溶剂， 反应 2.0h， 以80%的产率得到benzyl(trimethyl)ammonium formate
  参考文献：
  名称：

  Use of Formate Salts as a Hydride and a CO₂ Source in PGeP-Palladium Complex-Catalyzed Hydrocarboxylation of Allenes

  摘要：

  Use of formate salts as a hydride as well as a CO2 source was achieved in a PGeP-palladium complex-catalyzed hydrocarboxylation of allenes through a highly efficient decarboxylationcarboxylation process. This reaction proceeds under mild conditions and provides an alternative strategy for utilizing formate salts as a C1 source.

  DOI：

  10.1021/acs.orglett.5b00692

文献信息

• 3-aminochroman spiro compounds
  申请人：Adir et Compagnie

  公开号：US05376661A1

  公开（公告）日：1994-12-27

  The invention relates to a compound selected from those of formula (I): ##STR1## in which R.sub.1, R.sub.2, R.sub.3, A and m are as defined in the description. Medicinal product which is useful for treating depression and anxiety.

  该发明涉及选择自式(I)中的化合物：##STR1##其中R.sub.1、R.sub.2、R.sub.3、A和m如描述中所定义。该药物对治疗抑郁症和焦虑症有用。
• Ergoline compounds, their preparation and pharmaceutical compositions containing them
  申请人：ELI LILLY AND COMPANY

  公开号：EP0003667A1

  公开（公告）日：1979-08-22

  Novel ergoline compounds of the following formula are described: wherein R1 is ethyl, n-propyl, or allyl; Y is O, S, SO, or SO2; X is hydrogen, chloro, or bromo; the dotted line represents the optional presence of a double bond; and the pharmaceutically-acceptable acid addition salts thereof. The compounds are useful to inhibit prolactin secretion or to treat Parkinson's syndrome.

  描述了下式的新型麦角啉化合物： 其中 R1 是乙基、正丙基或烯丙基；Y 是 O、S、SO 或 SO2；X 是氢、氯或溴；虚线表示任选存在的双键；及其药学上可接受的酸加成盐。这些化合物可用于抑制催乳素分泌或治疗帕金森综合症。
• Verfahren zur Herstellung von bifunktionnellen Polyphenylenoxiden
  申请人：BAYER AG

  公开号：EP0144702A2

  公开（公告）日：1985-06-19

  Die Erfindung betrifft ein neues Verfahren zur Herstellung von bifunktionellen Polyphenylenoxiden.

  本发明涉及一种生产双功能聚苯氧化物的新工艺。
• Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and an acid functional component
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0351965A1

  公开（公告）日：1990-01-24

  A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about (a) 25-90% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecualr weight of about 2,000-50,000; (b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; (c) 5-50% by weight, based on the weight of the binder of an acid functional monomeric, oligomeric or polymeric compound which may or may not contain hydroxyl functionality; and the composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.

  一种可用于汽车和卡车面漆的涂料组合物，其中成膜粘结剂包含的活性粘结剂成分约为 (a) 25-90%（以粘合剂重量计）的丙烯酸聚合物，该聚合物具有至少两个活性酸酐基团，由乙烯基不饱和酸酐的聚合单体和甲基丙烯酸烷基酯、丙烯酸烷基酯及其混合物组成的组中的聚合单体构成，其中烷基具有 1-8 个碳原子，聚合物的平均摩尔重量约为 2,000-50,000 磅； (b) 5-50%（以粘合剂重量计）的缩水甘油成分，其中至少有两个活性缩水甘油基； (c) 5-50%（以粘合剂重量计）的酸官能团单体、低聚物或聚合化合物，其可能含也可能不 含羟基官能团；以及 以粘合剂重量计，组合物含有约 0.1-5%（重量）的催化剂。
• Multi-component coating composition comprising an anhydride containing polymer, a glycidyl component and a self-stabilized dispersion resin
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0351966A1

  公开（公告）日：1990-01-24

  A coating composition useful for a finish for automobiles and trucks in which the film forming binder contains reactive binder components of about (a) 25-94% by weight, based on the weight of the binder, of an acrylic polymer having at least two reactive anhydride groups composed of polymerized monomers of an ethylenically unsaturated anhydride and polymerized monomers from the group consisting of alkyl methacrylate, alkyl acrylate and any mixtures thereof, wherein the alkyl groups have 1-8 carbon atoms and the polymer has a weight average molecular weight of about 2,000-50,000; (b) 5-50% by weight, based on the weight of the binder, of a glycidyl component having at least two reactive glycidyl groups; (c) 1-40% by weight, based on the weight of the binder, of a self-stabilized dispersed resin; and the composition contains about 0.1-5% by weight; based on the weight of the binder, of a catalyst.

  一种可用于汽车和卡车面漆的涂料组合物，其中成膜粘结剂包含的活性粘结剂成分约为 (a) 25-94%（以粘合剂重量计）的丙烯酸聚合物，该聚合物具有至少两个活性酸酐基团，由乙烯基不饱和酸酐的聚合单体和甲基丙烯酸烷基酯、丙烯酸烷基酯及其混合物组成的组中的聚合单体构成，其中烷基具有 1-8 个碳原子，聚合物的重量平均分子量约为 2,000-50,000 ； (b) 5-50%（以粘合剂重量计）的缩水甘油成分，其中至少有两个活性缩水甘油基； (c) 自稳定分散树脂（按粘合剂重量计）1-40%；以及 组合物中含有约 0.1-5%（重量百分比）的催化剂，以粘合剂重量为基准。