MeSC6H4SeSiMe3 | 1235452-55-7

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: MeSC6H4SeSiMe3
• 英文别名: Trimethyl-(4-methylsulfanylphenyl)selanylsilane；trimethyl-(4-methylsulfanylphenyl)selanylsilane
• CAS: 1235452-55-7
• 化学式: C₁₀H₁₆SSeSi
• 分子量: 275.349
• InChiKey: OMCZUOAGTRDOTK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.57
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  MeSC6H4SeSiMe3 、 1,5-双(二苯基膦)戊烷 、 copper (I) acetate 、 甲苯 反应 1.0h， 以38%的产率得到[Cu₂(p-SeC₆H₄SMe)₂(1,5-bis(diphenylposphino)pentane)₂]*2(toluene)
  参考文献：
  名称：

  Synthesis, characterization and optical properties of a series of binuclear copper chalcogenolato complexes

  摘要：

  A series of isolated binuclear copper(I) thiolate and selenolate complexes [Cu-2(ER)(2)(dpppt)(2)] (1, E = S, R = C4H3S; 2, E = S, R = p-C6H4OMe; 3, E = Se, R = C6H5; 4, E = Se, R = p-C6H4SMe; 5, E = Se, R = p-C6H4NMe2) was synthesized. It was found that the luminescence of these complexes could be modulated by the chalcogenolate ligands. The five complexes show optical transitions with HOMO-LUMO gaps of ca. 2.95 eV (1), 2.82 eV (2), 2.99 eV (3), 2.95 eV (4) and 2.64 eV (5), respectively. Two of them (2 and 5) show a significant luminescence at room temperature at 465 or 480 nm, respectively. This might most probably result from the influence of the electron donating nature of the substituents -OMe and -NMe2. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2014.05.009

文献信息

• One‐Dimensional Coordination Polymers Containing Polynuclear (Selenolato)copper Complexes Linked by Bipyridine Ligands
  作者：Ming‐Lai Fu、Dieter Fenske、Bastian Weinert、Olaf Fuhr

  DOI：10.1002/ejic.200900711

  日期：2010.3

  Three one-dimensional coordination polymers [Cu 6 (SePh) 6 -(PPh 3 ) 3 (4,4'-bpy)] (1) (4,4'-bpy=4,4'-bipyridine), [Cu 2 (SePh) 2 -(dppm)(4,4'-bpy)] (2), and [Cu 2 (SePh) 2 (dppe)(4,4'-bpy)] (3), containing polynuclear (selenolato)copper complexes and linear cross-linking bipyridine ligands, and one isolated dinuclear complex, [Cu 2 (SeC 6 H 4 SMe) 2 (PPh 3 ) 2 (4,4'-bpy) 2 ] (4), have been prepared

  三种一维配位聚合物[Cu 6 (SePh) 6 -(PPh 3 ) 3 (4,4'-bpy)] (1) (4,4'-bpy=4,4'-联吡啶), [Cu 2 (SePh) 2 -(dppm)(4,4'-bpy)] (2) 和 [Cu 2 (SePh) 2 (dppe)(4,4'-bpy)] (3)，含有多核 (selenolato)铜配合物和线性交联联吡啶配体，以及一种分离的双核配合物，[Cu 2 (SeC 6 H 4 SMe) 2 (PPh 3 ) 2 (4,4'-bpy) 2 ] (4)，已被制备。这四种配合物显示出具有约 HOMO-LUMO 间隙的光学跃迁。分别为 1.76 eV (1)、1.83 eV (2)、1.76 eV (3) 和 2.12 eV (4)。
• Metal-Rich Copper Chalcogenide Clusters at the Border Between Molecule and Bulk Phase: The Structures of [Cu93Se42(SeC6H4SMe)9(PPh3)18], [Cu96Se45(SeC6H4SMe)6(PPh3)18], and [Cu136S56(SCH2C4H3O)24(dpppt)10]
  作者：Ming-Lai Fu、Ibrahim Issac、Dieter Fenske、Olaf Fuhr

  DOI：10.1002/anie.201001301

  日期：2010.9.10

  Between molecule and bulk phase: The three title compounds are examples of ligand‐stabilized clusters having significant structural features of the corresponding binary copper(I) chalcogenides. The cluster shown, [Cu136S56(SR)24(dpppt)10], can be seen as an approximate 1.2×1.4×1.9 nm3 section of a cubic phase of Cu2S. The background shows a typical X‐ray diffraction image of a single crystal of the

  在分子和本体相之间：这三种标题化合物是配体稳定簇的实例，具有相应二元铜硫属元素化物的显着结构特征。所示簇[Cu 136 S 56（SR）24（dpppt）10 ]可以看作是Cu 2 S立方相的大约1.2×1.4×1.9 nm 3截面。背景显示了典型的X射线团簇单晶的衍射图。