1-N',4-N'-bis(2-hydroxybenzoyl)butanedihydrazide | 36931-47-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-N',4-N'-bis(2-hydroxybenzoyl)butanedihydrazide
• CAS: 36931-47-2
• 化学式: C₁₈H₁₈N₄O₆
• 分子量: 386.364
• InChiKey: QHDUFMSGIWHWJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  28
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  157
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  吡啶 、 copper(II) nitrate trihydrate 、 1-N',4-N'-bis(2-hydroxybenzoyl)butanedihydrazide 以 吡啶 为溶剂， 生成
  参考文献：
  名称：

  Trinuclear copper(II) complexes with diacylhydrazines of aliphatic dicarboxylic acids and salicylic acid

  摘要：

  Trinuclear copper(II) complexes with diacyldihydrazines of aliphatic dicarboxylic acids (from succinic acid to heptadioic acid) and salicylic acid were synthesized. The complexes were studied by chemical analysis, thermogravimetry, and IR spectroscopy. The structure of trinuclear copper(II) complex with diacylhydrazine of glutaric and salicylic acids of the [Cu3L3 center dot 4Py] center dot 2Py composition was determined by X-ray crystallography. The complex has a molecular structure and contains three nonequivalent copper atoms. The Cu(2)...Cu(3) distance is 8.506 ; the Cu(2)...Cu(1) and Cu(3)...Cu(1) distances are 4.612 and 4.588 , respectively. The coordination polyhedra of two copper atoms are tetragonal pyramids, and the third copper atom has a square environment. An interest feature of the complex under study is the induced closure of the bent eight-membered chelate ring containing carbon atoms of a polymethylene spacer.

  DOI：

  10.1134/s0036023610100128

文献信息

• Trinuclear copper(II) complexes with diacylhydrazines of aliphatic dicarboxylic acids and salicylic acid
  作者：V. F. Shul’gin、A. I. Obukh、O. V. Konnik、E. B. Rusanov、V. V. Minin

  DOI：10.1134/s0036023610100128

  日期：2010.10

  Trinuclear copper(II) complexes with diacyldihydrazines of aliphatic dicarboxylic acids (from succinic acid to heptadioic acid) and salicylic acid were synthesized. The complexes were studied by chemical analysis, thermogravimetry, and IR spectroscopy. The structure of trinuclear copper(II) complex with diacylhydrazine of glutaric and salicylic acids of the [Cu3L3 center dot 4Py] center dot 2Py composition was determined by X-ray crystallography. The complex has a molecular structure and contains three nonequivalent copper atoms. The Cu(2)...Cu(3) distance is 8.506 ; the Cu(2)...Cu(1) and Cu(3)...Cu(1) distances are 4.612 and 4.588 , respectively. The coordination polyhedra of two copper atoms are tetragonal pyramids, and the third copper atom has a square environment. An interest feature of the complex under study is the induced closure of the bent eight-membered chelate ring containing carbon atoms of a polymethylene spacer.