2-methyl-4,6-di-p-tolyl-1,3,5-triazine | 30377-13-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-methyl-4,6-di-p-tolyl-1,3,5-triazine
• 英文别名: 2-Methyl-4,6-bis(4-methylphenyl)-1,3,5-triazine
• CAS: 30377-13-0
• 化学式: C₁₈H₁₇N₃
• 分子量: 275.353
• InChiKey: UITDPTGYWDSNDK-UHFFFAOYSA-N

物化性质

• 熔点：
  152-153 °C(Solv: ethanol (64-17-5))
• 沸点：
  481.6±48.0 °C(Predicted)
• 密度：
  1.108±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  acetyl-p-toluimidoyl-amine 生成 2-methyl-4,6-di-p-tolyl-1,3,5-triazine
  参考文献：
  名称：

  Pinner, Justus Liebigs Annalen der Chemie, 1897, vol. 298, p. 30

  摘要：

  DOI：

文献信息

• Synthesis of 1,3,5-triazines via Cu(OAc)₂-catalyzed aerobic oxidative coupling of alcohols and amidine hydrochlorides
  作者：Qing You、Fei Wang、Chaoting Wu、Tianchao Shi、Dewen Min、Huajun Chen、Wu Zhang

  DOI：10.1039/c5ob00724k

  日期：——

  1,3,5-Triazines were obtained via Cu(OAc)₂ catalyzed reaction of benzamidine hydrochlorides and alcohols in air.

  1,3,5-三嗪通过在空气中使用Cu(OAc)₂催化苯甲酰胺盐酸盐和醇的反应获得。
• Reactions of 3-aryl-5-methyl-1,2,4-oxadiazoles with benzyl alcohol and with benzylamine
  作者：Jonathan W. Brown、Dennis W. Clack、David A. Wilson

  DOI：10.1039/p29880000117

  日期：——

  When heated with benzyl alcohol, 3-aryl-5-methyl-1,2,4-oxadiazoles afford mainly the aryl nitrile, benzyl acetate, and benzaldehyde. A number of other products, including 1,3,5-triazines, have been identified. Benzylamine and 5-methyl-1,2,4-oxadiazoles similarly give aryl nitrile and N-acetylbenzylamine, but the reaction is slower. However, in mixtures of the alcohol and the amine, the amine reacts

  当与苄醇一起加热时，3-芳基-5-甲基-1,2,4-恶二唑类化合物主要提供芳基腈，乙酸苄酯和苯甲醛。已经鉴定出许多其他产品，包括1,3,5-三嗪。苄胺和5-甲基-1,2,4-恶二唑类似地得到芳基腈和N-乙酰基苄胺，但反应较慢。但是，在醇和胺的混合物中，胺反应更快。讨论了可能的反应机理。恶二唑的甲基显示出其质子与苄醇的质子交换比恶二唑更易与苄醇反应的质子交换。
• COMPOUND
  申请人：CAMBRIDGE DISPLAY TECHNOLOGY LIMITED

  公开号：US20170040556A1

  公开（公告）日：2017-02-09

  The present invention relates to a compound of general formula (I) which can transport holes in an organic optoelectronic device, and to blends and solutions comprising the compound of general formula (I): wherein X is C, Si or Ge; A is a group of formula (II) wherein Z is N, P, NH, O or S; E is C 1-10 alkyl or H; W is substituted or unsubstituted C 5-14 aryl or substituted or unsubstituted C 6-16 alkyl; e is an integer from 1 to 4; and z is 1 or 2; B, C and D are each independently A, H, C 1 -C 12 alkyl, C 5-14 aryl or OH; and a, b, c and d are each independently an integer from 1 to 5.

  本发明涉及一种通式（I）的化合物，该化合物可在有机光电器件中传输空穴，以及包含通式（I）的混合物和溶液：其中X为C，Si或Ge；A为式（II）的基团：其中Z为N，P，NH，O或S；E为C1-10烷基或H；W为取代或未取代的C5-14芳基或取代或未取代的C6-16烷基；e为1至4的整数；z为1或2；B、C和D各自独立地为A、H、C1-C12烷基、C5-14芳基或OH；a、b、c和d各自独立地为1至5的整数。
• POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：Sumitomo Chemical Company, Limited

  公开号：US20170137566A1

  公开（公告）日：2017-05-18

  Provided is a polymer compound which is useful for production of a light emitting device excellent in light emission efficiency is provided. The polymer compound contains a constitutional unit represented by the formula (1) and a constitutional unit represented by the formula (Y) as follows: wherein R 1 to R 8 represent a hydrogen atom, an alkyl group, an aryl group or the like, and R A and R B represent an aryl group or a monovalent heterocyclic group, and Ar Y1   (Y) wherein Ar Y1 represents an arylene group or the like.

  提供了一种聚合物化合物，可用于生产具有出色的光发射效率的发光装置。该聚合物化合物包含由式（1）表示的构成单元和由式（Y）表示的构成单元，其中R1至R8表示氢原子，烷基，芳基或类似物，RA和RB表示芳基或单价杂环基，而ArY1（Y）表示芳烃基或类似物。
• HIGH-MOLECULAR COMPOUND AND LIGHT-EMITTING ELEMENT USING SAME
  申请人：Sumitom Chemical Company, Limited

  公开号：US20150155495A1

  公开（公告）日：2015-06-04

  A polymer compound has a repeating unit represented by general formula (1): wherein R 1a represents an alkyl group, an aryl group, a monovalent aromatic heterocyclic group or an aralkyl group, each possibly substituted and the same or different; and X 1a represents a group selected from formulae (1a) to (1c).] wherein R 1c represents an aryl group or a monovalent aromatic heterocyclic group, possibly substituted; and R 1d to R 1f represent each independently an alkyl group, an aryl group, a monovalent aromatic heterocyclic group, an alkoxy group, an aryloxy group, an aralkyl group, an arylalkoxy group, a substituted amino group, a substituted carbonyl group, a substituted carboxyl group, a fluorine atom or a cyano group; and the pairs R 1d and R 1e , R 1f and R 1g , R 1d and R 1f , and R 1e and R 1g may be mutually linked to form a ring together with a carbon atom to which they are linked.

  一种聚合物化合物具有由通式（1）表示的重复单元，其中R1表示一个烷基、芳基、一价芳香杂环基或芳基烷基，每个可能被取代且相同或不同；X1表示从式（1a）到（1c）中选择的基团，其中R1c表示芳基或一价芳香杂环基，可能被取代；R1d到R1f分别独立地表示烷基、芳基、一价芳香杂环基、烷氧基、芳氧基、芳基烷基、芳基烷氧基、取代氨基、取代羰基、取代羧基、氟原子或氰基；并且R1d和R1e、R1f和R1g、R1d和R1f以及R1e和R1g这些配对可能相互连接，与它们连接的碳原子一起形成环。