resorcinol bis(tetraethylphosphodiamidite) | 194033-62-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: resorcinol bis(tetraethylphosphodiamidite)
• 英文别名: N-[[3-[bis(diethylamino)phosphanyloxy]phenoxy]-(diethylamino)phosphanyl]-N-ethylethanamine
• CAS: 194033-62-0
• 化学式: C₂₂H₄₄N₄O₂P₂
• 分子量: 458.564
• InChiKey: WPXQLZLCNLDFIY-UHFFFAOYSA-N

物化性质

• 沸点：
  491.7±55.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  30
• 可旋转键数：
  16
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  31.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  resorcinol bis(tetraethylphosphodiamidite) 在 sulfur 作用下， 以 1,4-二氧六环 为溶剂， 反应 1.5h， 以81%的产率得到O,O'-m-phenylene bis(tetraethylphosphodiamidothioate)
  参考文献：
  名称：

  Nifant'ev; Rasadkina; Yankovich, Russian Journal of General Chemistry, 1997, vol. 67, # 11, p. 1704 - 1709

  摘要：

  DOI：
• 作为产物：
  描述：

  六乙基亚磷酸胺 、 间苯二酚 以 乙腈 为溶剂， 生成 resorcinol bis(tetraethylphosphodiamidite)
  参考文献：
  名称：

  Nifant'ev; Rasadkina; Batalova, Doklady Chemistry, 1997, vol. 353, # 1-3, p. 41 - 44

  摘要：

  DOI：

文献信息

• Phosphorylation of 1,4-bis(hydroxymethyl)benzene with trivalent phosphorus derivatives
  作者：P. V. Slitikov、V. A. Bogoyavlenskii、E. N. Rasadkina、E. E. Nifant’ev

  DOI：10.1134/s1070363207060126

  日期：2007.6

  Phosphorylation of 1,4-bis(hydroxymethyl)benzene with complete phosphorous acid amides and phenyl phosphorodichloridite is studied. Some phosphorus-containing linear systems, the phosphamacrocycle precursors, are synthesized. The possibility of synthesis of phosphamacrocyclic systems based on 1,4-bis(hydroxymethyl)benzene is considered; it was shown that this compound does not tend to form macrocycles.
• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.
• Phosphomacrocyclic systems based on 2,2′-dihydroxy-1,1′-dinaphtylmethane
  作者：P. V. Slitikov、E. N. Rasadkina、Ya. A. Korunova、L. K. Vasyanina、E. E. Nifant’ev

  DOI：10.1134/s1070363210050099

  日期：2010.5

  For the first time phosphomacrocyclic systems were synthesized based on 2,2'-dihydroxy-1,1'-dinaphthylmethane, other aromatic diols, and phosphorous hexaethyltriamide. Spontaneous transformation of the obtained macrocycles into the more stable 1,3,2-dioxaphosphacyn and cyclobisamidophosphite was established.
• Nifant'ev, E. E.; Rasadkina, E. N.; Yankovich, I. V., Russian Journal of General Chemistry, 1999, vol. 69, # 1, p. 32 - 38
  作者：Nifant'ev, E. E.、Rasadkina, E. N.、Yankovich, I. V.、Vasyanina, L. K.、Bel'skii, V. K.、Stash, A. I.

  DOI：——

  日期：——
• Synthesis of Penta- and Hexa-<i>m</i>-Phenylenecyclophosphites and Thiophosphates
  作者：Eduard E. Nifantyev、Elena N. Rasadkina、Inna V. Yankovich、Larisa K. Vasyanina

  DOI：10.1080/10426500008076340

  日期：2000.2

  New representatives of an original crown ether class-penta- and hexaresorcinolamidophosphites (7a,b and 13a,b)-were synthesized using the molecular assemblage technique. Their thio derivatives (8a,b and 14a,b) were obtained, as well as the rhodium (I) complex of hexaphosphite 13b (16). Macrocycle 15 containing both P3+ and P5+ was synthesized, H-1 and P-31 NMR spectroscopy data suggested the higher conformational flexibility of phosphite macrocycles.