(C6H5)2Sn(cyclo-C6H11)2 | 20204-07-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (C6H5)2Sn(cyclo-C6H11)2
• 英文别名: dicyclohexyl-diphenyl stannane；Dicyclohexyl-diphenyl-stannan；Dicyclohexyl-diphenyl-zinn；dicyclohexyl-di(phenyl)tin；Dicyclohexyl(diphenyl)stannane
• CAS: 20204-07-3
• 化学式: C₂₄H₃₂Sn
• 分子量: 439.228
• InChiKey: PXQGTURWBNIMIM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.92
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (C6H5)2Sn(cyclo-C6H11)2 以 氨 为溶剂， 生成 K₂({(cyclo-C₆H₁₁)2Sn(NH₂)2}NH)
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.6, page 57 - 68

  摘要：

  DOI：
• 作为产物：
  描述：

  (C6H5)2Sn(C6H4-p-CH2CHCH2)2 以 四氢呋喃 为溶剂， 生成 (C6H5)2Sn(cyclo-C6H11)2
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.6, page 57 - 68

  摘要：

  DOI：

文献信息

• Organotin compounds and pesticides containing them
  申请人：Shionogi & Co., Ltd.

  公开号：US04774235A1

  公开（公告）日：1988-09-27

  A compound of the formula: ##STR1## in which R.sup.1 represents alkyl, cycloalkyl or aralkyl, R* represents fluorophenyl or trifluoromethylphenyl when R.sup.1 is alkyl; R* represents dichlorophenyl, neopentyl, trimethylsilylmethyl, dimethylphenylsilylmethyl or a group of the formula: ##STR2## wherein R.sup.2 represents halogen, trifluoromethyl, lower alkyl or lower alkoxy when R.sup.1 is cycloalkyl; or R* represents 2-thienyl, 3-thienyl, neopentyl, trimethylsilylmethyl, imethylphenylsilylmethyl or a group of the formula: ##STR3## wherein R.sup.3, R.sup.4 and R.sup.5 independently represent hydrogen, halogen, trifluoromethyl, lower alkyl or lower alkoxy when R.sup.1 is aralkyl, m represents 1 or 2, and X represents halogen, imidazolyl, triazolyl, phenylthio or a radical selected from the group consisting of: ##STR4## wherein R.sup.6 represents alkyl, R.sup.7 and R.sup.8 independently represent lower alkyl and R.sup.9 and R.sup.10 independently represent hydrogen or lower alkyl when m is 1; or they independently represent oxygen, sulfur or a radical selected from: ##STR5## A process for preparing the compound (I) and a pesticidal composition containing the compound (I) are also provided.

  一种化合物的分子式：##STR1## 其中，当R.sup.1代表烷基，环烷基或芳基烷基时，R*代表氟苯基或三氟甲基苯基；当R.sup.1代表环烷基时，R*代表二氯苯基、新戊基、三甲基硅基甲基、二甲基苯基硅基甲基或式子：##STR2## 其中，R.sup.2代表卤素、三氟甲基、低烷基或低烷氧基；当R.sup.1代表芳基烷基时，R*代表2-噻吩基、3-噻吩基、新戊基、三甲基硅基甲基、二甲基苯基硅基甲基或式子：##STR3## 其中，R.sup.3、R.sup.4和R.sup.5独立地代表氢、卤素、三氟甲基、低烷基或低烷氧基，m代表1或2，X代表卤素、咪唑基、三唑基、苯硫基或从以下组成的基团中选择的基团：##STR4## 其中，R.sup.6代表烷基，R.sup.7和R.sup.8独立地代表低烷基，R.sup.9和R.sup.10独立地代表氢或低烷基，当m为1时；或它们独立地代表氧、硫或从以下选择的基团中选择的基团：##STR5## 还提供了制备化合物(I)的方法和含有化合物(I)的杀虫剂组合物。
• Khmaruk, A. M.; Povolotskii, M. I.; Oleinik, V. A., Journal of general chemistry of the USSR, 1986, vol. 56, p. 2205 - 2211
  作者：Khmaruk, A. M.、Povolotskii, M. I.、Oleinik, V. A.、Pinchuk, A. M.

  DOI：——

  日期：——
• Cycloalkyl- and Secondary Alkyltin Compounds and Their Cleavage by Iodine in Benzene Solution
  作者：DIETMAR SEYFERTH

  DOI：10.1021/jo01363a017

  日期：1957.12.1
• Rubinchik, G. F.; Manulkin, Z. M., Zhurnal Obshchei Khimii, 1970, vol. 40, p. 123 - 126
  作者：Rubinchik, G. F.、Manulkin, Z. M.

  DOI：——

  日期：——
• Convenient preparation of hindered dialkyltin(IV) derivatives
  作者：Xianqi Kong、T. Bruce Grindley、Pradip K. Bakshi、T. Stanley Cameron

  DOI：10.1021/om00036a030

  日期：1993.12

  Diphenyltin dichloride was reacted with excess Grignard reagent to give dialkyldiphenyltin derivatives, R2Ph2Sn (R2 = 2 neopentyl, 2 trimethylsilyl, 2 neohexyl, 2 cyclohexyl, hexamethylene), in excellent yield when R is hindered but in lower yield when a ring is formed. Heating these compounds with chloroacetic acid cleaved the two phenyl groups in excellent yield to give crystalline bis(chloroacetates). The dialkyltin(IV) bis(chloroacetates) were converted to oxides by reaction with sodium hydroxide. The crystal structure of hexamethylenetin bis(chloroacetate) (R = R(w) = 0.0241) demonstrated that it was a monomer with a C-Sn-C angle of 122.2(3)-degrees having hexacoordinate tin bonded to anisobidentate chloroacetate groups. C-Sn-C bond angles for all compounds in solution were obtained from 1J(119Sn,13C) values. Literature Karplus-type equations for 3J(119Sn,13C) values in trimethyltin derivatives apply approximately to dialkyldiphenyltin derivatives but not to dialkyltin(IV) bis(chloroacetates).