4,5-di(vinyloxymethyl)-1-methylcyclohexene oxide | 1060769-97-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: 4,5-di(vinyloxymethyl)-1-methylcyclohexene oxide
• 英文别名: 3,4-bis(ethenoxymethyl)-1-methyl-7-oxabicyclo[4.1.0]heptane
• CAS: 1060769-97-2
• 化学式: C₁₃H₂₀O₃
• 分子量: 224.3
• InChiKey: WXPPMKCUZAWUOL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  31
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  乙酸乙烯酯 、 4,5-di(hydroxymethyl)-1-methylcyclohexene oxide 在 bis(1,5-cyclooctadiene)diiridium(I) dichloride sodium carbonate 、 丙酸 作用下， 以 甲苯 为溶剂， 以80%的产率得到4,5-di(vinyloxymethyl)-1-methylcyclohexene oxide
  参考文献：
  名称：

  Vinyl ether compounds and polymerizable compositions

  摘要：

  揭示了一种含氧杂环乙烯醚化合物，包括一个或多个芳香或非芳香碳环和/或两个或更多个乙烯醚结构，例如Formula公式的化合物： 其中环Z1为非芳香碳环；Ra为Formula公式的乙烯基： 其中R1、R2和R3中的每一个是氢或C1-C4烷基；Wa为单键或具有(m+1)价的有机基团；X1为例如烃基；"m"和"q"各自为1或2；"p"为0至5。还揭示了一种含脂环氧基的乙烯醚化合物，其Formula为： 其中环Z2为非芳香碳环；Rb为Formula公式的乙烯基： 其中R4、R5和R6中的每一个为氢或C1-C4烷基；Wb为单键或具有(r+1)价的有机基团；Rc和Rd为氢或烷基；"r"和"s"为1或2。

  公开号：

  EP1972622A3

文献信息

• CATIONICALLY POLYMERIZABLE RESIN COMPOSITION AND CURED OBJECT OBTAINED THEREFROM
  申请人：Funaki Yoshinori

  公开号：US20120077946A1

  公开（公告）日：2012-03-29

  Disclosed is a cationically polymerizable resin composition which includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-containing vinyl ether compound (B); and an oligomer or polymer (C) having a molecular weight of 500 or more, being liquid at 0° C., and containing at least one of structures represented by following Formulae (1a) to (1f), wherein R x represents hydrogen atom or methyl group; R 1 to R 3 each independently represent a hydrocarbon group having 1 to 5 carbon atoms; “a” is an integer of from 0 to 5; and “b” is 1 or 2. This cationically polymerizable resin composition has a low viscosity, is easy to work, cures extremely rapidly upon irradiation with light, and can give a cured object excellent in flexibility, thermal stability, and bendability after heat treatment.

  本发明公开了一种阳离子聚合树脂组合物，包括含氧杂环环氧基乙烯醚化合物（A）和/或含脂环氧基乙烯醚化合物（B）；以及具有分子量为500或更高、在0℃下为液态，并含有下式（1a）至（1f）所表示的结构中至少一种的寡聚物或聚合物（C），其中Rx代表氢原子或甲基基团；R1至R3各自独立地表示具有1至5个碳原子的烃基；“a”为0至5的整数；“b”为1或2。该阳离子聚合树脂组合物具有低粘度、易于加工，经光辐照后固化极快，经热处理后可以给出具有优异的柔性、热稳定性和可弯曲性的固化物。
• CATION-POLYMERIZABLE RESIN COMPOSITION AND CURED PRODUCT THEREOF
  申请人：Yoshida Tsukasa

  公开号：US20120027342A1

  公开（公告）日：2012-02-02

  Provided is a cationically polymerizable resin composition which has a low viscosity, is easy to work, and is extremely rapidly cured upon irradiation with light to give a cured product excellent in optical transparency, flexibility, thermal stability, and post-heating bendability. The cationically polymerizable resin composition includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-group-containing vinyl ether compound (B); an oligomer or polymer (C) containing, in the molecule, at least one selected from oxetane group, epoxy group, hydroxyl group, vinyl ether group, and an aliphatic or alicyclic unsaturated hydrocarbon group and having a molecular weight of 500 or more; and an oxetane compound (D) containing no vinyl ether group and having 6 or more carbon atoms.

  提供了一种阳离子聚合树脂组合物，具有低粘度、易于操作，并在光照辐射下极快地固化，形成的固化产物具有优异的光学透明度、柔韧性、热稳定性和后热弯曲性。该阳离子聚合树脂组合物包括含氧杂环环氧基乙烯醚化合物(A)和/或含脂环氧基团的乙烯醚化合物(B)；分子中含有至少一种氧杂环基、环氧基、羟基、乙烯基醚基和脂肪或脂环烯烃基且分子量为500或更高的低聚物或聚合物(C)；以及不含乙烯基醚基且碳原子数为6或更多的氧杂环化合物(D)。
• Epoxycyclohexane vinyl ether compounds and their use in polymerizable compositions
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2233475A1

  公开（公告）日：2010-09-29

  Disclosed is an alicyclic epoxy-containing vinyl ether compound represented by following Formula (3c) or (3d): wherein Rb represents a substituted or unsubstituted vinyl group represented by following Formula (4): wherein each of R4, R5 and R6 independently represents a hydrogen atom or an alkyl group containing one to four carbon atoms; These vinyl ether compunds are useful as polymerizable compounds that will polymerize or cure by the application of light and/or heat.

  本发明公开了由下式（3c）或（3d）表示的含脂环族环氧乙烯基醚化合物： 其中 Rb 代表下式（4）所代表的取代或未取代的乙烯基： 其中 R4、R5 和 R6 各自独立地代表氢原子或含有一至四个碳原子的烷基； 这些乙烯基醚化合物可用作可聚合化合物，在光和/或热的作用下聚合或固化。
• Oxetane-containing vinyl ether compounds and polymerizable compositions
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP2441761A1

  公开（公告）日：2012-04-18

  Disclosed is an oxetane-containing vinyl ether compound comprising: (a) at least one oxetane ring; and (b) two or more vinyl ether structures, per molecule, wherein the oxetane-containing vinyl ether compound is represented by the following Formula (1b): wherein Ra respresents a substituted or unsubstitued vinyl group represented by the following Formula (2):

  公开了一种含氧杂环丁基醚化合物，该化合物包括 (a) 至少一个氧杂环；和 (b) 两个或多个乙烯基醚结构、 每个分子 其中含氧乙烷的乙烯基醚化合物由下式（1b）表示： 其中 Ra 代表由下式（2）表示的取代或未取代的乙烯基：
• US7985866B2
  申请人：——

  公开号：US7985866B2

  公开（公告）日：2011-07-26