3-acetoxy-2-hydroxy-propylmethacrylate | 29601-69-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油脂
• 英文名称: 3-acetoxy-2-hydroxy-propylmethacrylate
• 英文别名: 3-(Acetyloxy)-2-hydroxypropyl 2-methylprop-2-enoate；(3-acetyloxy-2-hydroxypropyl) 2-methylprop-2-enoate
• CAS: 29601-69-2
• 化学式: C₉H₁₄O₅
• 分子量: 202.207
• InChiKey: GGJSOZXRIXSEFY-UHFFFAOYSA-N

物化性质

• 沸点：
  120 °C(Press: 0.20 Torr)
• 密度：
  1.143±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  14
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  72.8
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  甲基丙烯酸缩水甘油酯 、 sodium acetate 在 Fe₃O₄(at)SiO₂/N,N-bis(triethoxysilylpropyl)-4,4-bipyridinium dichloride nanocomposite 作用下， 以 水 为溶剂， 反应 0.83h， 以78%的产率得到3-acetoxy-2-hydroxy-propylmethacrylate
  参考文献：
  名称：

  Synthesis and characterization of a novel Fe3O4@SiO2/bipyridinium dichloride nanocomposite and its application as a magnetic and recyclable phase-transfer catalyst in the preparation of β-azidoalcohols, β-cyanohydrins, and β-acetoxy alcohols

  摘要：

  摘要 β-叠氮醇、β-氰醇和 β-乙酰氧基醇在作为新型磁性可回收相转移催化剂（PTC）的 Fe3O4@SiO2/ 联吡啶纳米复合材料（Fe3O4@SiO2/BNC）存在下于水中合成。该催化剂通过傅立叶变换红外光谱、扫描电镜、XRD、VSM 和热重分析进行了表征。该方法具有多个优点，包括操作简便、具有优异的区域选择性、产率高、反应时间短、催化剂可回收、催化剂易于通过外部磁铁分离以及操作过程环保。

  DOI：

  10.1016/j.crci.2015.06.019

文献信息

• Reactivity of Some Carboxylic Acids in Reactions with Some Epoxides in the Presence Chromium (III) Ethanoate
  作者：Agnieszka Bukowska、Wiktor Bukowski

  DOI：10.1021/op010112q

  日期：2002.5.1

  Reactivities have been compared of acetic, acrylic, and methacrylic acid in reactions with epichlorohydrin, phenylglycidyl ether, glycidyl acetate, and glycidyl methacrylate carried in the presence of chromium (III) ethanoate. The acid reactivities changed differently with respect to the oxirane series. The effect of solvents on the reactions of acids with epichlorohydrin has also been observed.

  在乙酸铬 (III) 存在下，比较了乙酸、丙烯酸和甲基丙烯酸在与环氧氯丙烷、苯基缩水甘油醚、乙酸缩水甘油酯和甲基丙烯酸缩水甘油酯的反应中的反应性。相对于环氧乙烷系列，酸反应性变化不同。还观察到溶剂对酸与表氯醇反应的影响。
• Chloride-free cationic polymers using acetate anions
  申请人：Rohm and Haas Company

  公开号：US11230616B2

  公开（公告）日：2022-01-25

  A composition contains ethylenically unsaturated quaternary ammonium cations with acetate counterions, where each of the ethylenically unsaturated ammonium cations contain only one non-aromatic carbon-carbon double bond and the composition contains less than one mole-percent chloride relative to quaternary ammonium cations can be polymerized to form a cationic polymer acetate.

  含有乙烯基不饱和季铵盐阳离子和醋酸盐反离子的组合物，其中每个乙烯基不饱和铵盐阳离子只含有一个非芳香族碳碳双键，并且相对于季铵盐阳离子，组合物中氯化物的含量小于 1 摩尔百分数，可以聚合形成阳离子聚合物醋酸盐。
• Blends of polyolefins with functionalized polybutadienes
  申请人：BRASKEM AMERICA, INC.

  公开号：US11518871B2

  公开（公告）日：2022-12-06

  This invention relates to a polyolefin blend composition comprising a polyolefin base polymer component and a functionalized polybutadiene component. The polyolefin blend exhibits both i) an increased melt flow and ii) an increased impact toughness and/or melt elasticity, as compared to the same composition without the functionalized polybutadiene. This invention also relates to a method of increasing the melt flow of a polyolefin and simultaneously increasing the impact toughness and/or the melt elasticity of the polyolefin by blending a polyolefin base polymer component and a functionalized polybutadiene component.

  本发明涉及一种聚烯烃共混组合物，该组合物由聚烯烃基础聚合物组分和官能化聚丁二烯组分组成。与不含官能化聚丁二烯的相同组合物相比，该聚烯烃混合物具有 i) 增加的熔体流动性和 ii) 增加的冲击韧性和/或熔体弹性。本发明还涉及一种通过混合聚烯烃基础聚合物组分和官能化聚丁二烯组分来提高聚烯烃熔体流动性并同时提高聚烯烃冲击韧性和/或熔体弹性的方法。
• CHLORIDE-FREE CATIONIC POLYMERS USING ACETATE ANIONS
  申请人：Union Carbide Chemicals & Plastics Technology LLC

  公开号：EP3658663A1

  公开（公告）日：2020-06-03
• POLYAMIC ACID, POLYIMIDE, PHOTOSENSITIVE RESIN COMPOSITION COMPRISING THE SAME AND DRY FILM MANUFACTURED BY THE SAME
  申请人：LEE Kwang-Joo

  公开号：US20110200939A1

  公开（公告）日：2011-08-18

  The present invention relates to a polyamic acid or polyimide comprising a heat-polymerizable or photo-polymerizable functional group, a photosensitive resin composition comprising the polyamic acid or the polyimide, a photosensitive resin composition being capable of providing a cured film that can be used for patterning at a high resolution and that has an excellent developing property in an alkaline aqueous solution, flexibility, adhesion strength, resistance to welding heat, and pressure cooker test (PCT) resistance, and a dry film prepared from the composition.