3,4-oxybis(benzoic acid) | 62507-84-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3,4-oxybis(benzoic acid)
• 英文别名: 3,4′-oxybis(benzoic acid)；3,4'-oxydibenzoic acid；(3-Caroxy-phenyl)-(4-carboxy-phenyl)-aether；3,4'-Oxy-di-benzoesaeure；3,4'-dicarboxydiphenyl ether；3-(4-Carboxyphenoxy)benzoic acid
• CAS: 62507-84-0
• 化学式: C₁₄H₁₀O₅
• 分子量: 258.23
• InChiKey: CULWHZJWAKFHMK-UHFFFAOYSA-N

物化性质

• 熔点：
  281 °C
• 沸点：
  482.9±30.0 °C(Predicted)
• 密度：
  1.395±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  19
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  83.8
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  3,4-oxybis(benzoic acid) 在 N,N-二甲基甲酰胺 草酰氯 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 生成 3,4'-oxybis(benzoyl chloride)
  参考文献：
  名称：

  [EN] ANTIVIRAL COMPOUNDS
  [FR] COMPOSÉS ANTIVIRAUX

  摘要：

  这项发明涉及抗病毒化合物，含有这种化合物的组合物，包括给予这种化合物的治疗方法，以及用于制备这种化合物的过程和中间体。

  公开号：

  WO2010132601A1
• 作为产物：
  描述：

  间甲酚 在 potassium permanganate 作用下， 生成 3,4-oxybis(benzoic acid)
  参考文献：
  名称：

  Tomita, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1937, vol. 57, p. 391,396; dtsch. Ref. S. 76, 77

  摘要：

  DOI：

文献信息

• MODIFIER FOR AROMATIC POLYESTER AND AROMATIC POLYESTER RESIN COMPOSITION COMPRISING THE SAME
  申请人：TABATA Masayoshi

  公开号：US20110224343A1

  公开（公告）日：2011-09-15

  The present invention provides a modifier for aromatic polyesters which enhances the melt fluidity of aromatic polyesters without a significant decrease in the heat resistance of the aromatic polyesters, and an aromatic polyester resin composition including the modifier for aromatic polyesters. The present invention relates to a modifier for aromatic polyesters comprising polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof, and the modifier comprises a material having a structure composed of a first residue selected from the group consisting of divalent residues represented by Formula (I): —Ar—W 1 x —Ar— and by Formula (II): —Ar—, the first residues being bonded to two identical or different second residues selected from the group consisting of monovalent residues represented by Formula (III): and monovalent residues represented by Formula (IV): —O—C(O)—R 7 —.

  本发明提供了一种用于芳香族聚酯的改性剂，可以增强芳香族聚酯的熔融流动性，而不明显降低芳香族聚酯的耐热性，以及包括该改性剂的芳香族聚酯树脂组合物。本发明涉及一种用于芳香族聚酯的改性剂，包括多羟基酚残基和芳香族多羧酸、酸卤或其酸酐残基，该改性剂包括具有以下结构的材料：第一残基，选择自由式(I)所代表的二价残基：—Ar—W1x—Ar—和自由式(II)所代表的：—Ar—，第一残基与选择自由式(III)所代表的单价残基：和自由式(IV)所代表的单价残基：—O—C(O)—R7—的两个相同或不同的第二残基结合。
• A new three-dimensional cobalt(II) coordination polymer based on V-shaped 3,4′-oxydibenzoate: synthesis, crystal structure and magnetic properties
  作者：Wenlong Lan、Zhen Zhou、Fu-Chao Jia、Xiaoyun Hao、Yong Dou、Lu Yang、Hui Liu、Qingyun Liu、Daopeng Zhang

  DOI：10.1107/s2053229619008337

  日期：2019.7.1

  4′‐obb2− ligands, of which two function as monodentate ligands and the other as a bidentate ligand, and by two N atoms from bridging 4,4′‐bipy ligands, thereby forming a distorted octahedral CoN2O4 coordination geometry. Adjacent crystallographically equivalent CoII ions are bridged by the O atoms of 3,4′‐obb2− ligands, affording an eight‐membered Co2O4C2 ring which is further extended into a two‐dimensional

  一种新的配位聚合物（CP），即聚[（μ-4,4'-联吡啶）（μ 3 -3,4'- oxydibenzoato）钴（II）]，[CO（C 14 H ^ 8 ø 5）（C通过自组装Co（NO 3）2 ·6H 2制备10 H 8 N 2）] n或[Co（3,4'-obb）（4,4'-bipy）] n（1）O与很少使用的3,4'-氧二苯甲酸（3,4'-obbH 2）配体和4,4'-联吡啶（4,4'-联吡啶）在溶剂热条件下进行结构分析，并通过元素分析，红外光谱，单晶X射线晶体学和粉末X射线衍射（PXRD）进行了表征。X射线单晶衍射显示，每个Co II离子与来自三个3,4'-obb 2-配体的四个O原子六配位，其中两个用作单齿配体，另一个用作双齿配体，通过桥接4,4'-bipy配体形成两个N原子，从而形成扭曲的八面体CoN 2 O 4配位几何形状。相邻的晶体等效的Co II离子被3,4'-obb 2-配体的O原子桥接，提供了八元的Co2
• BISPHENOL HAVING FLUORENE SKELETON, METHOD FOR PRODUCING SAME, POLYARYLATE RESIN, (METH)ACRYLATE COMPOUND AND EPOXY RESIN WHICH ARE DERIVED FROM THE BISPHENOL
  申请人：TAOKA CHEMICAL CO., LTD.

  公开号：US20190055180A1

  公开（公告）日：2019-02-21

  Provided are a bisphenol represented by the general formula (1), a method for producing the bisphenol, and a polyarylate resin, a (meth)acrylate compound and an epoxy resin which are derived from the bisphenol. In the formula (1), R 1 to R 4 are the same or different, and each represent an alkyl group, an aryl group or a halogen atom, n 1 and n 2 are the same or different, and each represent an integer of 1 to 4, and k 1 to k 4 are the same or different, and each represent 0 or an integer of 1 to 4. When at least one of k 1 to k 4 is 2 or more, corresponding R 1 to R 4 may be the same or different.

  提供的是由通式（1）表示的双酚，一种生产双酚的方法，以及源自双酚的聚苯醚树脂、（甲基）丙烯酸酯化合物和环氧树脂。在式（1）中，R1至R4相同或不同，每个代表一个烷基、芳基或卤素原子，n1和n2相同或不同，每个代表1到4的整数，k1至k4相同或不同，每个代表0或1到4的整数。当k1至k4中至少有一个为2或更大时，相应的R1至R4可以相同或不同。
• Multifunctional crosslinking agent, crosslinked polymer, and method of making same
  申请人：The United States of America, as represented by the Secretary of the Air Force

  公开号：US10294255B1

  公开（公告）日：2019-05-21

  A multifunctional crosslinking agent, a crosslinked polymer, and a method of making the same are disclosed. The multifunctional crosslinking agent, which may be used to crosslink amine-terminated polyamides, polyimides, or poly(amide-imide)s, includes three or four anhydride functional groups. The multifunctional crosslinking agent may be defined by a general chemical formula (I): (Z—Ar—)n—W, wherein W represents an anhydride functional group that is directly or indirectly bonded to Ar; Ar represents an aryl group that is directly bonded to W; and n is equal to 3 when W is P═O or N, or n is equal to 4 when W is Si or a carbon moiety.

  本发明涉及一种多功能交联剂、交联聚合物及其制备方法。该多功能交联剂可用于交联胺基末端的聚酰胺、聚酰亚胺或聚酰亚胺酰类，包括三个或四个酸酐官能团。该多功能交联剂可由通式(I)表示：(Z—Ar—)n—W，其中W表示直接或间接与Ar键合的酸酐官能团；Ar表示直接与W键合的芳基团；当W为P═O或N时，n等于3；当W为Si或碳基团时，n等于4。
• Isostructural lanthanide-based metal–organic frameworks: structure, photoluminescence and magnetic properties
  作者：Li-Lin Luo、Xiang-Long Qu、Zheng Li、Xia Li、Hao-Ling Sun

  DOI：10.1039/c7dt04024e

  日期：——

  4′-oba ligands. These complexes feature high chemical stabilities in common solvents, boiling water, and acidic (pH = 3) and alkaline (pH = 13) solutions and high thermal stability even up to 400 °C. The photoluminescence and magnetic properties were studied. Especially, 2 shows bright red emission with a high luminescence efficiency of 40.51%. We mainly discuss the luminescence properties of 2 in

  在水热条件下，Ln（III）离子与3,4'-氧双（苯甲酸酯）（3,4'-oba），草酸酯（ ox）和1,10-菲咯啉（phen）。结构分析表明，它们是同构的3D开放框架，其公式为[Ln（3,4'-oba）（phen）（ox）0.5 ] n（Ln = Sm表示1，Eu表示2，Gd表示3，Tb为4，和Dy为5）和拓扑3 3 ·4 3 ·5 8 ·6}。在3D结构中，[LnO 6 N 2]单元被ox桥接以形成[Ln 2 ox]二聚体，然后进一步通过3,4'-oba配体连接。这些配合物在普通溶剂，沸水，酸性（pH = 3）和碱性（pH = 13）溶液中均具有很高的化学稳定性，甚至在高达400°C的温度下也具有很高的热稳定性。研究了光致发光和磁性。特别地，2显示出具有40.51％的高发光效率的鲜红色发射。我们主要讨论2在普通溶剂和无机离子中的发光特性。它显示了在普通溶剂中的发光稳定性以及在长激发波长（350