Phenyl-chlor-difluorsilan | 368-45-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyl-chlor-difluorsilan
• 英文别名: Phenyl(chloro)difluorosilane；chloro-difluoro-phenylsilane
• CAS: 368-45-6
• 化学式: C₆H₅ClF₂Si
• 分子量: 178.641
• InChiKey: YNVHMIVASYJIAB-UHFFFAOYSA-N

物化性质

• 沸点：
  59-63 °C(Press: 50 Torr)
• 密度：
  1.200 g/cm3(Temp: 27 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  2.01
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  三甲基硅乙酸酯 、 Phenyl-chlor-difluorsilan 以100%的产率得到PhSiF2OC(O)CH3
  参考文献：
  名称：

  Unusual transformations of the PhSiFCl group

  摘要：

  DOI：

  10.1134/s001250080909002x
• 作为产物：
  描述：

  苯基三氯硅烷 在 PbF₂ 作用下， 以 neat (no solvent) 为溶剂， 生成 Phenyl-chlor-difluorsilan
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 58, page 165 - 167

  摘要：

  DOI：

文献信息

• Phenyl(fluoro)dichlorosilane: A new synthon for the preparation of compounds containing chiral silicon atom
  作者：S. V. Basenko、M. G. Voronkov、L. E. Zelenkov、A. I. Albanov

  DOI：10.1134/s0012500811080015

  日期：2011.8
• Acetoxy(fluoro)(phenyl)silanes C6H5Si(OCOCH3) n F3−n
  作者：S. V. Basenko、M. G. Voronkov、L. E. Zelenkov、A. I. Albanov、I. A. Gebel’

  DOI：10.1134/s1070363209010319

  日期：2009.1
• Phenyl(acyloxy)fluorosilanes C6H5Si(OCOR) n F3−n (n = 1, 2) and phenyl(acyloxy)fluorochlorosilanes C6H5Si(OCOR)FCl
  作者：S. V. Basenko、L. E. Zelenkov、M. G. Voronkov、A. I. Albanov、D. A. Shabalin

  DOI：10.1134/s1070363211120103

  日期：2011.12

  The method of synthesis of the hitherto unknown class of organosilicon compounds, phenyl(acyloxy)fluorosilanes C6H5Si(OCOR) (n) F3-n (n = 1, 2) and phenyl(acyloxy)fluorochlorosilanes C6H5Si(OCOR) FCl in up to 91% yield has been developed based on the reaction of phenyl(fluoro)chlorosilanes C6H5SiCl (n) F3-n (n = 1, 2) with trimethylsilyl esters of carboxylic acids Me3SiOC(O)R [R = H, CH3, CF3, CCl3, ClCH2, BrCH2, CH2=CHCH3, CH2=CHPh, CH(CH3)=CH2, Ph].
• Phenyl(fluoro)chlorodisiloxanes
  作者：S. V. Basenko、L. E. Zelenkov、M. G. Voronkov、A. I. Albanov

  DOI：10.1134/s107036321002009x

  日期：2010.2

  Cohydrolysis of phenyltrichlorosilane with phenyl(fluoro)dichloro- and phenyl(difluoro)-chlorosilanes and thermolysis of the formed siloxanes leading to the formation of phenyl(difluoro)chlorosilane are studied. The scheme of thermal decomposition of disiloxanes possessing fluorine atoms in the 1,3 positions is suggested. The scheme is based on the intermediate formation of an active four-membered cyclic complex closed by the fluorine bridge between the silicon atoms. In agreement with the scheme, no thermolysis of 1,3-diphenyl-1-fluoro-1,3,3-trichlorodisiloxane is observed under the studied conditions.
• 2-Halo-2-organyl-4H-benzo[d][1,3,2]dioxasilin-4-ones
  作者：Sergey V. Basenko、Lev E. Zelenkov

  DOI：10.1007/s10593-015-1698-1

  日期：2015.3

  [GRAPHICS]Original method has been developed for the preparation of previously unknown cyclic organosilicon esters of salicylic acid, containing halogen-silicon bonds. This method is based on the reaction of trimethylsilyl ester of 2-(trimethylsiloxy) benzoic acid with organylhalosilanes (RRSiXY)-Si-1 under mild conditions, where R, R-1 = Cl, Me, CH=CH2, Ph; X, Y = Cl, F.