3-But-3-enylsulfonylpent-4-enylbenzene | 1101195-06-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-But-3-enylsulfonylpent-4-enylbenzene
• 英文别名: 3-but-3-enylsulfonylpent-4-enylbenzene
• CAS: 1101195-06-5
• 化学式: C₁₅H₂₀O₂S
• 分子量: 264.389
• InChiKey: XFYPWTUDWFEYOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  18
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  42.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-But-3-enylsulfonylpent-4-enylbenzene 在 PQS-attached Grubbs-Hoveyda-1 metathesis catalyst 作用下， 以 水 为溶剂， 反应 3.0h， 以94%的产率得到6-phenethyl-1,1-dioxo-3,6-dihydro-2H-thiopyran
  参考文献：
  名称：

  PQS: A New Platform for Micellar Catalysis. RCM Reactions in Water, with Catalyst Recycling

  摘要：

  The first "designer" surfactant containing a covalently bound ruthenium catalyst is reported. This species dissolves freely in water, forming nanomicelles in which ring-closing metathesis reactions on water-insoluble dienic substrates can occur in pure water at room temperature. It can also be recycled continuously without reaction workup.

  DOI：

  10.1021/ol8027829
• 作为产物：
  描述：

  3-But-3-enylsulfanylpent-4-enylbenzene 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以49%的产率得到3-But-3-enylsulfonylpent-4-enylbenzene
  参考文献：
  名称：

  PQS: A New Platform for Micellar Catalysis. RCM Reactions in Water, with Catalyst Recycling

  摘要：

  The first "designer" surfactant containing a covalently bound ruthenium catalyst is reported. This species dissolves freely in water, forming nanomicelles in which ring-closing metathesis reactions on water-insoluble dienic substrates can occur in pure water at room temperature. It can also be recycled continuously without reaction workup.

  DOI：

  10.1021/ol8027829

文献信息

• [EN] WATER SOLUBLE OLEFIN METATHESIS<br/>[FR] MÉTATHÈSE D'OLÉFINES HYDROSOLUBLES
  申请人：UNIV CALIFORNIA

  公开号：WO2009009597A1

  公开（公告）日：2009-01-15

  This invention provides a composition comprising (a) a catalyst; and (b) a solubilizing agent, wherein the catalyst is utilized in a metathesis reaction.
• PQS: A New Platform for Micellar Catalysis. RCM Reactions in Water, with Catalyst Recycling
  作者：Bruce H. Lipshutz、Subir Ghorai

  DOI：10.1021/ol8027829

  日期：2009.2.5

  The first "designer" surfactant containing a covalently bound ruthenium catalyst is reported. This species dissolves freely in water, forming nanomicelles in which ring-closing metathesis reactions on water-insoluble dienic substrates can occur in pure water at room temperature. It can also be recycled continuously without reaction workup.