N-4-aminophenyl-N',N''-diphenyl-1,3,5-triazine-2,4,6-triamine | 313485-52-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-4-aminophenyl-N',N''-diphenyl-1,3,5-triazine-2,4,6-triamine
• 英文别名: 2-N-(4-aminophenyl)-4-N,6-N-diphenyl-1,3,5-triazine-2,4,6-triamine
• CAS: 313485-52-8
• 化学式: C₂₁H₁₉N₇
• 分子量: 369.429
• InChiKey: GUGWDAABOJHNAJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  28
• 可旋转键数：
  6
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  101
• 氢给体数：
  4
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  N-4-aminophenyl-N',N''-diphenyl-1,3,5-triazine-2,4,6-triamine 、 6-氯-N,N'-二苯基-[1,3,5]三嗪-2,4-二胺 在 N,N-二异丙基乙胺 作用下， 以 二甲基亚砜 为溶剂， 170.0 ℃ 、101.33 kPa 条件下， 反应 0.25h， 以97%的产率得到N,N'-bis[4,6-bis(phenylamino)-1,3,5-triazin-2-yl]-p-phenylenediamine
  参考文献：
  名称：

  Microwave-Assisted Selective Synthesis of Mono- and Bistriazines with π-Conjugated Spacers and Study of the Optoelectronic Properties

  摘要：

  A series of mono- and bistriazine derivatives were selectively prepared in high yields using microwave irradiation. Donor substituents were attached on the triazine ring, including pyrazolyl-substituted anilines and o-, m-, and p-phenylenediamine as pi-conjugated spacers. This method was used to build sigma-pi-sigma-A-sigma-D systems for monotriazines and D-sigma-A-sigma-pi-sigma-A-sigma-D systems for bistriazines. A study of the optoelectronic properties was performed by UV-vis and fluorescence spectroscopy and cyclic voltammetry. The monotriazines do not show any emission, but the bistriazines are blue emitters and show an interesting solvatochromic effect with large Stokes shifts of more than 10 000 cm(-1) in some cases and quantum yields up to 23%. The optoelectronic properties depend on the conjugation and the position and donor character of the substituents and spacers. Cyclic voltammetry was used to determine the energy levels (HOMO and LUMO) in the bistriazines. An increase in the energy of the HOMO and a decrease in the energy of the LUMO were observed upon extending the conjugation. The title compounds showed interesting properties for use in optoelectronic devices, especially as blue emitters.

  DOI：

  10.1021/jo500480r
• 作为产物：
  描述：

  6-氯-N,N'-二苯基-[1,3,5]三嗪-2,4-二胺 、 对苯二胺 在 N,N-二异丙基乙胺 作用下， 以 二甲基亚砜 为溶剂， 140.0 ℃ 、101.33 kPa 条件下， 反应 0.17h， 以98%的产率得到N-4-aminophenyl-N',N''-diphenyl-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  Microwave-Assisted Selective Synthesis of Mono- and Bistriazines with π-Conjugated Spacers and Study of the Optoelectronic Properties

  摘要：

  A series of mono- and bistriazine derivatives were selectively prepared in high yields using microwave irradiation. Donor substituents were attached on the triazine ring, including pyrazolyl-substituted anilines and o-, m-, and p-phenylenediamine as pi-conjugated spacers. This method was used to build sigma-pi-sigma-A-sigma-D systems for monotriazines and D-sigma-A-sigma-pi-sigma-A-sigma-D systems for bistriazines. A study of the optoelectronic properties was performed by UV-vis and fluorescence spectroscopy and cyclic voltammetry. The monotriazines do not show any emission, but the bistriazines are blue emitters and show an interesting solvatochromic effect with large Stokes shifts of more than 10 000 cm(-1) in some cases and quantum yields up to 23%. The optoelectronic properties depend on the conjugation and the position and donor character of the substituents and spacers. Cyclic voltammetry was used to determine the energy levels (HOMO and LUMO) in the bistriazines. An increase in the energy of the HOMO and a decrease in the energy of the LUMO were observed upon extending the conjugation. The title compounds showed interesting properties for use in optoelectronic devices, especially as blue emitters.

  DOI：

  10.1021/jo500480r

文献信息

• Microwave-Assisted Selective Synthesis of Mono- and Bistriazines with π-Conjugated Spacers and Study of the Optoelectronic Properties
  作者：A. Ruiz-Carretero、O. Noguez、T. Herrera、J. R. Ramírez、A. Sánchez-Migallón、A. de la Hoz

  DOI：10.1021/jo500480r

  日期：2014.6.6

  A series of mono- and bistriazine derivatives were selectively prepared in high yields using microwave irradiation. Donor substituents were attached on the triazine ring, including pyrazolyl-substituted anilines and o-, m-, and p-phenylenediamine as pi-conjugated spacers. This method was used to build sigma-pi-sigma-A-sigma-D systems for monotriazines and D-sigma-A-sigma-pi-sigma-A-sigma-D systems for bistriazines. A study of the optoelectronic properties was performed by UV-vis and fluorescence spectroscopy and cyclic voltammetry. The monotriazines do not show any emission, but the bistriazines are blue emitters and show an interesting solvatochromic effect with large Stokes shifts of more than 10 000 cm(-1) in some cases and quantum yields up to 23%. The optoelectronic properties depend on the conjugation and the position and donor character of the substituents and spacers. Cyclic voltammetry was used to determine the energy levels (HOMO and LUMO) in the bistriazines. An increase in the energy of the HOMO and a decrease in the energy of the LUMO were observed upon extending the conjugation. The title compounds showed interesting properties for use in optoelectronic devices, especially as blue emitters.