1-Propyloxy-1-phenyl-propan | 71544-46-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Propyloxy-1-phenyl-propan
• 英文别名: 1-Phenyl-dipropyl-aether；1-Phenyldipropyl ether；1-propoxypropylbenzene
• CAS: 71544-46-2
• 化学式: C₁₂H₁₈O
• 分子量: 178.274
• InChiKey: ZGUPGYABYFUUOR-UHFFFAOYSA-N

物化性质

• 沸点：
  70-72 °C(Press: 4 Torr)
• 密度：
  0.9201 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  13
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  1-苯丙醇 以 乙醚 为溶剂， 生成 1-Propyloxy-1-phenyl-propan
  参考文献：
  名称：

  Mamedov,S. et al., Journal of general chemistry of the USSR, 1964, vol. 34, p. 2910 - 2913

  摘要：

  DOI：

文献信息

• Lanthanide(III) Triflate-Catalyzed Thermal- and Microwave-Assisted Synthesis of Benzyl Ethers from Benzyl Alcohols
  作者：Anthony Handlon、Yu Guo

  DOI：10.1055/s-2004-836063

  日期：——

  The lanthanide(III) trifluoromethanesulfonate-catalyzed condensation of benzyl alcohols with primary and secondary ­alcohols is described. This reaction proceeds readily with benzyl ­alcohols that have an alkyl or aryl substituent at the α-, ortho-, or para-position using microwave radiation or heating. The intra­molecular variant of this reaction leads to cyclic benzofurans.

  三氟甲磺酸镧(III)催化苄醇与一、二级醇的缩合反应被报道。该反应在微波辐射下或加热下可顺利进行，苄醇在α位、邻位或对位带有烷基或芳基取代基。该反应的分子内变体则生成苯并呋喃。
• ADDITION-FRAGMENTATION OLIGOMERS HAVING HIGH REFRACTIVE INDEX GROUPS
  申请人：3M INNOVATIVE PROPERTIES COMPANY

  公开号：US20160346170A1

  公开（公告）日：2016-12-01

  Addition-fragmentation oligomers of the general formula Z—B y -A-(B-A) x -B-A-B y —Z, where the A monomers units are derived from a diester or diacid, the B monomer units are derived from a difunctional monomer having functional groups co-reactive with the acid or ester groups of the A monomer, x+y is zero to 60, Z comprises an ethylenically unsaturated, polymerizable group, A monomers comprise a 1-methylene-3,3-dimethylpropyl group, and at least one B monomer unit comprises a high refractive index group.

  一般公式为Z-By-A-(B-A)x-B-A-By-Z的加成-断裂寡聚体，其中A单体单元来源于二酯或二酸，B单体单元来源于具有与A单体的酸或酯基反应的官能团的双官能单体，x+y为0至60，Z包括一个具有乙烯基不饱和度、可聚合的基团，A单体包括1-亚甲基-3,3-二甲基丙基基团，并且至少一个B单体单元包括高折射率基团。
• PROPYL-PHENYL-ETHER DERIVATIVE, AND MELANOGENESIS INHIBITOR, SKIN-LIGHTENING AGENT, ANTIMICROBIAL AGENT AND COSMETIC CONTAINING SAID PROPYL-PHENYL-ETHER DERIVATIVE
  申请人：SEIWA KASEI COMPANY, LIMITED

  公开号：US20150238401A1

  公开（公告）日：2015-08-27

  Provided is a compound that exhibits an excellent melanogenesis-inhibiting effect (skin-lightening effect), exhibits an excellent antimicrobial effect, excels in terms of temporal stability and the like, and is suitable for use as an ingredient of a cosmetic. Said compound is a propyl-phenyl-ether derivative compound comprising a propyl group that has a substituent such as a hydroxyl group and is bound to the hydroxyl group of a phenol group that has a substituent such as a tert-butyl group. A melanogenesis inhibitor, skin-lightening agent, and antimicrobial agent containing the aforementioned compound as an active ingredient are also provided, as is a cosmetic characterized by containing said compound.

  提供了一种化合物，具有出色的黑色素生成抑制作用（美白作用），表现出出色的抗菌作用，在时间稳定性等方面表现出色，并适用于作为化妆品成分。该化合物是一种丙基苯醚衍生物化合物，包括一个丙基基团，其具有类似于羟基的取代基，并与具有类似于叔丁基的取代基的酚基的羟基结合。还提供了一种含有上述化合物作为活性成分的黑色素生成抑制剂，美白剂和抗菌剂，以及一种含有该化合物的化妆品。
• Hardenable compositions, process to make a shaped article therefrom and dental appliance comprising it
  申请人：DENTSPLY INTERNATIONAL, INC.

  公开号：EP0014515A2

  公开（公告）日：1980-08-20

  Compositions hardenable by exposure to heat or electro-magnetic radiation are provided by blending from about 0% to about 50% by weight of an uncrosslinked polymer, from about 20% to about 66% of a polymerizable monomer capable of dissolving said polymer, from about 10% to about 70% of a crosslinked polymer in the form of discrete particles having average diameters of from 0.001 micron to about 500 microns and being swellable by said monomer, and from about 0.25%to about 27%of a crosslinking agent for said monomer. Such compositions exhibit superior chemical and physical characteristics when hardened and are suitable in a wide variety of applications as construction media. In accordance with a preferred form of the invention, a precursor blend is formed from a mixture comprising (A) from 13 to 52 weight percent of a crosslinked polymer of an ester of a C1 - C6 alkyl acrylic acid and a C1 - C20 alkyl or cycloalkyl alcohol, said crosslinked polymer being in the form of fine particles at least 50% by weight of which have average diameters less than 150 microns; (B) from 13 to 34 weight percent of an uncrosslinked polymerized ester of a C, - C6 alkyl acrylic acid and a C, - C20 alkyl or cycloalkyl alcohol having an average molecular weight of from 500,000 to 900,000 g/mole; (C) from 25 to 55%by weight of a polymerizable monomeric ester of a C1-C6 alkyl acrylic acid and a C1-C2 alkyl or cycloalkyl alcohol, which monomeric ester is capable of dissolving said uncrosslinked polymerized ester and of swelling, or interpenetrating, said crosslinked polymer particles; and (D) from 7% to 22 % by weight of a crosslinking agent for said polymerizable monomeric ester. Such precursor blends, after being aged for a time sufficient to insure that the crosslinked polymer particles have become substantially fully swollen with or interpenetrated by the mixture of monomeric ester and crosslinking agent, is especially suitable in the production of prosthetic dental appliances, such as, for example, prosthetic teeth.

  可通过受热或电磁辐射硬化的组合物是通过以下混合物提供的：按重量计，约 0% 至约 50% 的未交联聚合物、约 20% 至约 66% 的能溶解所述聚合物的可聚合单体、约 10% 至约 70% 的交联聚合物（以平均直径为 0.001 微米至约 500 微米且可被所述单体溶胀的离散颗粒形式存在），以及约 0.25% 至约 27% 的所述单体的交联剂。这种组合物硬化后具有优异的化学和物理特性，适合作为建筑介质广泛应用。根据本发明的一种优选形式，前驱体混合物由一种混合物形成，该混合物包括 (A) 13 至 52 重量百分比的 C1 - C6 烷基丙烯酸酯和 C1 - C20 烷基或环烷基醇的交联聚合物，所述交联聚合物呈细小颗粒状，其中至少 50%（按重量计）的平均直径小于 150 微米；(B) 13%至 34%的 C, - C6 烷基丙烯酸和 C, - C20 烷基或环烷基醇的未交联聚合酯，其平均分子量为 500,000 至 900,000 克/摩尔；(C) 25%至 55%(重量)的 C1-C6 烷基丙烯酸和 C1-C2 烷基或环烷基醇的可聚合单体酯，该单体酯能够溶解所述未交联聚合酯，并使所述交联聚合物颗粒溶胀或相互渗透；以及 (D) 7%至 22%(重量)的用于所述可聚合单体酯的交联剂。这种前体混合物在经过足够时间的老化，以确保交联聚合物颗粒已与单体酯和交联剂的混合物充分溶胀或相互渗透后，特别适用于生产修复牙科用具，例如，修复牙齿。
• PROPYL-PHENYL-ETHER DERIVATIVE AND MELANOGENESIS INHIBITOR, SKIN-LIGHTENING AGENT, ANTIMICROBIAL AGENT, AND COSMETIC CONTAINING SAID PROPYL-PHENYL-ETHER DERIVATIVE
  申请人：Seiwa Kasei Company, Limited

  公开号：EP2915796A1

  公开（公告）日：2015-09-09

  Provided is a compound that exhibits an excellent melanogenesis-inhibiting effect (skin-lightening effect), exhibits an excellent antimicrobial effect, excels in terms of temporal stability and the like, and is suitable for use as an ingredient of a cosmetic. Said compound is a propyl-phenyl-ether derivative compound comprising a propyl group that has a substituent such as a hydroxyl group and is bound to the hydroxyl group of a phenol group that has a substituent such as a tert-butyl group. A melanogenesis inhibitor, skin-lightening agent, and antimicrobial agent containing the aforementioned compound as an active ingredient are also provided, as is a cosmetic characterized by containing said compound.

  本发明提供了一种化合物，该化合物具有出色的黑色素生成抑制效果（美白效果）、出色的抗菌效果、出色的时间稳定性等，适合用作化妆品成分。所述化合物是一种丙基苯基醚衍生物化合物，包括一个具有羟基等取代基的丙基，并与具有叔丁基等取代基的苯酚基的羟基结合。还提供了含有上述化合物作为活性成分的黑色素生成抑制剂、皮肤美白剂和抗菌剂，以及以含有上述化合物为特征的化妆品。