(E)-14-Phenyl-tetradec-13-enal | 133100-38-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-14-Phenyl-tetradec-13-enal
• 英文别名: (E)-14-phenyltetradec-13-enal
• CAS: 133100-38-6
• 化学式: C₂₀H₃₀O
• 分子量: 286.458
• InChiKey: MVQKVEGXCWSGES-FOWTUZBSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  21
• 可旋转键数：
  13
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-Phenyl-cyclotetradecanone 在 十二烷基三甲基氯化铵 作用下， 以 水 为溶剂， 以2.9%的产率得到(Z)-14-Phenyl-tetradec-13-enal
  参考文献：
  名称：

  Photochemistry of large-ring 2-phenylcycloalkanones in various environments. Intramolecular para-coupling products of acyl benzyl biradicals

  摘要：

  DOI：

  10.1021/jo00008a065

文献信息

• Novel silicon compounds and process for preparation thereof
  申请人：——

  公开号：US20040143081A1

  公开（公告）日：2004-07-22

  (1) An organic silicon compound represented by the following Formula (1): 1 (2) The organic silicon compound represented by Formula (1) is produced by reacting polysilsesquioxane, which is obtained by hydrolyzing a silane compound having three hydrolyzable groups and represented by the following Formula (2), with a monovalent alkaline metal hydroxide in an organic solvent, or by subjecting the silane compound having three hydrolyzable groups to hydrolysis and polycondensation in the presence of an organic solvent and an alkaline metal hydroxide: 2 In Formulas ( 1 ) and ( 2 ), R represents independently a hydrogen atom, a linear, branched, or partially or wholly cyclic alkyl group, a linear, branched, or partially or wholly cyclic alkenyl group, a substituted or non-substituted aryl group, a substituted or non-substituted arylalkyl group, or a substituted or non-substituted arylalkenyl group; these selected R's may be the same or different; M represents a monovalent alkaline metal; and X represents a hydrolyzable group. A novel organic silicon compound which has a group having a high reactivity and in which a structure is prescribed and a production process for the same are provided by the technical methods of the items ( 1 ) and ( 2 ) described above.

  (1) 下式(1)所代表的有机硅化合物： 1 (2) 式(1)所代表的有机硅化合物是通过将具有三个可水解基团并由下式(2)所代表 的硅烷化合物与一价碱金属氢氧化物在有机溶剂中进行水解反应，或将具有三个 可水解基团的硅烷化合物在有机溶剂和碱金属氢氧化物存在下进行水解和缩聚反应 而制得的： 2 在公式 ( 1 )和( 2 )中，R 独立地代表氢原子、直链、支链或部分或全部环状烷基、直链、支链或部 分或全部环状烯基、取代或非取代芳基、取代或非取代芳烷基或取代或非取代芳烯基； 这些选定的 R 可以相同或不同；M 代表一价碱金属；X 代表可水解基团。 本发明的技术方法提供了一种新型有机硅化合物，该化合物中的基团具有高反应活性，并规定了其结构及其生产工艺。 1 )和( 2 ) 的技术方法提供。
• US7291747B2
  申请人：——

  公开号：US7291747B2

  公开（公告）日：2007-11-06