1,4-Diamino-9,10-dioxo-9,10-dihydroanthracen-2-carbonsaeuremethylester | 60345-96-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4-Diamino-9,10-dioxo-9,10-dihydroanthracen-2-carbonsaeuremethylester
• 英文别名: 1,4-diaminoanthraquinone-2-carboxylic acid methyl ester；1,4-Diamino-anthraquinone-2-carboxylic acid methyl ester；methyl 1,4-diamino-9,10-dioxoanthracene-2-carboxylate
• CAS: 60345-96-2
• 化学式: C₁₆H₁₂N₂O₄
• 分子量: 296.282
• InChiKey: BAVVZBIXCSLNQU-UHFFFAOYSA-N

物化性质

• 沸点：
  596.1±50.0 °C(Predicted)
• 密度：
  1.470±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  22
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  113
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,4-Diamino-9,10-dioxo-9,10-dihydroanthracen-2-carbonsaeuremethylester 在 sodium azide 、 碳酸氢铵 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 34.0h， 生成 1,4-Diamino-9,10-dioxo-2-(2'H-tetrazol-5'-yl)-9,10-dihydroanthroanthracen-3-carbonitril
  参考文献：
  名称：

  黚死Dicyanierung DER 1,4- Diaminoanthrachinone UND模具ReaktivitätDER 1,4-二氨基-9,10- dihydroanthracen -2,3-二腈gegenübernucleophilen Reagenzien 3. Mitteilung黚Arylierungen UND Heterocyclisierungen冯Anthrachinonsystemen †

  摘要：

  1,4-二氨基蒽醌的重氰基化和1,4-二氨基-9,10-二氧代-9,10-二氢蒽-2,3-二碳腈对亲核试剂的反应性

  DOI：

  10.1002/hlca.19830660203
• 作为产物：
  描述：

  甲醇 、 4-硝基-1-氨基蒽醌-2-甲酸 生成 1,4-Diamino-9,10-dioxo-9,10-dihydroanthracen-2-carbonsaeuremethylester
  参考文献：
  名称：

  Imazeki, S.; Mukon, A.; Ozawa, T., Molecular Crystals and Liquid Crystals (1969-1991), 1989, vol. 170, p. 107 - 118

  摘要：

  DOI：

文献信息

• Anthraquinone dyes
  申请人：BASF Aktiengesellschaft

  公开号：US04181668A1

  公开（公告）日：1980-01-01

  Anthraquinone dyes of the formula ##STR1## where R is C.sub.1 -C.sub.10 -alkyl, C.sub.5 -C.sub.8 -cycloalkyl, alkoxyalkyl of a total of 3 to 11 carbon atoms, phenoxyalkyl, where alkyl is of 2 to 4 carbon atoms, or phenyl-C.sub.1 -C.sub.4 -alkyl. On synthetic fibers and blends thereof with cellulosic fibers, the dyes give brilliant clear blues. The dyes are particularly suitable for transfer printing onto synthetic fibers and give high color yields. The transfer prints obtained have excellent fastness characteristics.

  蒽醌染料的化学式为##STR1##其中R为C.sub.1 -C.sub.10 -烷基，C.sub.5 -C.sub.8 -环烷基，总碳原子数为3到11的烷氧基烷基，苯氧基烷基，其中烷基为2到4个碳原子，或苯基-C.sub.1 -C.sub.4 -烷基。在合成纤维和混纺纤维上，这些染料呈现出明亮清晰的蓝色。这些染料特别适用于在合成纤维上进行转移印花，并且具有高色彩产量。所得的转印品具有优异的色牢度特性。
• IMAGE FORMING METHOD
  申请人：Furukawa, Ken-ichi

  公开号：EP1302330A1

  公开（公告）日：2003-04-16

  A method for forming an image, comprising providing an ink jet receiving film comprising a resin made film or substrate having a resin layer on its surface and an ink jet receiving layer provided thereon, ink jet printing an image on the ink jet receiving layer with an ink containing a sublimating or volatile dye, heating the ink jet receiving layer having the printed image to allow the printed image to migrate to the resin made film or to the surface resin layer of the substrate, and then peeling off the ink jet receiving layer as a film layer. By the method of the present invention, a sharp full color image can be imparted using an ink jet printer on any desired film article having a resin layer on its surface in a state where the surface gloss is retained. Concerning film articles in a sheet state, a full color image of a predetermined size can be formed in a simple and inexpensive manner. This is because the operation of accurate registration between the transfer paper and film article that is indispensable in the conventional sublimating thermal transfer dyeing method is no longer employed.

  一种形成图像的方法，包括提供一种喷墨接收薄膜，该薄膜由表面具有树脂层的树脂制薄膜或基材组成，其上设有喷墨接收层；用含有升华染料或挥发性染料的墨水在喷墨接收层上喷墨打印图像；加热具有打印图像的喷墨接收层，使打印图像迁移到树脂制薄膜或基材的表面树脂层；然后将喷墨接收层作为薄膜层剥离。 通过本发明的方法，可以使用喷墨打印机在任何所需的表面有树脂层的薄膜制品上打印出清晰的全彩图像，并保持表面光泽。对于片状薄膜物品，可以用简单而廉价的方式形成预定尺寸的全彩图像。这是因为不再需要传统升华热转印染色方法中不可或缺的转印纸和薄膜制品之间的精确套准操作。
• Image formation
  申请人：——

  公开号：US20020149658A1

  公开（公告）日：2002-10-17

  A method for forming an image, comprising providing an ink jet receiving film comprising a resin made film or substrate having a resin layer on its surface and an ink jet receiving layer provided thereon, ink jet printing an image on the ink jet receiving layer with an ink containing a sublimating or volatile dye, heating the ink jet receiving layer having the printed image to allow the printed image to migrate to the resin made film or to the surface resin layer of the substrate, and then peeling off the ink jet receiving layer as a film layer. By the method of the present invention, a sharp full color image can be imparted using an ink jet printer on any desired film article having a resin layer on its surface in a state where the surface gloss is retained. Concerning film articles in a sheet state, a full color image of a predetermined size can be formed in a simple and inexpensive manner. This is because the operation of accurate registration between the transfer paper and film article that is indispensable in the conventional sublimating thermal transfer dyeing method is no longer employed.

  一种形成图像的方法，包括提供一种喷墨接收薄膜，该薄膜由表面具有树脂层的树脂制薄膜或基材组成，其上设有喷墨接收层；用含有升华染料或挥发性染料的墨水在喷墨接收层上喷墨打印图像；加热具有打印图像的喷墨接收层，使打印图像迁移到树脂制薄膜或基材的表面树脂层；然后将喷墨接收层作为薄膜层剥离。 通过本发明的方法，可以使用喷墨打印机在任何所需的表面有树脂层的薄膜制品上打印出清晰的全彩图像，并保持表面光泽。对于片状薄膜物品，可以用简单而廉价的方式形成预定尺寸的全彩图像。这是因为不再使用传统升华热转印染色法中不可或缺的转印纸和薄膜制品之间的精确套准操作。
• BE626676
  申请人：——

  公开号：——

  公开（公告）日：——
• ADAM, J. -M.;WINKLER, T., HELV. CHIM. ACTA, 1983, 66, N 2, 411-421
  作者：ADAM, J. -M.、WINKLER, T.

  DOI：——

  日期：——