3-imino-5,6-dibutoxy-3H-isoindol-1-ylamine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 英文名称: 3-imino-5,6-dibutoxy-3H-isoindol-1-ylamine
• 英文别名: 5,6-dibutoxy-3-iminoisoindol-1-amine
• 化学式: C₁₆H₂₃N₃O₂
• 分子量: 289.378
• InChiKey: WVPVOXHRMUMGKO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  21
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  80.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-imino-5,6-dibutoxy-3H-isoindol-1-ylamine 在 喹啉 、 四氯化硅 作用下， 反应 0.25h， 以78%的产率得到
  参考文献：
  名称：

  Improved Synthesis of Octaalkoxymetalphthalocyanines (MCl2, M = Si, Ge, Sn) Under Microwave Conditions

  摘要：

  DOI：

  10.1055/s-1999-3593
• 作为产物：
  描述：

  1,2-二溴-4,5-二丁氧基苯 在 氨 、 sodium 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 生成 3-imino-5,6-dibutoxy-3H-isoindol-1-ylamine
  参考文献：
  名称：

  Sauer, Thomas; Wegner, Gerhard, Molecular Crystals and Liquid Crystals (1969-1991), 1988, vol. 162, p. 97 - 118

  摘要：

  DOI：

文献信息

• A μ-oxo hetero dimer of silicon phthalocyanine and naphthalocyanine
  作者：Kazuaki Oniwa、Soji Shimizu、Yuta Shiina、Takamitsu Fukuda、Nagao Kobayashi

  DOI：10.1039/c3cc44490b

  日期：——

  A novel mu-oxo hetero dimer of silicon phthalocyanine and silicon naphthalocyanine was synthesized. Its unique optical properties, such as a single Q band, which is unusual for hetero dimer species, and solvatochromic behavior, were revealed to be better interpreted by taking interchromophore interactions into consideration.

  合成了一种新型的酞菁硅和萘酞菁的mu-oxo杂二聚体。通过考虑发色团之间的相互作用，可以更好地解释其独特的光学性质，例如异二聚体物种不常见的单个Q波段和溶剂变色行为。
• Haberroth, Klaus; Rack, Michael; Ruff, Detlef, Chemische Berichte, 1995, vol. 128, # 4, p. 417 - 422
  作者：Haberroth, Klaus、Rack, Michael、Ruff, Detlef、Hanack, Michael

  DOI：——

  日期：——
• Controlling the Dipole–Dipole Interactions between Terbium(III) Phthalocyaninato Triple-Decker Moieties through Spatial Control Using a Fused Phthalocyaninato Ligand
  作者：Takaumi Morita、Keiichi Katoh、Brian K. Breedlove、Masahiro Yamashita

  DOI：10.1021/ic4020459

  日期：2013.12.2

  Using a fused phthalocyaninato ligand to control the spatial arrangement of Tb-III moieties in Tb-III single-molecule magnets (SMMs), we could control the dipole-dipole interactions in the molecules and prepared the first tetranuclear Tb-III SMM complex. [Tb(obPc)(2)]Tb(Fused-Pc)Tb[Tb(obPc)(2)] (abbreviated as [Tb-4]; obPc = 2,3,9,10,16,17,23,24-octabutoxyphthalocyaninato, Fused-Pc = bis(7(2),8(2),12(2),13(2),17(2),18(2)-hexabutoxytribenzo[g,l,q]-5,10,15,20-tetraazaporphirino} [b,e]benzenato). In direct-current magnetic susceptibility measurements, ferromagnetic interactions among the four Tb3+ ions were observed. In [Tb-4], there are two kinds of magnetic dipole-dipole interactions. One is strong interactions in the triple-decker moieties, which dominate the magnetic relaxations, and the other is the weak one through the fused phthalocyaninato (Pc) ligand linking the two triple-decker complexes. In other words, [Tb-4] can be described as a weakly ferromagnetically coupled dimer of triple-decker Tb-2(obPc)(3) complexes with strong dipole dipole interactions in the triple-decker moieties and weak ones through the fused phthalocyaninato ligand linking the two triple-decker complexes. For [Tb-4], dual magnetic relaxation processes were observed similar to other dinuclear (TbPc)-Pc-III complexes. The relaxation processes are due to the anisotropic centers. This is clear evidence that the magnetic relaxation mechanism depends heavily on the dipole-dipole (f-f) interactions between the Tb3+ ions in the systems. Through a better understanding of the magnetic dipole-dipole interactions obtained in these studies, we have developed a new strategy for preparing Tb-III SMMs. Our work shows that the SMM properties can be fine-tuned by introducing weak intermolecular magnetic interactions in a controlled SMM spatial arrangement.
• Highly Fluorescent Self-Coordinated Phthalocyanine Dimers
  作者：Kazuya Kameyama、Mitsuhiko Morisue、Akiharu Satake、Yoshiaki Kobuke

  DOI：10.1002/anie.200501199

  日期：2005.7.25
• Utilisation de dérivés de la Di-imino-isoindoline ou de la 3-amino-isoindolone pour la teinture des fibres kératiniques et compositions de teinture les renfermant
  申请人：L'OREAL

  公开号：EP0847749B1

  公开（公告）日：1999-12-01