bis(η4-1,3-butadiene)(triethylphosphino)iron(II) | 103835-78-5

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: bis(η4-1,3-butadiene)(triethylphosphino)iron(II)
• 英文别名: bis(η4-s-cis-1,3-butadiene)(triethylphosphine)iron
• CAS: 103835-78-5
• 化学式: C₁₄H₂₇FeP
• 分子量: 282.189
• InChiKey: WPAZKNKZOZOGLF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (η4-1,3-butadiene)tris(triethylphosphine)iron(0) 以 四氢呋喃 为溶剂， 以40%的产率得到bis(η4-1,3-butadiene)(triethylphosphino)iron(II)
  参考文献：
  名称：

  Neue methoden zur herstellung von trialkylphosphan-alkadien-eisen(0)-komplexen

  摘要：

  DOI：

  10.1016/0022-328x(87)85057-x

文献信息

• The preparation of bis(η3-allyl)iron(II) complexes and their reactions with 1,3-dienes
  作者：B. Gabor、S. Holle、P.W. Jolly、R. Mynott

  DOI：10.1016/0022-328x(94)88046-8

  日期：1994.2

  The title compounds were prepared by treating Fe(PR(3))(2)Cl-2 or Fe(R(2)P(CH2)(n)PR(2))Cl-2 with allylmagnesium chloride. Some of them were also made by reaction of Fe(PR(3))(2)Cl-2 with isopropylmagnesium chloride, or with active-magnesium and allyl chloride, or by reaction between tris(eta(3)-allyl)iron and bis(dimethylphosphino)ethane. The new compounds were characterized by NMR spectroscopy and shown to be formed as a mixture of two isomers that differ in the mutual arrangement of the two allyl groups. The reactions of the bis(allyl)iron compounds with 1,3-dienes were studied: complexes containing eta(4)-1,3-C4H6, eta(4)-1-C3H5C4H5 or eta(5)-l-ethylcyclohexadienyl groups were isolated from the reaction with 1,3-butadiene. The reaction between (eta(3)-C3H5)(2)Fe((Pr2PC2H4PPr)-Pr-i-Pr-i(2)) and 1,3-cyclohexadiene gave (eta(5)-cyclohexadienyl)Fe((Pr2PC2H4PPr2)-Pr-i-Pr-i)H.
• η4,3-butadien-tris(triethylphosphan)eisen(0): Ein komplex zur fixierung von alkenen oder alkinen
  作者：Heinz Hoberg、Klaus Jenni

  DOI：10.1016/0022-328x(86)80049-3

  日期：1986.3