3-(4-aminophenoxy)phthalonitrile | 913700-93-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(4-aminophenoxy)phthalonitrile
• 英文别名: 4-Aminophenoxyphthalonitrile；3-(4-aminophenoxy)benzene-1,2-dicarbonitrile
• CAS: 913700-93-3
• 化学式: C₁₄H₉N₃O
• 分子量: 235.245
• InChiKey: WTSJLYWSCIPJNI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  82.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-(4-aminophenoxy)phthalonitrile 在 盐酸 、 sodium nitrite 作用下， 生成
  参考文献：
  名称：

  Honeycomb-patterned phthalocyanine films with photo-active antibacterial activities

  摘要：

  我们报告了利用呼吸图（BF）技术通过十二环氧偶氮锌酞菁（daZnPc）的自组装制造的蜂窝状酞菁（Pc）薄膜。这些超薄酞菁薄膜对大肠杆菌（E. coli）具有很强的光依赖性抗菌效果。

  DOI：

  10.1039/c3cc42085j
• 作为产物：
  描述：

  3-硝基邻苯二腈 、 对氨基苯酚 在 potassium carbonate 作用下， 以 二甲基亚砜 为溶剂， 反应 22.0h， 以98.7%的产率得到3-(4-aminophenoxy)phthalonitrile
  参考文献：
  名称：

  WO2006/117399

  摘要：

  公开号：

文献信息

• Colorant compounds
  申请人：Banning Jeffrey H.

  公开号：US20080146794A1

  公开（公告）日：2008-06-19

  Disclosed is a compound of the formula wherein M is atom or group of atoms capable of bonding to central cavity of phthalocyanine molecule, wherein axial ligands optionally can be attached to M, each R′ is a substituent, each n is 0, 1, 2, 3, or 4, each R″ is a substituent, each m is 0, 1, 2, or 3, each R is alkylene, arylene, arylalkylene, or alkylarylene, each X is —OH, —COOH, or wherein each Y and each Z is a direct bond, oxygen, or —NR 1 —, wherein R 1 is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, provided that Z and Y are not both direct bonds connected to a single C═O moiety at the same time, provided that when X is —COOH, R can also be a direct bond, and each R d is alkyl, aryl, arylalkyl, or alkylaryl.

  揭示了一个化合物的结构式，其中 M 是一个原子或原子团，能够与酞菁分子的中央空腔形成键合，其中轴向配体可以选择性地附着在 M 上，每个 R′ 是一个取代基，每个 n 是 0、1、2、3 或 4，每个 R″ 是一个取代基，每个 m 是 0、1、2 或 3，每个 R 是烷基、芳基、芳基烷基或烷基芳基，每个 X 是—OH、—COOH 或，其中每个 Y 和每个 Z 是直接键、氧或—NR1—，其中 R1 是氢、烷基、芳基、芳基烷基或烷基芳基，前提是 Z 和 Y 不同时是连接到单个 C═O 基团的直接键，前提是当 X 是—COOH 时，R 也可以是一个直接键，每个 Rd 是烷基、芳基、芳基烷基或烷基芳基。
• A comparative photophysicochemical study of mono substituted phthalocyanines grafted onto silica nanoparticles
  作者：Adedayo Fashina、Edith Antunes、Tebello Nyokong

  DOI：10.1142/s1088424614500138

  日期：2014.5

  In this study, we report on the covalent linking of carboxylic acid functionalized silica nanoparticles with zinc phthalocyanine mono-substituted non-peripherally and peripherally with either a 4-amino phenoxy (1, peripheral and 2, non-peripheral) or an amino group (3 peripheral). The grafting is achieved via the formation of an amide bond between the carboxylic acid of the silica nanoparticles and the amino group of the phthalocyanine complexes. The hybrid nanoparticles retained the amorphous nature of silica nanoparticles after conjugation. A slight decrease in fluorescence and a general improvement in triplet quantum yields compared to free Pcs were observed. Triplet lifetimes for 2- SiNPs and 3- SiNPs also improved when compared to the free phthalocyanine. The changes in singlet oxygen quantum yields upon conjugation were minimal.

  在本研究中，我们报告了羧酸官能化二氧化硅纳米粒子与单取代酞菁锌的非外围和外围 4-氨基苯氧基（1，外围和 2，非外围）或氨基（3，外围）的共价连接。接枝是通过在纳米二氧化硅的羧酸和酞菁复合物的氨基之间形成酰胺键来实现的。接枝后的混合纳米粒子保留了二氧化硅纳米粒子的无定形性质。与游离的 Pcs 相比，荧光略有下降，三重量子产率普遍提高。与游离酞菁相比，2- SiNPs 和 3- SiNPs 的三重寿命也有所改善。共轭后，单线态氧量子产率的变化很小。
• PHTHALOCYANINE DERIVATIVES, PROCESS FOR THEIR PREPARATION, PHARMACEUTICAL COMPOSITIONS CONTAINING THEM, AND THEIR USE
  申请人：L. MOLTENI & C. DEI FRATELLI ALITTI SOCIETA' DI ESERCIZIO S.P.A

  公开号：EP1883641A1

  公开（公告）日：2008-02-06
• COMPOSITION OF PHTHALONITRILE RESIN MATRIX FOR POLYMER COMPOSITE MATERIALS, METHOD FOR FABRICATION THEREOF, METHOD FOR MANUFACTURING OF POLYMER COMPOSITE MATERIAL, AND MATERIAL OBTAINED BY THIS METHOD
  申请人：Joint Stock Company

  公开号：EP3877447A1

  公开（公告）日：2021-09-15
• Phase change inks
  申请人：Banning Jeffrey H.

  公开号：US20080145559A1

  公开（公告）日：2008-06-19

  Phase change ink comprising carrier and colorant of formula wherein M is atom or group of atoms capable of bonding to central cavity of phthalocyanine molecule, wherein axial ligands optionally can be attached to M, each R′ is a substituent, each n is 0, 1, 2, 3, or 4, each R″ is a substituent, each m is 0, 1, 2, or 3, each R is alkylene, arylene, arylalkylene, or alkylarylene, each X is —OH, —COOH, or wherein each Y and each Z is a direct bond, oxygen, or —NR 1 —, wherein R 1 is hydrogen, alkyl, aryl, arylalkyl, or alkylaryl, provided that Z and Y are not both direct bonds connected to a single C═O moiety at the same time, provided that when X is —COOH, R can also be a direct bond, and each R d is alkyl, aryl, arylalkyl, or alkylaryl.