N,N'-dibenzyl-1,3-xylylenediamine | 25790-40-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-dibenzyl-1,3-xylylenediamine
• 英文别名: 1,3-bis[(N-benzyl)aminomethyl]benzene；1,3-bis-(benzylaminomethyl)benzene；N,N'-dibenzyl-m-xylylene diamine；N,N'-(1,3-phenylenebis(methylene))bis(1-phenylmethaneamine)；N,N'-Dibenzyl-m-xylylendiamin；α.α'-Bis-benzylamino-m-xylol；1,3-Bn-amb；N-[[3-[(benzylamino)methyl]phenyl]methyl]-1-phenylmethanamine
• CAS: 25790-40-3
• 化学式: C₂₂H₂₄N₂
• 分子量: 316.446
• InChiKey: OWQVCMBDPJHIRG-UHFFFAOYSA-N

物化性质

• 沸点：
  459.9±35.0 °C(Predicted)
• 密度：
  1.075±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-benzyl-N-[[3-[[benzyl-(4,6-dichloro-1,3,5-triazin-2-yl)amino]methyl]phenyl]methyl]-4,6-dichloro-1,3,5-triazin-2-amine 、 N,N'-dibenzyl-1,3-xylylenediamine 在 N,N-二异丙基乙胺 作用下， 以 丙酮 为溶剂， 反应 17.0h， 生成 2,10,16,24-Tetrabenzyl-13,27-dichloro-2,10,12,14,16,24,26,28,29,31-decazapentacyclo[23.3.1.14,8.111,15.118,22]dotriaconta-1(29),4(32),5,7,11(31),12,14,18,20,22(30),25,27-dodecaene
  参考文献：
  名称：

  杂杂杂螺[2]芳烃[2]三嗪的合成，结构和功能化：桥联元素调控的多功能构型和腔结构

  摘要：

  通过氰基卤化物，芳香族和脂肪族二醇以及二胺，在非常温和的反应条件下，通过一般且收率良好的片段偶联方法合成了许多homo [2]和homo [4]杂杯[2]芳烃[2]三嗪。虽然homo [2] tetraazacalix [2] arene [2] triazine提供了扭曲和捏合的1,2-交替构象异构体，但几乎所有的homo [2] heterocalix [2] arene [2] triazines固态均采用了不同的部分锥构象。同源[4]异杯[2]芳烃[2]三嗪产生的构象结构更加多样，包括部分锥，夹缩的部分锥，1，2-交替和扭曲的1，2-交替，具体取决于桥联部分的性质。在1的基础上1 H NMR谱图表明，均[2]和均[4]异杯[2]芳烃[2]三嗪是溶液中的通量大环，并且它们在不同温度下经历了快速的构象互换。在氯三嗪环上高效而直接的亲核芳族取代反应和钯催化的交叉偶联反应，以及在桥接氮原子

  DOI：

  10.1021/jo100571c
• 作为产物：
  描述：

  N,N'-(1,3-phenylenebismethylene)bisphthalimide 在 氢氧化钾 、 乙醇 、 镍 、 苯 作用下， 生成 N,N'-dibenzyl-1,3-xylylenediamine
  参考文献：
  名称：

  Window observers for linear systems

  摘要：

  Given a linear system (x) over dot = Ax + Bu with output y = Cx and a window function omega>(*) over bar * (t), i.e., For Allt, omega>(*) over bar * (t) is an element of {0,1}, and assuming that the window function is Lebesgue measurable, we refer to the following observer, (x) over cap = A (x) over cap + Bu + omega>(*) over bar * (t)LC(x - (x) over cap) as a window observer. The stability issue is treated in this paper. It is proven that for linear time-invariant systems, the window observer can be stabilized by an appropriate design under a very mild condition on the window functions, albeit for linear time-varying system, some regularity of the window functions is required to achieve observer designs with the asymptotic stability. The corresponding design methods are developed. An example is included to illustrate the possible applications.

  DOI：

  10.1155/s1024123x0000140x

文献信息

• 24- and 26-Membered Macrocyclic Diorganotin(IV) Bis-Dithiocarbamate Complexes with <i>N</i>,<i>N′</i>-Disubstituted 1,3- and 1,4-Bis(aminomethyl)benzene and 1,1′-Bis(aminomethyl)ferrocene as Spacer Groups
  作者：Ericka Santacruz-Juárez、Jorge Cruz-Huerta、Irán Fernando Hernández-Ahuactzi、Reyna Reyes-Martínez、Hugo Tlahuext、Hugo Morales-Rojas、Herbert Höpfl

  DOI：10.1021/ic801464s

  日期：2008.11.3

  cis-oriented dtc functions. Thus, for the complexes derived from 1,3-Bn/(i)Bu-ambdtc, two different macrocyclic structures were observed. In the dimethyl- and di-n-butyltin derivatives, the bridging bis-dtc ligands adopt U-shaped conformations, while in the case of the diphenyltin derivative, the conformation is L-shaped. Furthermore, two different macrocyclic ring conformations can occur, which differ

  1,3-双（苄基氨基甲基）苯（1,3-Bn-ambdtc），1,3-双（异丁基氨基甲基）苯（1,3-（i））的双二硫代氨基甲酸钾（bis-dtc）盐使Bu-ambdtc），1,4-双（苄基氨基甲基）苯（1,4-Bn-ambdtc）和1,4-双（异丁基氨基甲基）苯（1,4-（i）Bu-ambdtc）反应与三种不同的二有机二有机二氯化物（R2SnCl2，R = Me，（n）Bu和Ph）按化学计量比1：1混合，得到相应的二有机锡双-二硫代氨基甲酸酯。另外，制备了1，1'-双（苄基氨基甲基）二茂铁（1，1'-Bn-amfdtc）的二甲基锡双-二硫代氨基甲酸酯。所得络合物已通过元素分析，FAB（+）质谱，IR和NMR（（1）H，（13）C和（119）Sn）光谱以及单晶X射线进行了尽可能多的表征衍射，表明锡络合物是组成[R2Sn（bis-dtc）} 2]的双核24和26元大环物种。如（119）Sn
• AMINE FOR RAPID-CURING EPOXY RESIN COMPOSITIONS
  申请人：SIKA TECHNOLOGY AG

  公开号：US20180079710A1

  公开（公告）日：2018-03-22

  An amine of formula (I) which is particularly suitable for use as a curing agent for epoxy resins. The amine of formula (I) is devoid of non-incorporable toxic phenols, and is low-viscosity and pale in colour. It allows the production of easily-workable, low-emission or emission-free epoxy resin products which cure rapidly even at relatively low ambient temperatures thus obtaining a high degree of hardness and a nice surface with hardly any yellowing. This is particularly suited to use in floor or top coatings.

  一种化学式为(I)的胺，特别适用作环氧树脂的固化剂。该化学式(I)的胺不含不可溶性有毒酚类物质，具有低粘度和浅色。它可以生产易于加工、低排放或无排放的环氧树脂制品，即使在相对较低的环境温度下也可以快速固化，从而获得高度硬度和几乎没有发黄的漂亮表面。这特别适用于地板或表面涂层的使用。
• Low-emission hardener for epoxy resins
  申请人：Burckhardt Urs

  公开号：US09212287B2

  公开（公告）日：2015-12-15

  The present invention concerns a low-odor, low-viscosity hardener for epoxy resins comprising the amine of formula (I), as well as a method for thinning of hardeners for epoxy resins by adding the amine of formula (I). These hardeners harden with epoxy resins quickly and without blushing to form films of high hardness and little brittleness, even without non-incorporable thinners such as benzyl alcohol. They are especially suitable for low-emission coatings.

  本发明涉及一种低气味、低粘度的环氧树脂固化剂，包括式(I)的胺，以及一种通过添加式(I)的胺来稀释环氧树脂固化剂的方法。这些固化剂可以快速固化环氧树脂，而不会出现发白现象，形成硬度高、脆性小的薄膜，即使没有像苯甲醇这样的不可溶解的稀释剂。它们特别适用于低排放涂料。
• Benzylated Polyamine Curing Agents
  申请人：Raymond Williams Rene Edouard

  公开号：US20130079435A1

  公开（公告）日：2013-03-28

  A curing agent composition including at least one benzylated polyamine compound. The benzylated polyamine compound is a reaction product of a benzaldehyde compound or benzyl halide compound and a polyamine according to the following formula: H2N—CH2-A-CH2-NH2 where A is a phenylene group or a cyclohexylene group. A method for making the curing agent composition and an amine-epoxy composition are also disclosed.

  一种固化剂组合物，包括至少一种苯基聚胺化合物。该苯基聚胺化合物是苯甲醛化合物或苯基卤化物化合物和聚胺按以下公式反应产生的产物：H2N—CH2-A-CH2-NH2，其中A是苯基或环己基。还公开了制备固化剂组合物和胺-环氧组合物的方法。
• AMINE FOR LOW-EMISSION EPOXY RESIN PRODUCTS
  申请人：SIKA TECHNOLOGY AG

  公开号：US20150344406A1

  公开（公告）日：2015-12-03

  An amine which can be used in epoxy resin compositions that cure at room temperature. The amine dilutes the composition highly effectively, allows rapid, trouble-free curing, even in cold and damp conditions, and reduces brittleness. The amine is particularly suitable as a constituent of a curing agent for low-emission epoxy resin compositions that cure at room temperature, in particular for floor coverings.

  一种胺可以用于在室温下固化的环氧树脂组合物中。该胺高效地稀释组合物，使其可以在冷湿条件下快速、无困难地固化，并减少脆性。该胺特别适用于作为低排放环氧树脂组合物的固化剂成分，尤其适用于地面覆盖材料。