bis(α-hydroxyethyl)phenylphosphine | 68100-14-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(α-hydroxyethyl)phenylphosphine
• 英文别名: 1,1'-(Phenylphosphanediyl)di(ethan-1-ol)；1-[1-hydroxyethyl(phenyl)phosphanyl]ethanol
• CAS: 68100-14-1
• 化学式: C₁₀H₁₅O₂P
• 分子量: 198.202
• InChiKey: BXIIBXNTFQLUIA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bis(α-hydroxyethyl)phenylphosphine 在 dinitrogen tetraoxide 作用下， 生成 Phenyl-di(ethylol)-phosphin-oxid
  参考文献：
  名称：

  Petrov,K.A. et al., Journal of general chemistry of the USSR, 1961, vol. 31, p. 3180 - 3182

  摘要：

  DOI：
• 作为产物：
  描述：

  乙醛 、 苯基膦 在 盐酸 作用下， 生成 bis(α-hydroxyethyl)phenylphosphine
  参考文献：
  名称：

  Petrov,K.A. et al., Journal of general chemistry of the USSR, 1961, vol. 31, p. 3180 - 3182

  摘要：

  DOI：

文献信息

• Transition metal complexes and polymerization catalysts
  申请人：Otomaru Yuka

  公开号：US20060229195A1

  公开（公告）日：2006-10-12

  There are provided a transition metal complex of formula (1): wherein M represents an element of Group 6 of Periodic Table of Elements, A and A′ are the same or different, and represent a substituted or unsubstituted C1-10 alkylene group or the like, Y represents a substituted or unsubstituted C1-10 alkyl group, or the like, X 1 and X 2 are the same or different, and represent a hydrogen atom, a halogen atom, a substituted or unsubstituted C1-10 alkyl group, or an amino group disubstituted with C1-20 hydrocarbon, and n 1 is an integer of 0 to 3, an olefin polymerization catalyst obtained by combining a transition metal complex with an organic aluminum or aluminoxane, a polymerization catalyst further containing a boron compound, and a process for producing olefin polymer using the polymerization catalyst.

  提供了一种公式为（1）的过渡金属配合物：其中M代表元素周期表的第6组元素，A和A'相同或不同，代表取代或未取代的C1-10烷基或类似物，Y代表取代或未取代的C1-10烷基或类似物，X1和X2相同或不同，代表氢原子、卤素原子、取代或未取代的C1-10烷基或二取代C1-20碳氢化合物的氨基，n1为0至3的整数，通过将过渡金属配合物与有机铝或铝烷氧化物结合获得的烯烃聚合催化剂，进一步含有硼化合物的聚合催化剂，以及使用该聚合催化剂生产烯烃聚合物的方法。
• TRANSITION METAL COMPLEXES AND POLYMERIZATION CATALYSTS
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1557423A1

  公开（公告）日：2005-07-27

  There are provided a transition metal complex of formula (1): wherein M represents an element of Group 6 of Periodic Table of Elements, A and A' are the same or different, and represent a substituted or unsubstituted C1-10 alkylene group or the like, Y represents a substituted or unsubstituted C1-10 alkyl group, or the like, X1 and X2 are the same or different, and represent a hydrogen atom, a halogen atom, a substituted or unsubstituted C1-10 alkyl group, or an amino group disubstituted with C1-20 hydrocarbon, and n1 is an integer of 0 to 3, an olefin polymerization catalyst obtained by combining a transition metal complex with an organic aluminum or aluminoxane, a polymerization catalyst further containing a boron compound, and a process for producing olefin polymer using the polymerization catalyst.

  提供了一种式（1）的过渡金属配合物： 其中 M 代表元素周期表第 6 族元素，A 和 A'相同或不同，代表取代或未取代的 C1-10 烷基或类似基团，Y 代表取代或未取代的 C1-10 烷基或类似基团，X1 和 X2 相同或不同，代表氢原子、卤素原子、取代或未取代的 C1-10 烷基、或与 C1-20 碳氢化合物二取代的氨基，且 n1 为 0 至 3 的整数，通过将过渡金属络合物与有机铝或铝氧烷结合而获得的烯烃聚合催化剂，进一步含有硼化合物的聚合催化剂，以及使用该聚合催化剂生产烯烃聚合物的工艺。
• Synthesis and steric structure of 2,2-disubstituted 5-phenyl-1,3,5-dioxaphosphorinanes
  作者：B. A. Arbuzov、O. A. Erastov、A. S. Ionkin

  DOI：10.1007/bf00953343

  日期：1986.11
• Reaction of bis(?-hydroxyethyl)phenylphosphine with phenylarsine oxide and dimethyl ester of phenylarsenous acid
  作者：O. A. Erastov、I. P. Romanova、N. A. Chadaeva

  DOI：10.1007/bf01167801

  日期：1983.1
• Synthesis and several properties of 1, 3, 2, 5-dioxaboraphosphorinanes with a branched substituent at the boron atom
  作者：A. A. Karasik、G. N. Nikonov、B. A. Arbuzov、R. Z. Musin、Yu. Ya. Efremov

  DOI：10.1007/bf00958010

  日期：1991.3

  Bis (alpha-hydroxyalkyl)phenylphosphines react with alpha-iminoboranes in protic solvents such as dihydric alcohols to give 2-(1',1'-dibutylamyl)-4,6-di-R-5-phenyl-1,3,2,5-dioxaboraphosphorinanes, which react with CuI in pyridine to form [LCuI(Py)] complexes. PMR spectroscopy showed that the phosphorus-containing ligands exist as a single stereoisomer.