1,1,2,2-Tetrafluoro-2-[1,1,2,3,3-pentafluoro-1-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonyl fluoride | 921204-33-3

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 磺酰卤
• 英文名称: 1,1,2,2-Tetrafluoro-2-[1,1,2,3,3-pentafluoro-1-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonyl fluoride
• 英文别名: 1,1,2,2-tetrafluoro-2-[1,1,2,3,3-pentafluoro-1-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonyl fluoride
• CAS: 921204-33-3
• 化学式: C₉F₁₈O₇S₂
• 分子量: 626.198
• InChiKey: OEWNHGKFYOBVQE-UHFFFAOYSA-N

物化性质

• 沸点：
  318.0±42.0 °C(Predicted)
• 密度：
  1.898±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  36
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  113
• 氢给体数：
  0
• 氢受体数：
  25

反应信息

• 作为产物：
  描述：

  Perfluoro-2-{2,3-bis[2-(fluorosulfonyl)ethoxy]propoxy}propanoyl fluoride 反应 1.5h， 生成 1,1,2,2-Tetrafluoro-2-[1,1,2,3,3-pentafluoro-1-(1,1,2,2-tetrafluoro-2-fluorosulfonylethoxy)-3-(1,2,2-trifluoroethenoxy)propan-2-yl]oxyethanesulfonyl fluoride
  参考文献：
  名称：

  WO2007/13532

  摘要：

  公开号：

文献信息

• ELECTROLYTE MATERIAL, LIQUID COMPOSITION, AND MEMBRANE-ELECTRODE ASSEMBLY FOR SOLID POLYMER FUEL CELL
  申请人：Asahi Glass Company, Limited

  公开号：EP3239189A1

  公开（公告）日：2017-11-01

  To provide a membrane/electrode assembly excellent in the power generation characteristics in a wide temperature range and a wide humidity range; an electrolyte material suitable for a catalyst layer of the membrane/electrode assembly; and a liquid composition suitable for forming a catalyst layer of the membrane/electrode assembly. To use an electrolyte material which is formed of a polymer (H) obtained by converting precursor groups in a polymer (F) having structural units (A) based on a perfluoromonomer having a precursor group represented by the formula (g1), structural units (B) represented by the formula (u2), and structural units (C) based on tetrafluoroethylene, wherein the proportion of the structural units (A) is from 8 to 19 mol%, the proportion of the structural units (B) is from 65 to 80 mol%, and the proportion of the structural units (C) is from 1 to 27 mol%, to ion exchange groups.

  提供一种在宽温度范围和宽湿度范围内具有优异发电特性的膜/电极组件；一种适用于膜/电极组件催化剂层的电解质材料；以及一种适用于形成膜/电极组件催化剂层的液体组合物。 使用一种电解质材料，该材料由聚合物 (F) 中的前体基团转化而成，聚合物 (F) 的结构单元 (A) 基于具有式 (g1) 所示前体基团的全氟单体，结构单元 (B) 基于式 (u2) 所示前体基团、和基于四氟乙烯的结构单元（C），其中结构单元（A）与离子交换基团的比例为 8 至 19 摩尔%，结构单元（B）与离子交换基团的比例为 65 至 80 摩尔%，结构单元（C）与离子交换基团的比例为 1 至 27 摩尔%。
• METHOD FOR PRODUCING LIQUID COMPOSITION, METHOD FOR PRODUCING COATING LIQUID FOR FORMING CATALYST LAYER, AND METHOD FOR PRODUCING MEMBRANE ELECTRODE ASSEMBLY
  申请人：Asahi Glass Company, Limited

  公开号：EP3339369A1

  公开（公告）日：2018-06-27

  To provide a method for producing a liquid composition or a coating liquid for forming a catalyst layer, which can make cracking less likely to occur at the time of forming a solid polymer electrolyte membrane or a catalyst layer; and a method for producing a membrane electrode assembly, which can make cracking less likely to occur at the time of forming the catalyst layer or the solid polymer electrolyte membrane. This liquid composition is prepared by dispersing in a medium containing water and a hydrocarbon-type alcohol a polymer (x) having a structural unit having a ring structure and a structural unit having an ion exchange group, or a polymer (y) having either one or both of a structural unit having two ion-exchange groups in a pendant group and a structural unit having one ion exchange group in a short-chain pendant group, to prepare a dispersion in which the concentration of the polymer (x) or the polymer (y) is from 10 to 26 mass%, and mixing the dispersion and a fluorinated solvent so that the sum of the concentration of the polymer (x) or the polymer (y) and the concentration of the fluorinated solvent becomes to be from 12 to 35 mass%.

  提供一种生产用于形成催化剂层的液体组合物或涂覆液的方法，该方法可在形成固体聚合物电解质膜或催化剂层时减少裂纹的发生；以及一种生产膜电极组件的方法，该方法可在形成催化剂层或固体聚合物电解质膜时减少裂纹的发生。这种液体组合物的制备方法是：将具有环状结构的结构单元和具有离子交换基团的结构单元的聚合物 (x) 或具有在一个悬垂基团中具有两个离子交换基团的结构单元和在一个短链悬垂基团中具有一个离子交换基团的结构单元中的一个或两个的聚合物 (y) 分散在含有水和烃类醇的介质中、制备聚合物 (x) 或聚合物 (y) 浓度为 10 至 26 质量％的分散液，并将分散液与含氟溶剂混合，使聚合物 (x) 或聚合物 (y) 浓度与含氟溶剂浓度之和达到 12 至 35 质量％。
• Process for producing liquid composition and process for producing catalyst layer-forming coating liquid
  申请人：AGC Inc.

  公开号：US10457760B2

  公开（公告）日：2019-10-29

  A process for producing a liquid composition, which includes holding a fluorinated polymer having —SO2F groups at from 140 to 160° C. for at least 45 minutes, cooling it to less than 110° C. at a rate of at least 50° C./min, converting the —SO2F groups in the fluorinated polymer to ion exchange groups to obtain a fluorinated polymer having ion exchange groups, and mixing the fluorinated polymer having ion exchange groups and a liquid medium.

  一种生产液体组合物的工艺，包括将具有 -SO2F 基团的含氟聚合物在 140 至 160 摄氏度下保温至少 45 分钟，以至少 50 摄氏度/分钟的速度冷却至 110 摄氏度以下，将含氟聚合物中的 -SO2F 基团转化为离子交换基团以获得具有离子交换基团的含氟聚合物，以及将具有离子交换基团的含氟聚合物与液体介质混合。
• Method for producing fluorine-containing compound having iodine atom content reduced
  申请人：AGC Inc.

  公开号：US10604461B2

  公开（公告）日：2020-03-31

  The purpose of the present invention is to obtain a fluorine-containing compound which is easily stabilized without irradiation of ultraviolet light, by efficiently converting a C—I bond in an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to a C—H bond. A method for producing a fluorine-containing compound having an iodine atom content reduced than the following iodine-containing compound, which comprises subjecting an iodine-containing compound having a group represented by —CFRf—I (wherein Rf is a fluorine atom or a perfluoroalkyl group) to deiodinating treatment in the presence of an organic peroxide and a hydrogen-containing compound having a group represented by —CHR1—CHR2—CHR3— (wherein R1, R2 and R3 are each independently a hydrogen atom or an alkyl group).

  本发明的目的是通过有效地将具有-CFRf-I（其中Rf为氟原子或全氟烷基）所代表基团的含碘化合物中的C-I键转化为C-H键，获得一种无需紫外线照射即可轻松稳定的含氟化合物。一种生产碘原子含量低于下述含碘化合物的含氟化合物的方法，该方法包括在有机过氧化物和具有-CHR1-CHR2-CHR3-(其中R1、R2和R3各自独立地为氢原子或烷基)基团的含氢化合物存在下，对具有-CFRf-I(其中Rf为氟原子或全氟烷基)基团的含碘化合物进行脱碘处理。
• Process for producing fluorinated polymer
  申请人：AGC Inc.

  公开号：US10611859B2

  公开（公告）日：2020-04-07

  To provide a process for producing a fluorinated polymer having a cyclic structure at a relatively low cost, by efficiently recovering, from a mixture containing a fluorinated polymer obtained by polymerizing a perfluoromonomer having a cyclic structure and an unreacted perfluoromonomer having a cyclic structure, the unreacted perfluoromonomer having a cyclic structure. A monomer component containing a perfluoromonomer having a specific cyclic structure is polymerized in the presence of a polymerization initiator at a predetermined polymerization temperature to obtain a mixture containing a fluorinated polymer and an unreacted cyclic structure monomer, and the perfluoromonomer having a cyclic structure is recovered from the mixture at a temperature of at most the maximum ultimate temperature of the polymerization temperature+12° C. and at most the 10 hour half-life temperature of the polymerization initiator+12° C. under a pressure of less than the atmospheric pressure.

  提供一种工艺，通过从含有通过聚合具有环状结构的全氟单体而获得的含氟聚合物和具有环状结构的未反应全氟单体的混合物中有效回收具有环状结构的未反应全氟单体，以相对较低的成本生产具有环状结构的含氟聚合物。含有具有特定环状结构的全氟单体的单体组分在聚合引发剂存在下，在预定聚合温度下聚合，得到含有含氟聚合物和未反应的环状结构单体的混合物，具有环状结构的全氟单体在聚合温度的最高极限温度+12℃和聚合引发剂的最多 10 小时半衰期温度+12℃的温度下，在低于大气压的压力下从混合物中回收。