2,2-bis[4-(N-phenylphthalimide-4-oxy)phenyl]propane | 38103-03-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2-bis[4-(N-phenylphthalimide-4-oxy)phenyl]propane
• 英文别名: 5-[4-[2-[4-(1,3-Dioxo-2-phenylisoindol-5-yl)oxyphenyl]propan-2-yl]phenoxy]-2-phenylisoindole-1,3-dione
• CAS: 38103-03-6
• 化学式: C₄₃H₃₀N₂O₆
• 分子量: 670.721
• InChiKey: PRRFHDINEATRPA-UHFFFAOYSA-N

物化性质

• 沸点：
  828.7±75.0 °C(Predicted)
• 密度：
  1.345±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  51
• 可旋转键数：
  8
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  93.2
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  双酚A 在 咪唑 、 cesium fluoride 作用下， 以 二氯甲烷 为溶剂， 反应 0.08h， 生成 2,2-bis[4-(N-phenylphthalimide-4-oxy)phenyl]propane
  参考文献：
  名称：

  Rapid synthesis of etherimides via catalytic arylation of silylated phenols

  摘要：

  We report here a rapid and efficient method for the synthesis of aromatic etherimides from silylated phenols and 4-fluorophthalimides catalyzed by CsF. Reaction times are a few minutes and products are easily purified requiring no column chromatography. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)02505-2

文献信息

• [EN] METHOD FOR PURIFICATION OF A BISPHENOL A DIANHYDRIDE COMPOSITION, BISPHENOL A DIANHYDRIDE COMPOSITION, POLY(ETHERIMIDE) DERIVED FROM THE BISPHENOL A DIANHYDRIDE COMPOSITION, AND ARTICLES PREPARED THEREFROM<br/>[FR] PROCÉDÉ DE PURIFICATION D'UNE COMPOSITION DE DIANHYDRIDE DE BISPHÉNOL A, COMPOSITION DE DIANHYDRIDE DE BISPHÉNOL A, POLY(ÉTHERIMIDE) DÉRIVÉ DE LA COMPOSITION DE DIANHYDRIDE DE BISPHÉNOL A, ET ARTICLES PRÉPARÉS À PARTIR DE CEUX-CI
  申请人：SABIC GLOBAL TECHNOLOGIES BV

  公开号：WO2020160215A1

  公开（公告）日：2020-08-06

  A method for the purification of a bisphenol A dianhydride composition includes contacting the bisphenol A dianhydride composition with a halogenated solvent to form a solution, and one or more of filtering the solution to remove ionic species; washing the solution with aqueous media to remove ionic species; crystallizing bisphenol A dianhydride from the solution to remove ionic species; and contacting the solution with an adsorbent to remove ionic species. A purified bisphenol A dianhydride composition is also described. The bisphenol A dianhydride composition can be used in the preparation of a poly(etherimide), and poly (etherimides) made from the bisphenol A dianhydride composition can be useful for forming a variety of articles.

  一种用于纯化双酚A二酐组合物的方法包括将双酚A二酐组合物与卤代溶剂接触以形成溶液，以及通过以下一种或多种方法来过滤溶液以去除离子物种：过滤溶液以去除离子物种；用水介质洗涤溶液以去除离子物种；从溶液中结晶出双酚A二酐以去除离子物种；以及将溶液与吸附剂接触以去除离子物种。还描述了一种纯化的双酚A二酐组合物。双酚A二酐组合物可用于制备聚醚酰亚胺，由双酚A二酐组合物制成的聚醚酰亚胺可用于形成各种物品。
• Polymer-metal junction
  申请人：Solvay Specialty Polymers USA, LLC

  公开号：US11359120B2

  公开（公告）日：2022-06-14

  Disclosed is a polymer-metal junction including a polymer composition in contact with a metal substrate, where the polymer composition comprises a polymer component including a PEEK-PEDEK copolymer having a PEEK/PEDEK mole ratio ranging from about 60/40 to about 30/70 and a melting point (Tm) greater than 320° C., and where the polymer composition includes less than 10 wt. % of a sulfur-or-carbonyl-containing solvent, based on the total weight of the polymer composition. Also disclosed are methods of making the polymer-metal junction and articles including the polymer-metal junction.

  本发明公开了一种聚合物-金属接头，包括与金属基板接触的聚合物组合物，其中所述聚合物组合物包含一种聚合物成分，所述聚合物成分包括一种PEEK-PEDEK共聚物，所述PEEK/PEDEK摩尔比范围为约60/40至约30/70，且所述PEEK-PEDEK共聚物的熔点(Tm)大于320°C。此外，所述聚合物组合物中含有一种含硫或羰基的溶剂，其含量小于聚合物组合物总重量的10重量%。本发明还公开了制备所述聚合物-金属接头的方法以及包含所述聚合物-金属接头的产品。
• Phase transfer catalysts
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0126951B1

  公开（公告）日：1994-07-20
• POLY(ARYL ETHER KETONE) (PAEK) COMPOSITIONS INCLUDING A LOW MOLECULAR WEIGHT AROMATIC COMPOUND
  申请人：Solvay Specialty Polymers USA, LLC

  公开号：EP3494163B1

  公开（公告）日：2020-10-07
• Polyetherimide and Polyetherimide Sulfone Blends Having Automotive Lighting Applications
  申请人：Yamaguchi Norimitsu

  公开号：US20090258991A1

  公开（公告）日：2009-10-15

  Compositions and articles of manufacture made therefrom for use in high temperature application, such as automotive reflectors, have a minimum haze onset temperature of about 205° C. and are made from a transparent, miscible blend of from about 30 to about 70 weight percent of a polyetherimide sulfone comprising greater than or equal to 50 mole percent of the polymer linkages have an aryl sulfone group and from about 70 to about 30 weight percent of a polyetherimide or polyimide.