[Cu(2,2'-bipyridine)2I]I | 100731-12-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(2,2'-bipyridine)2I]I
• 英文别名: [CuI(2,2'-bipyridine)2]I；[CuI(bipy)2]I；[Cu(bpy)2I]I；copper;2-pyridin-2-ylpyridine;diiodide
• CAS: 100731-12-2；15679-48-8
• 化学式: C₂₀H₁₆CuIN₄*I
• 分子量: 629.729
• InChiKey: RVTDFPLMZIMJDH-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -1.71
• 重原子数：
  27
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  copper(II) nitrate trihydrate 在 KI 、 2,2'-bipyridyl 作用下， 以 乙醇 、 水 为溶剂， 生成 [Cu(2,2'-bipyridine)2I]I
  参考文献：
  名称：

  Dubey, S. N., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1981, vol. 20, # 4, p. 406 - 408

  摘要：

  DOI：

文献信息

• Production of urethane compounds
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：EP0083096A2

  公开（公告）日：1983-07-06

  A process for producing a urethane compound which comprises reacting at least one compound selected from the group consisting of a primary amine, a secondary amine and a urea compound with carbon monoxide and an organic hydroxyl compound in the presence of a catalyst system comprising: (a) at least one member selected from the group consisting of platinum group metals and compounds containing at least one platinum group element; and (b) at least one halogen-containing compound selected from the group consisting of alkali or alkaline earth metal halides, onium halides, compounds capable of forming onium halides in the reaction, oxo acids of halogen atoms and their salts, complex compounds containing halogen ions, organic halides and halogen molecules, in the presence of molecular oxygen and/or an organic nitro compound as an oxidizing agent at a temperature of from about 80°C to about 300°C under a pressure of from about 1 Kg/cm2 to about 500 Kg/cm2.

  一种生产聚氨酯化合物的工艺，包括使至少一种选自由伯胺、仲胺和脲化合物组成的组中的化合物与一氧化碳和有机羟基化合物在催化剂体系存在下发生反应，催化剂体系包括 (a) 至少一种选自铂族金属和含有至少一种铂族元素的化合物的成员；以及 (b) 至少一种含卤化合物，该化合物选自由碱金属或碱土金属卤化物、卤化铌、能在反应中 形成卤化铌的化合物、卤素原子的氧酸及其盐、含卤素离子的复合物、有机卤化物和卤素 分子组成的组、 在分子氧和/或作为氧化剂的有机硝基化合物存在下，在约 1 Kg/cm2 至约 500 Kg/cm2 的压力下，温度约为 80°C 至约 300°C。
• Drew, Michael G. B.; Clerac, Rodolphe; De, Senjuti, Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 2007, vol. 46, # 5, p. 760 - 763
  作者：Drew, Michael G. B.、Clerac, Rodolphe、De, Senjuti、Datta, Dipankar

  DOI：——

  日期：——
• Models for thyroxine: Aromatic iodine-assisted self-assemblies
  作者：Miquel Barceló-Oliver、Angel Terrón、Angel García-Raso、Elies Molins

  DOI：10.1016/j.poly.2006.11.024

  日期：2007.5

  Trying to understand the different recognition factors between thyroxine and its binding proteins, the chemistry of the ternary complexes between copper and o-iodobenzoylglycine (1-hip) [or o-iodobenzoylglycilglycine (B(I)GG)] as simple thyroxine models were studied lwith 2,2'-bipyridyl as secondary ligand.Two new compounds have been synthesized and structurally characterized: [Cu(1-hip)(bpy)(2)](+)(I-) center dot 1.5H(2)O and [Cu(B(I)GG)-(bpy)(2)](+)(I-) center dot 4H(2)O. These compounds and other previously reported by us offer interesting recognition patterns that could have biological relevance: iodine-iodine short interactions, iodine-hydrogen(aliphatic or aromatic) interactions, iodine-metal bonds, iodine-pi interactions (like C-H center dot center dot center dot pi), and aromatic self-assemblies assisted by iodine atoms. These patterns can be coupled in a synergistic manner, producing, for instance, a new C-I center dot center dot center dot pi center dot center dot center dot pi center dot center dot center dot I-C cluster pattern. (C) 2006 Elsevier Ltd. All rights reserved.
• Crystal structures, electronic properties and structural pathways of thirty [Cu(bipy)2X][Y] complexes, where X = Cl−, Br− or I− †
  作者：Cathal O’Sullivan、Gillian Murphy、Brian Murphy、Brian Hathaway

  DOI：10.1039/a810020i

  日期：——

  The crystal structures of ten distortion isomers of the [Cu(bipy)2X]+ cation have been determined, where X = Cl– (2), Br– (5) or I– (3), and compared by scatter plot analysis with twenty [Cu(bipy)2X]Y complexes of known crystal structure. In the ten new structures two involve a near regular trigonal bipyramidal stereochemistry (τ = 0.94–0.90) and eight show a square based pyramidal distorted trigonal bipyramidal stereochemistry (τ = 0.89–0.49), where τ = (α8 – α1)/60 [where α1 = N(2)–Cu–Cl, α8 = N(1)–Cu–N(3)]. Scatter plots of the eighteen cation distortion isomers of the [Cu(bipy)2Cl][Y] series of complexes suggest that all eighteen complexes lie on a common structural pathway, involving a mixture of the symmetric, C2, and the asymmetric, non-C2, in-plane modes of vibration of the CuN4Cl chromophore. The resulting structural pathways are consistent with the direct observation of the effect of the modes of vibration on the stereochemistries of the complexes. A comparison of the trends in the bipy/Cl, Br and I data suggests a size effect of the Br– and I– ligands.
• Dubey, S. N., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1981, vol. 20, # 4, p. 406 - 408
  作者：Dubey, S. N.

  DOI：——

  日期：——