5,10,15,20-tetraazaporphyrin magnesium | 14516-08-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 5,10,15,20-tetraazaporphyrin magnesium
• 英文别名: magnesium complex of 5,10,15,20-tetraazaporphin；Mg(II) tetraazaporphine；magnesium tetraazaporphinate；Magnesium;2,7,12,17,21,22-hexaza-23,24-diazanidapentacyclo[16.2.1.13,6.18,11.113,16]tetracosa-1(21),2,4,6,8,10,12,14,16(22),17,19-undecaene
• CAS: 14516-08-6
• 化学式: C₁₆H₈MgN₈
• 分子量: 336.598
• InChiKey: CSBBCFFEKMMITB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.11
• 重原子数：
  25
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  76.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5,10,15,20-tetraazaporphyrin magnesium 在 Cu-bronze 作用下， 以 吡啶 为溶剂， 生成 (tetraazaporphyrin)copper(II)
  参考文献：
  名称：

  Linstead, R. P.; Whalley, M., Journal of the Chemical Society

  摘要：

  DOI：
• 作为产物：
  描述：

  21H,22H-紫菜嗪 、 magnesium acetate 以 吡啶 为溶剂， 生成 5,10,15,20-tetraazaporphyrin magnesium
  参考文献：
  名称：

  Khelevina, O. G.; Berezin, B. D.; Petrov, O. A., Koordinatsionnaya Khimiya, 1990, vol. 16, p. 558 - 562

  摘要：

  DOI：

文献信息

• Picket-fence ruthenium(II) phthalocyaninates bearing (1R,2S,5R)-menthoxy groups as prototype of chiral catalysts
  作者：Andrey P. Kroitor、Anna A. Sinelshchikova、Mikhail S. Grigoriev、Gayane A. Kirakosyan、Alexander G. Martynov、Yulia G. Gorbunova、Alexander B. Sorokin

  DOI：10.1016/j.dyepig.2023.111830

  日期：2024.3

  We report design and synthesis of novel picket fence phthalocyanines to access the ruthenium(II) complexes carrying di-(1R,2S,5R)-menthoxy -substituted aryloxy-groups. Owing to bulkiness of such groups located either at peripheral (β) or non-peripheral (α) positions, they are nearly orthogonal to the plane of the phthalocyanine thus creating a chiral environment around the metal center. This orthogonality

  我们报道了新型栅栏酞菁的设计和合成，以获取带有二-( 1R，2S，5R )-薄荷氧基取代的芳氧基的钌(II)配合物。由于这些基团位于外围（β）或非外围（α）位置的体积大，它们几乎与酞菁平面正交，从而在金属中心周围形成手性环境。这种正交性得到了相应邻苯二甲腈前体的 X 射线分析的支持（α-和 β-取代邻苯二甲腈的芳香族部分平面之间的角度分别为 86.0° 和 81.4°）。作为概念证明，我们对合成的配合物作为重氮乙酸乙酯环丙烷化苯乙烯基准反应中的催化剂进行了研究。虽然β-取代的配合物显示出非常低的对映选择性，但α-取代的类似物对( 1S , 2R )-2-苯基环丙烷-1-甲酸乙酯具有中等的不对称诱导作用。该结果强调了手性基团相对于酞菁催化中心适当排列的重要性，并为进一步阐述用于卡宾不对称转移的酞菁催化剂提供了指导。
• Synthesis and properties of the molecular complex formed by tetrabromotetraazaporphyrin with bromine
  作者：N. V. Chizhova、O. G. Khelevina、B. D. Berezin

  DOI：10.1134/s1070363207080269

  日期：2007.8

  Magnesium complex of tetraazaporphyrin reacted with bromine in glacial acetic acid to give a 1:2 molecular adduct of tetrabromotetraazaporphyrin with bromine. The stability of the adduct in media of different polarities was studied. Zinc complex of tetrabromotetraazaporphyrin was synthesized by reaction of the molecular adduct with zinc acetate in dimethylformamide at 20 degrees C.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 141, page 1757 - 1760
  作者：

  DOI：——

  日期：——
• The state and stability of magnesium(II) complexes with azaporphyrins in the proton-donor medium
  作者：O. G. Khelevina、M. V. Ishutkina、A. S. Malyasova

  DOI：10.1134/s1070363213080136

  日期：2013.8

  The state and stability of magnesium complexes with various azaporphyrins in the proton-donor media containing acetic acid have been studied. Kinetic parameters of the complexes dissociation have been determined, possible reactions mechanisms have been proposed.
• Synthesis of Mg(II) Complexes of Phenyltetraazaporphyrins
  作者：A. S. Malyasova、O. V. Potekhina、V. V. Aleksandriiskii、O. G. Khelevina

  DOI：10.1134/s1070363217120532

  日期：2017.12

  Magnesium complexes of tetraazaporphyrins containing different numbers of phenyl rings in the macrocycles were synthesized by template condensation of maleodinitrile and phenylmaleodinitrile in the presence of magnesium butoxide in butanol at the boiling point of the alcohol. Magnesium(II) 2-phenyltetraazaporphyrin was synthesized and characterized.