2',6',3'',5''-tetramethyl-4''-hydroxybiphenyl-3,5-dimethyl-4-hydroxyphenylether | 15770-87-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2',6',3'',5''-tetramethyl-4''-hydroxybiphenyl-3,5-dimethyl-4-hydroxyphenylether
• 英文别名: 4-<3.5-Dimethyl-4-hydroxy-phenoxy>-4'-hydroxy-3.3'.5.5'-tetramethyl-biphenyl；4-(3.5-Dimethyl-4-hydroxy-phenoxy)-4'-hydroxy-3.3'.5.5'-tetramethyl-biphenyl；4-[4-(4-Hydroxy-3,5-dimethylphenoxy)-3,5-dimethylphenyl]-2,6-dimethylphenol
• CAS: 15770-87-3
• 化学式: C₂₄H₂₆O₃
• 分子量: 362.469
• InChiKey: MUYIGIGHSOGXDK-UHFFFAOYSA-N

物化性质

• 熔点：
  201.5-202.5 °C
• 沸点：
  474.1±45.0 °C(Predicted)
• 密度：
  1.133±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  49.7
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3.3'.5.5'-Tetramethyl-4-trimethylsilyloxy-4'-<3.5-dimethyl-4-trimethylsilyloxy-phenoxy>-biphenyl 在 盐酸 作用下， 生成 2',6',3'',5''-tetramethyl-4''-hydroxybiphenyl-3,5-dimethyl-4-hydroxyphenylether
  参考文献：
  名称：

  Synthesis of 4-hydroxyarylene ethers by the equilibration of phenols with poly(2,6-dimethyl-1,4-phenylene ether)

  摘要：

  DOI：

  10.1021/jo01254a010

文献信息

• Cerium(IV) induced hydroxylation of c-alkylated hydrocarbons and phenols
  作者：H.Mohindra Chawla、S.K. Sharma、K. Chakrabarty、S. Bhanumati

  DOI：10.1016/s0040-4020(01)85902-0

  日期：1988.1

  Hydroxylation of C-alkylated phenols has been achieved by employing cerium (IV) ammonium nitrate and hydrogen peroxide in acetic acid medium. The yield of hydroxylation products increases markedly when 3 × 10-3 M solution of sodium dodecyl sulphate is added to the oxidation system. The plausible mechanism of the reaction seems to involve free radical intermediates and is influenced by hydrophobic environment

  通过在乙酸介质中使用硝酸铈（IV）铵和过氧化氢，可以实现C烷基化苯酚的羟基化。当将3×10 -3 M十二烷基硫酸钠溶液添加到氧化系统中时，羟基化产物的产率显着增加。该反应的合理机制似乎涉及自由基中间体，并且受疏水环境的影响。从酚的氧化偶联的观点来看，该发现也具有重要意义。
• Hydroxylation of alkylphenols by cerium(IV) in conjunction with hydrogen peroxide and sodium dodecyl sulphate
  作者：H. Mohindra Chawla、S. Kumar Sharma、K. Chakrabarty、S. Bhanumati

  DOI：10.1039/c39880000128

  日期：——

  Hydroxylation of alkylphenols has been achieved by oxidation with cerium(IV) ammonium nitrate in conjunction with hydrogen peroxide in sodium dodecyl sulphate medium; concurrent oxidation of alkyl groups and subsequent decarboxylation have also been observed in some cases.

  烷基酚的羟化反应是通过在十二烷基硫酸钠介质中用硝酸铈（IV）铵和过氧化氢进行氧化来实现的。在某些情况下还观察到烷基同时氧化和随后的脱羧。
• CHAWLA, H. MOHINDRA;SHARMA, S. KUMAR;CHAKRABARTY, K.;BHANUMATI, S., J. CHEM. SOC. CHEM. COMMUN.,(1988) N 2, 128-129
  作者：CHAWLA, H. MOHINDRA、SHARMA, S. KUMAR、CHAKRABARTY, K.、BHANUMATI, S.

  DOI：——

  日期：——
• CHAWLA, H. MOHINDRA;SHARMA, S. CHAKRABARTY SHAKRABARTY K.;BHANUMATI, S., TETRAHEDRON, 44,(1988) N 4, 1227-1234
  作者：CHAWLA, H. MOHINDRA、SHARMA, S. CHAKRABARTY SHAKRABARTY K.、BHANUMATI, S.

  DOI：——

  日期：——
• PHOSPHORUS-CONTAINING POLYPHENYLENE OXIDE RESIN, ITS PREPARATION METHOD, METHOD FOR PREPARING PREPOLYMER OF PHOSPHORUS-CONTAINING POLYPHENYLENE OXIDE, RESIN COMPOSITION AND ITS APPLICATION
  申请人：Elite Material Co., Ltd.

  公开号：US20170088669A1

  公开（公告）日：2017-03-30

  The present invention relates to a phosphorus-containing polyphenylene oxide resin, its preparation method, a method for preparing the prepolymer of the phosphorus-containing polyphenylene oxide, a resin composition and an article thereof, wherein the phosphorus-containing polyphenylene oxide resin has a chemical structure represented by the following formula (I): wherein R′ is R″ is R′″ is hydrogen, Through the use of the above phosphorus-containing polyphenylene oxide resin, an article made from the resin composition can has good flame retardance, good thermal resistance and a lower percent of thermal expansion while dielectric properties can be maintained, such that the present invention is suitable for use in products such as copper clad laminate and printed circuit board.