S-phenyl diphenethylphosphinoselenothioate | 1443211-61-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: S-phenyl diphenethylphosphinoselenothioate
• 英文别名: Bis(2-phenylethyl)-phenylsulfanyl-selanylidene-lambda5-phosphane；bis(2-phenylethyl)-phenylsulfanyl-selanylidene-λ5-phosphane
• CAS: 1443211-61-7
• 化学式: C₂₂H₂₃PSSe
• 分子量: 429.424
• InChiKey: VACKSFHLDYIYHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.28
• 重原子数：
  25
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  bis(2-phenylethyl)phosphine selenide 、 苯硫酚 在 三乙胺 作用下， 以 四氯化碳 为溶剂， 反应 1.17h， 以92%的产率得到S-phenyl diphenethylphosphinoselenothioate
  参考文献：
  名称：

  Oxidative cross-coupling between secondary phosphine selenides and thiols or dithiols: a facile regio-selective synthesis of thioselenophosphinic S-esters and S-diesters

  摘要：

  Reactions between secondary phosphine selenides and a wide range of aliphatic, aromatic and heteroaromatic thiols or dithiols proceed in the Et3N/CCl4 oxidative system under mild conditions (rt 1-3 h) to give thioselenophosphinic S-esters or S-diesters in 80-92% isolated yields. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2013.04.117

文献信息

• Oxidative cross-coupling between secondary phosphine selenides and thiols or dithiols: a facile regio-selective synthesis of thioselenophosphinic S-esters and S-diesters
  作者：Nina K. Gusarova、Pavel A. Volkov、Nina I. Ivanova、Yurii V. Gatilov、Boris A. Trofimov

  DOI：10.1016/j.tetlet.2013.04.117

  日期：2013.7

  Reactions between secondary phosphine selenides and a wide range of aliphatic, aromatic and heteroaromatic thiols or dithiols proceed in the Et3N/CCl4 oxidative system under mild conditions (rt 1-3 h) to give thioselenophosphinic S-esters or S-diesters in 80-92% isolated yields. (c) 2013 Elsevier Ltd. All rights reserved.