triphenyl-λ⁶-sulfanenitrile | 191402-10-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenyl-λ⁶-sulfanenitrile
• 英文别名: Azanylidyne(triphenyl)-lambda6-sulfane；azanylidyne(triphenyl)-λ6-sulfane
• CAS: 191402-10-5
• 化学式: C₁₈H₁₅NS
• 分子量: 277.39
• InChiKey: QOHYAYOBPFEPPT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.45
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  24.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  triphenyl-λ⁶-sulfanenitrile 在 氢氧化钾 、 nitronium tetrafluoborate 作用下， 以 甲醇 、 水 、 乙腈 为溶剂， 反应 2.0h， 生成 二苯砜
  参考文献：
  名称：

  Preparation and Reactivity of N-Substituted S,S,S-Triphenyliminosulfonium Salts

  摘要：

  通过S,S,S-三苯基噻嗪与多种亲电试剂的反应，制备了N-取代的S,S,S-三苯基亚胺磺酸酯。通过X射线晶体学分析确定了N-甲基-S,S,S-三苯基亚胺磺酸高氯酸盐的分子结构。此外，还研究了它们的反应性。

  DOI：

  10.1246/cl.1998.1013
• 作为产物：
  描述：

  sodium isopropylate 、 以95%的产率得到苯甲酸异丙酯
  参考文献：
  名称：

  Preparation and Reactivity of N-Substituted S,S,S-Triphenyliminosulfonium Salts

  摘要：

  通过S,S,S-三苯基噻嗪与多种亲电试剂的反应，制备了N-取代的S,S,S-三苯基亚胺磺酸酯。通过X射线晶体学分析确定了N-甲基-S,S,S-三苯基亚胺磺酸高氯酸盐的分子结构。此外，还研究了它们的反应性。

  DOI：

  10.1246/cl.1998.1013

文献信息

• Syntheses, Crystal Structures, and Photophysical Properties of Platinum(II) Complexes Containing a Disulfanenitrile Ligand
  作者：Hiroya Honda、Takayoshi Fujii、Junpei Kuwabara、Takaki Kanbara

  DOI：10.1246/bcsj.20120336

  日期：2013.5.15

  New PtII complexes of bidendate Ph2S(=N(Ph2)S≡N)2 (ndsdsd) ligand were prepared, including the homoleptic complex, i.e., [Pt(ndsdsd)2](hfac)2 (1) (hfac: 1,1,1,5,5,5-hexafluoro-2,4-pentanedionato), and the heteroleptic complexes, [Pt(N^N)(ndsdsd)]X2 [N^N = 1,10-phenanthroline (phen) (2), 4,7-diphenylphenanthroline (bathophen) (3); X = PF6 (a) and ClO4 (b)] and [Pt(C^N)(ndsdsd)]X [C^N = 2-phenylpyridine (ppy) (4) and benzo[h]quinoline (bzq) (5); X = PF6 (a) and ClO4 (b)]. The complexes were characterized by IR, NMR spectroscopy, and elemental analysis. The molecular structures of complexes 1, 2a, and 4b have been elucidated by X-ray crystallographic analysis. The photophysical properties of all complexes were examined. Complexes 2 and 3a are very weakly luminescent in solution, whereas they show highly emissive in the solid state (Φem = 0.11–0.27).

  新的双齿配体Ph2S(=N(Ph2)S≡N)2 (ndsdsd)铂(II)配合物被制备，包括同配合物，即[Pt(ndsdsd)2](hfac)2 (1)（hfac：1,1,1,5,5,5-六氟-2,4-戊二酮），以及异配合物[Pt(N^N)(ndsdsd)]X2 [N^N = 1,10-菲咯啉 (phen) (2)、4,7-二苯基菲咯啉 (bathophen) (3)；X = PF6 (a) 和 ClO4 (b)]和[Pt(C^N)(ndsdsd)]X [C^N = 2-苯基吡啶 (ppy) (4) 和苯并[h]喹啉 (bzq) (5)；X = PF6 (a) 和 ClO4 (b)]。这些配合物通过红外光谱、核磁共振光谱和元素分析进行了表征。配合物1、2a和4b的分子结构通过X射线晶体学分析得以阐明。所有配合物的光物理性质均进行了检查。配合物2和3a在溶液中发光非常微弱，而在固态下则表现出高度发射性（Φem = 0.11–0.27）。
• Synthesis and Crystal Structures of [CuCl₂(μ-NSPh₃)]₂and [CuCl₂(Ph₃SN)₂]: Novel Copper Complexes Bearing Organic λ⁶-Sulfanenitrile as Ligand
  作者：Toshiaki Yoshimura、Takayoshi Fujii、Huagang Dai

  DOI：10.1246/cl.2002.1000

  日期：2002.10

  Dinuclear complex [CuCl2(μ-NSPh3)]2 (2) and mononuclear complex [CuCl2(Ph3SN)2] (3) were obtained concurrently by a reaction of CuCl2 with triphenyl-λ6-sulfanenitrile (1) in acetonitrile. They were characterized by elemental analysis, IR and NMR spectroscopy, and their molecular structures were determined by X-ray crystallographic analysis.

  通过 CuCl2 与三苯基-λ6-硫烷腈 (1) 在乙腈中反应，同时获得双核配合物 [CuCl2(μ-NSPh3)]2 (2) 和单核配合物 [CuCl2(Ph3SN)2] (3)。通过元素分析、红外光谱和核磁共振光谱对其进行了表征，并通过X射线晶体学分析确定了它们的分子结构。
• Generation of sulfenylnitrenes by N-sulfenylation of triphenyl-λ6-sulfanenitrile
  作者：Takayoshi Fujii、Taeko Kousaka、Toshiaki Yoshimura

  DOI：10.1016/s0040-4039(02)01170-x

  日期：2002.8

  The sulfenylation of triphenyl-lambda(6)-sulfanenitrile (1) with 2,4-dinitrobenzenesulfenyl chloride in the presence of alkenes affords aziridines together with triphenylsulfonium salt. The reaction of 1 with sulfur dichloride also generates CISN which is trapped by 2,5-diphenylfuran to give 5-benzoylisothiazole. (C) 2002 Elsevier Science Ltd. All rights reserved.
• First preparation and crystal structure of heterocyclic λ6-sulfanenitrile, 2,2′-biphenylylene(phenyl)-λ6-sulfanenitrile
  作者：Takayoshi Fujii、Akiko Itoh、Kouki Hamata、Toshiaki Yoshimura

  DOI：10.1016/s0040-4039(01)00913-3

  日期：2001.7

  The first heterocyclic lambda (6)-sulfanenitrile. 2,2 ' -biphenylylene(phenyl)-lambda (6)-sulfanenitrile is prepared and its molecular and electronic structures are determined by X-ray crystallographic analysis and quantum chemical calculations, respectively. (C) 2001 Elsevier Science Ltd. All rights reserved.
• First Preparation and X-ray Crystallographic Structure Determination of <i>S</i>,<i>S</i>,<i>S</i>-Triphenylthiazyne
  作者：Toshiaki Yoshimura、Kohki Hamada、Masahiro Imado、Kouki Hamata、Kazumi Tomoda、Takayoshi Fujii、Hiroyuki Morita、Choichiro Shimasaki、Shin Ono、Eiichi Tsukurimichi、Naomichi Furukawa、Takeshi Kimura

  DOI：10.1021/jo9703919

  日期：1997.6.13