N-(1-Naphthalenyl)-N-phenylbenzenemethanamine | 135505-47-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-(1-Naphthalenyl)-N-phenylbenzenemethanamine
• 英文别名: 1-(N-benzyl-N-phenylamino)naphthalene；N-benzyl-N-phenylnaphthalen-1-amine
• CAS: 135505-47-4
• 化学式: C₂₃H₁₉N
• 分子量: 309.411
• InChiKey: GMEFLMYTWJUZQZ-UHFFFAOYSA-N

物化性质

• 沸点：
  494.2±24.0 °C(Predicted)
• 密度：
  1.150±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  萘酚 在 氢氧化钾 、 sodium 、 N,N-二甲基甲酰胺 作用下， 反应 2.7h， 生成 N-(1-Naphthalenyl)-N-phenylbenzenemethanamine
  参考文献：
  名称：

  Novel synthesis of N,N-diarylarylmethanamines from N-(arylmethylene)arenamines and (arylmethoxy)arenes

  摘要：

  Various N,N-diarylarylmethanamines were synthesized by the reaction of N-(arylmethylene)arenamines with (arylmethoxy)arenes in dimethylformamide solution in the presence of a strong base as a catalyst which is obtained in situ by reacting metallic sodium with this solvent. In general, the reaction may be depicted as the reduction of the imine and addition, on the original imino nitrogen atom, of the aryl group (of the aryloxy moiety) of the ether and presumably oxidation of the arylmethoxy group of the either to its corresponding aldehyde. Side reactions and a proposed reaction mechanism are discussed.

  DOI：

  10.1021/jo00020a032

文献信息

• Chemical compounds
  申请人：Zeneca Limited

  公开号：US05395969A1

  公开（公告）日：1995-03-07

  A compound suitable for use as a charge transport compound in organic photoconductors or as a charge control agent in electrophotographic toners. The compound, in the neutral form, is of the Formula (1): ##STR1## wherein: Ar is of formula (a), (b) or (c) ##STR2## each L independently is H, C.sub.1-4 -alkyl or halo; R.sup.1, R.sup.3 and R.sup.4 are each independently alkyl, substituted alkyl, aryl, substituted aryl, aralkyl, substituted aralkyl, cycloalkyl or allyl; R.sup.2 is an alkyl, aralkyl, cycloalkyl, allyl or aryl group which is unsubstituted or substituted by a group defined by X.sup.4 ; and X.sup.1, X.sup.2, X.sup.3, X.sup.4 & X.sup.5 are each independently H or a group capable of stabilising a positive charge on the adjacent carbon atom.

  一种适用于有机光导体中的电荷传输化合物或静电复印调控剂的化合物。该化合物在中性形式下的化学式为(1)：Ar为化学式(a)、(b)或(c)；每个L独立地为H、C.sub.1-4-烷基或卤素；R.sup.1、R.sup.3和R.sup.4各自独立地为烷基、取代烷基、芳基、取代芳基、芳基烷基、取代芳基烷基、环烷基或烯丙基；R.sup.2为烷基、芳基烷基、环烷基、烯丙基或芳基，未取代或通过X.sup.4定义的基团取代；X.sup.1、X.sup.2、X.sup.3、X.sup.4和X.sup.5各自独立地为H或能够稳定相邻碳原子上正电荷的基团。
• BIODEGRADABLE LUBRICANT COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2428552A1

  公开（公告）日：2012-03-14

  A biodegradable lubricating oil composition includes (A) an ester being obtained by reacting a saturated aliphatic carboxylic acid, a straight-chain aliphatic dicarboxylic acid and a polyhydric alcohol together, the ester having a kinematic viscosity in a range from 400 mm2/s to 1000 mm2/s at 40 degrees C and an acid value of 0.5 mgKOH/g or less; (B) an ester being obtained by reacting a straight-chain saturated aliphatic carboxylic acid with a polyhydric alcohol, the ester having an acid value of 0.5 mgKOH/g or less; and (C) a phosphate amine salt being obtained by reacting an acidic phosphate with an alkylamine.

  一种可生物降解的润滑油组合物包括：(A) 由饱和脂肪族羧酸、直链脂肪族二羧酸和多元醇一起反应得到的酯，该酯在 40 摄氏度时的运动粘度范围为 400 mm2/s 至 1000 mm2/s，酸值为 0.5 mgKOH/g 或更低；(B) 由直链饱和脂肪族羧酸与多元醇反应得到的酯，该酯的酸值为 0.5 mgKOH/g 或更低；以及(C) 由酸性磷酸盐与烷基胺反应得到的磷酸盐胺盐。
• BIODEGRADABLE LUBRICATING OIL COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2752480A1

  公开（公告）日：2014-07-09

  A biodegradable lubricating oil composition of the invention includes a component (A) that is an ester obtained by reacting a linear saturated aliphatic carboxylic acid and a linear aliphatic dicarboxylic acid with a polyhydric alcohol, a component (B) that is an ester obtained by reacting a linear saturated aliphatic carboxylic acid with a polyhydric alcohol, and a component (C) that is a phosphate amine salt obtained by reacting an acidic phosphate with an alkylamine, in which the linear saturated aliphatic carboxylic acid of the component (A) is formed of a linear saturated aliphatic carboxylic acid having 8 carbon atoms and a linear saturated aliphatic carboxylic acid having 10 carbon atoms, and a molar amount of the linear saturated aliphatic carboxylic acid having 8 carbon atoms is larger than a molar amount of the linear saturated aliphatic carboxylic acid having 10 carbon atoms.

  本发明的一种可生物降解的润滑油组合物包括一种成分（A），该成分是通过使线性饱和脂肪族羧酸和线性脂肪族二羧酸与多元醇反应而得到的酯；一种成分（B），该成分是通过使线性饱和脂肪族羧酸与多元醇反应而得到的酯；以及一种成分（C），该成分是通过使酸性磷酸盐与烷基胺反应而得到的磷胺盐、其中，组分（A）中的线性饱和脂肪族羧酸由具有 8 个碳原子的线性饱和脂肪族羧酸和具有 10 个碳原子的线性饱和脂肪族羧酸组成，具有 8 个碳原子的线性饱和脂肪族羧酸的摩尔量大于具有 10 个碳原子的线性饱和脂肪族羧酸的摩尔量。
• EP2431450B1
  申请人：——

  公开号：EP2431450B1

  公开（公告）日：2014-05-07
• Photosensitive composition and forming process of structured material using the composition
  申请人：Yamada Kenji

  公开号：US20060210929A1

  公开（公告）日：2006-09-21

  The invention provides a photosensitive composition for forming a highly heat-resistant pattern of a micro phase separation structure. The photosensitive composition comprises: (A) a block copolymer containing a segment composed of an alkoxysilyl-group-containing monomer as a repeating unit, and (B) a photosensitive decomposition agent. The polydispersity index (Mw/Mn) of the block copolymer is 1.8 or lower.