bis(mesityl) iron(II) | 59774-47-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(mesityl) iron(II)
• 英文别名: dimesityl iron；[Fe(Mes)2]
• CAS: 59774-47-9
• 化学式: C₁₈H₂₂Fe
• 分子量: 294.22
• InChiKey: KYHOZNFUCDNKMD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.82
• 重原子数：
  19
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  bis(mesityl) iron(II) 在 pyridine 作用下， 以 乙醚 为溶剂， 生成 dimesityl(pyridine)2 iron
  参考文献：
  名称：

  Lattermann, Karl-Juergen; Seidel, Wolfgang, Zeitschrift fur Chemie, 1983, vol. 23, p. 31 - 31

  摘要：

  DOI：
• 作为产物：
  描述：

  iron(II) chloride 、 magnesium,1,3,5-trimethylbenzene-6-ide,bromide 以 四氢呋喃 为溶剂， 以34%的产率得到bis(mesityl) iron(II)
  参考文献：
  名称：

  On the path to bulk FeH2: Synthesis and magnetic properties of amorphous iron (II) hydride

  摘要：

  DOI：

  10.1016/j.jallcom.2013.12.099

文献信息

• Mono- and Dinuclear Neutral and Cationic Iron(II) Compounds Supported by an Amidinato-diolefin Ligand: Characterization and Catalytic Application
  作者：Crispin Lichtenberg、Mario Adelhardt、Michael Wörle、Torsten Büttner、Karsten Meyer、Hansjörg Grützmacher

  DOI：10.1021/acs.organomet.5b00395

  日期：2015.6.22

  interactions in neutral compounds. A set of iron compounds was shown to be active as precatalysts in the synthesis of poly silylethers by dehydrogenative alcoholysis of PhSiH3. The most active catalyst was generated from a dinuclear iron compound. Characterization techniques include NMR, IR, and Mössbauer spectroscopy, single crystal X-ray analysis, magnetic susceptibility measurements, and mass spectrometry

  提出了一种新的酰胺基二烯烃配体及其钠盐，作为制备铁（II）化合物的起点。已经建立了对阳离子和双核铁物种的合理合成方法，并允许首次分离a基稳定的阳离子Fe物种。潜在的四齿配体系统的多功能性通过三种不同结合模式的结构验证得到反映。这些包括中性化合物中Fe（II）-烯烃相互作用的罕见例子。在PhSiH 3的脱氢醇解中，显示出一组铁化合物在合成聚甲硅烷基醚中具有作为前催化剂的活性。。活性最高的催化剂是由双核铁化合物生成的。表征技术包括NMR，IR和Mössbauer光谱，单晶X射线分析，磁化率测量和质谱。
• Synthesis, Characterization, and Electrochemical Properties of a Series of Sterically Varied Iron(II) Alkoxide Precursors and Their Resultant Nanoparticles
  作者：Timothy J. Boyle、Leigh Anna M. Ottley、Christopher A. Apblett、Constantine A. Stewart、Sarah M. Hoppe、Krista L. Hawthorne、Mark A. Rodriguez

  DOI：10.1021/ic200423m

  日期：2011.7.4

  A new family of iron(II) aryloxide [Fe(OAr)(2)(py)(x)] precursors was synthesized from the alcoholysis of iron(II) mesityl [Fe(Mes)(2)] in pyridine (py) using a series of sterically varied 2-alkyl phenols (alkyl = methyl (H-oMP), isopropyl (H-oPP), tert-butyl (H-oBP)) and 2,6-dialkyl phenols (alkyl = methyl (H-DMP), isopropyl (H-DIP), tert-butyl (H-DBP), phenyl (H-DPhP)). All of the products were found to be mononuclear and structurally characterized as [Fe(OAr)(2)(py)(x)] (x = 3 OAr = oMP (1), oPP (2), oBP (3), DMP (4), DIP (5); x = 2 OAr = DBP (6), DPhP (7)). The use of tris-tert-butoxysilanol (OSi(OBut)(3) = TOBS) led to isolation of [Fe(TOBS)(2)(py)(2)] (8). The new Fe(OAr)(2)(py)(x) (1-6) were found, under solvothermal conditions, to produce nanodots identified by PXRD as the gamma-maghemite phase. The model precursor 3 and the nanoparticles 6n were evaluated using electrochemical methods. Cyclic voltammetry for 3 revealed multiple irreversible oxidation peaks, which have been tentatively attributed to the loss of alkoxide ligand coupled with the deposition of a solid Fe-containing coating on the electrode. This coating was stable out to the voltage limits for the acetonitrile solvent.
• [Fe(2,4,6-tBu3C6H2)2], a Monomeric Diaryl Complex with Two-Coordinate Iron(II)
  作者：Wolfgang Seidel、Hardy Müller、Helmar Görls

  DOI：10.1002/anie.199503251

  日期：1995.2.21
• LATTERMANN, K. -G.;SEIDEL, W., Z. CHEM., 1983, 23, N 1, 31
  作者：LATTERMANN, K. -G.、SEIDEL, W.

  DOI：——

  日期：——
• LATTERMANN, K. -J.;SEIDEL, W.;SCHADE, W., WISS. Z. FRIEDRICH-SCHILLER-UNIV. JENA, 1984, 33, N 1-2, 195-196
  作者：LATTERMANN, K. -J.、SEIDEL, W.、SCHADE, W.

  DOI：——

  日期：——