cuprous phenoxide | 34046-55-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: cuprous phenoxide
• 英文别名: Phenyloxykupfer(I)；Cu(I)-Phenoxid；copper(I) phenoxide；Copper(1+) phenoxide；copper(1+);phenoxide
• CAS: 34046-55-4
• 化学式: C₆H₅O*Cu
• 分子量: 156.651
• InChiKey: LTGBYAPCOUAFDM-UHFFFAOYSA-M

物化性质

• 溶解度：
  sol DMF, diglyme; insol ether and benzene.

计算性质

• 辛醇/水分配系数(LogP)：
  0.76
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

安全信息

• 海关编码：
  2907119000

反应信息

• 作为反应物：
  描述：

  cuprous phenoxide 在 硝酸 作用下， 生成 硝苯酚
  参考文献：
  名称：

  铜（I）与芳族化合物的配合物促进选择性亲电芳族取代

  摘要：

  摘要 我们报告了通过苯酚的 Cu(I)-芳香环络合物的反应选择性形成邻硝基苯酚、邻硝基甲苯（1-甲基-2-硝基苯）和邻苯酚磺酸（2-羟基苯磺酸）。甲苯。在苯酚硝化的情况下，反应可以表述为：铜（I）-芳香环络合物由铜（II）和金属铜在含有芳香族化合物的脱气水溶液中原位形成。苯酚或甲苯将铜 (0) 和铜 (II) 的混合反应转变为形成 Cu(I)：先前报道的水溶液中 Cu(I)-苯酚的稳定性常数为 900 ± 100 M-1。令人惊讶的稳定 d⟶π* Cu(I)-苯酚复合物会导致环结构的扭曲，从而促进选择性取代。苯酚的磺化（在水溶液中）和甲苯的硝化和磺化在两相过程中报告了类似的结果。图形概要

  DOI：

  10.1080/00958972.2018.1490415
• 作为产物：
  描述：

  copper (I) tert-butoxide 在 苯酚 作用下， 以 吡啶 为溶剂， 生成 cuprous phenoxide
  参考文献：
  名称：

  Copper(II)-induced oxidations of aromatic substrates: catalytic conversion of catechols to o-benzoquinones. Copper phenoxides as intermediates in the oxidation of phenol, and a single-step conversion of phenol, ammonia, and oxygen into muconic acid mononitrile

  摘要：

  DOI：

  10.1021/ja00409a030

文献信息

• COMPOSITION, FILM, NEAR INFRARED CUT FILTER, LAMINATE, PATTERN FORMING METHOD, SOLID IMAGE PICKUP ELEMENT, IMAGE DISPLAY DEVICE, INFRARED SENSOR, AND COLOR FILTER
  申请人：FUJIFILM Corporation

  公开号：US20180305552A1

  公开（公告）日：2018-10-25

  The composition includes two or more near infrared absorbing compounds having an absorption maximum in a wavelength range of 650 to 1000 nm and having a solubility of 0.1 mass % or lower in water at 23° C., in which the two or more near infrared absorbing compounds include a first near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm, and a second near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm which is shorter than the absorption maximum of the first near infrared absorbing compound, and a difference between the absorption maximum of the first near infrared absorbing compound and the absorption maximum of the second near infrared absorbing compound is 1 to 150 nm.

  该组合物包括两种或更多在波长范围为650到1000纳米具有吸收峰值的近红外吸收化合物，并且在23°C下其在水中的溶解度为0.1质量%或更低。其中，这两种或更多的近红外吸收化合物包括第一种在波长范围为650到1000纳米具有吸收峰值的近红外吸收化合物，以及第二种在波长范围为650到1000纳米具有比第一种近红外吸收化合物吸收峰值更短的吸收峰值的近红外吸收化合物，第一种近红外吸收化合物的吸收峰值与第二种近红外吸收化合物的吸收峰值之间的差值为1到150纳米。
• Method for making diaryl carbonate
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0720979A1

  公开（公告）日：1996-07-10

  Diaryl carbonate is prepared by hydrolysis of a tetraaryl orthocarbonate in the presence of an acid catalyst. The tetraaryl orthocarbonate is synthesized by a reaction between carbon disulfide and a cuprous phenate; the cuprous phenate can be made from cuprous chloride and the corresponding alkali metal phenate. The process may be integrated with recycle of by-products.

  碳酸二芳基酯是通过原碳酸四芳基酯在酸催化剂存在下水解制备的。原碳酸四芳基酯是由二硫化碳和苯酸亚铜反应合成的；苯酸亚铜可由氯化亚铜和相应的碱金属苯酸盐制成。该工艺可与副产品循环利用相结合。
• Volatile metal beta-ketoiminate complexes
  申请人：Air Products and Chemicals, Inc.

  公开号：EP1676849A1

  公开（公告）日：2006-07-05

  Metal complexes, containing copper, silver, gold, cobalt, ruthenium, rhodium, platinum, palladium, nickel, osmium, and/or indium, and methods for making and using same are described herein. In certain embodiments, the metal complexes described herein may be used as precursors to deposit metal or metal-containing films on a substrate through, for example, atomic layer deposition or chemical vapor deposition conditions.

  本文描述了含有铜、银、金、钴、钌、铑、铂、钯、镍、锇和/或铟的金属络合物，以及制造和使用这些金属络合物的方法。在某些实施方案中，本文所述的金属络合物可用作前驱体，通过原子层沉积或化学气相沉积等条件在基底上沉积金属或含金属的薄膜。
• Copper precursors for thin film deposition
  申请人：Air Products and Chemicals, Inc.

  公开号：EP2060577A1

  公开（公告）日：2009-05-20

  Non-fluorinated copper precursors and methods for making and using same are described herein. In certain embodiments, the copper precursors described herein may be used as precursors to deposit copper films and alloys thereof on a substrate through, for example, atomic layer deposition or chemical vapor deposition conditions.

  本文描述了非氟化铜前体及其制造和使用方法。 在某些实施例中，本文所述的铜前驱体可用作前驱体，通过原子层沉积或化学气相沉积等条件在基底上沉积铜膜及其合金。
• COMPOSITION, FILM, NEAR-INFRARED CUTOFF FILTER, LAMINATE, PATTERN FORMATION METHOD, SOLID-STATE IMAGE SENSOR, IMAGE DISPLAY DEVICE, INFRARED SENSOR AND COLOR FILTER
  申请人：FUJIFILM Corporation

  公开号：EP3410162A1

  公开（公告）日：2018-12-05

  Provided is a composition with which a film having excellent infrared shielding properties and reduced spectral variation can be formed. In addition, provided are a film, a near infrared cut filter, a laminate, a pattern forming method, a solid image pickup element, an image display device, an infrared sensor, and a color filter. The composition includes two or more near infrared absorbing compounds having an absorption maximum in a wavelength range of 650 to 1000 nm and having a solubility of 0.1 mass% or lower in water at 23°C, in which the two or more near infrared absorbing compounds include a first near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm, and a second near infrared absorbing compound having an absorption maximum in a wavelength range of 650 to 1000 nm which is shorter than the absorption maximum of the first near infrared absorbing compound, and a difference between the absorption maximum of the first near infrared absorbing compound and the absorption maximum of the second near infrared absorbing compound is 1 to 150 nm.

  本发明提供了一种组合物，使用该组合物可以形成具有优异红外线屏蔽性能和较小光谱变化的薄膜。此外，还提供了一种薄膜、一种近红外切割滤光片、一种层压板、一种图案形成方法、一种固体图像拾取元件、一种图像显示装置、一种红外传感器和一种彩色滤光片。该组合物包括两种或两种以上的近红外吸收化合物，它们在 650 到 1000 纳米的波长范围内具有吸收最大值，在水中的溶解度为 0.1 质量％或更低，其中两种或多种近红外吸收化合物包括第一种近红外吸收化合物，其吸收最大值在 650 至 1000 纳米的波长范围内；以及第二种近红外吸收化合物，其吸收最大值在 650 至 1000 纳米的波长范围内，比第一种近红外吸收化合物的吸收最大值短，且第一种近红外吸收化合物的吸收最大值与第二种近红外吸收化合物的吸收最大值之间的差值为 1 至 150 纳米。