eicosafluoro-octahydro-[1,1']bipyridinyl | 383-97-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: eicosafluoro-octahydro-[1,1']bipyridinyl
• 英文别名: Eicosafluor-octahydro-[1,1']bipyridyl；1-(2,2,3,3,4,4,5,5,6,6-Decafluoropiperidin-1-yl)-2,2,3,3,4,4,5,5,6,6-decafluoropiperidine
• CAS: 383-97-1
• 化学式: C₁₀F₂₀N₂
• 分子量: 528.091
• InChiKey: HHDJMRPQOWCPCX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  32
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  22

反应信息

• 作为产物：
  描述：

  nonafluoro-2,3,4,5-tetrahydropyridine 在 六氟环丁烯 、 氯 、 cesium fluoride 作用下， 反应 38.0h， 生成 eicosafluoro-octahydro-[1,1']bipyridinyl
  参考文献：
  名称：

  N-halogeno-compounds. Part 8. Perfluoro-N-chloropiperidine

  摘要：

  DOI：

  10.1016/s0022-1139(00)81281-6

文献信息

• Fluorocarbon Derivatives. II. Cyclic Nitrides
  作者：Thomas C. Simmons、Friedrich W. Hoffmann、R. B. Beck、H. V. Holler、T. Katz、R. J. Koshar、E. R. Larsen、J. E. Mulvaney、K. E. Paulson、F. E. Rogers、B. Singleton、R. E. Sparks

  DOI：10.1021/ja01570a030

  日期：1957.7
• On the electrochemical fluorination of derivatives of morpholine and piperidine
  作者：H. Meinert、R. Fackler、J. Mader、P. Reuter、W. Rohlke

  DOI：10.1016/s0022-1139(00)80306-1

  日期：1991.1

  Electrochemical fluorination (ECF) of alpha,omega-dimorpholino- and dipiperidino-alkanes of different chain length (n = 1-6) and of morpholinocyclohexene gave the perfluoro derivatives in yields up to 45%. By ring contractions, fragmentations and rearrangements several side products were obtained. Conclusions on the mechanism of ECF, based on a sterical model, were drawn.
• Investigations on the product distribution pattern during the electrochemical fluorination of 2-fluoropyridine and pyridine
  作者：P. Sartori、D. Velayutham、N. Ignat'ev、M. Noel

  DOI：10.1016/s0022-1139(97)00095-x

  日期：1998.1

  By using 2-fluoropyridine instead of pyridine as the starting material, a 19% conversion yield of perfluoropiperidine was obtained during the electrochemical fluorination process. At least ten products including perfluoropiperidine were characterised using repeated fractional distillation followed by GC and NMR analysis. (C) 1998 Elsevier Science S.A.
• BAILEY, A. R.;BANKS, R. E., J. FLUOR. CHEM., 1983, 23, N 1, 87-96
  作者：BAILEY, A. R.、BANKS, R. E.

  DOI：——

  日期：——
• N-halogeno-compounds. Part 8. Perfluoro-N-chloropiperidine
  作者：Allan R. Bailey、Ronald E. Banks

  DOI：10.1016/s0022-1139(00)81281-6

  日期：1983.7