1,1-bis-ethylsulfanyl-heptane | 60340-44-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代缩醛
• 英文名称: 1,1-bis-ethylsulfanyl-heptane
• 英文别名: 1,1-Bis-aethylmercapto-heptan；Heptanal-diaethyldithioacetal；1,1-Diaethylmercapto-heptan；Oenanthol-diaethylmercaptal；Heptanal-diaethylmercaptal；1,1-Bis(ethylsulfanyl)heptane
• CAS: 60340-44-5
• 化学式: C₁₁H₂₄S₂
• 分子量: 220.444
• InChiKey: OSLBBMLRPMDGAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,1-bis-ethylsulfanyl-heptane 在 乙醇 、 镍 作用下， 生成 正庚烷
  参考文献：
  名称：

  Carbonyl Reduction by Thioacetal Hydrogenolysis

  摘要：

  DOI：

  10.1021/ja01234a021
• 作为产物：
  描述：

  庚醛 、 乙硫醇 在 silica gel-supported phosphorus pentoxide 作用下， 以87%的产率得到1,1-bis-ethylsulfanyl-heptane
  参考文献：
  名称：

  Silica-supported phosphorus pentoxide: a reusable catalyst for S,S-acetalization of carbonyl groups under ambient conditions

  摘要：

  Phosphorus pentoxide supported on silica gel (P2O5/SiO2) efficiently acts as a highly active and reusable catalyst for cyclic and non-cyclic S,S-acetalization of a variety of carbonyl compounds under mild, solvent-free and ambient conditions. This method offers significant advantages such as high conversion, clean work-up, short reaction times and simplicity in operation.[GRAPHICS].

  DOI：

  10.1080/17415993.2010.542155

文献信息

• 1-ALKENYL THIOETHERS
  申请人：Ortho Pharmaceutical Corporation

  公开号：US04086278A1

  公开（公告）日：1978-04-25

  1-Alkenyl thioethers of glycols are described. The alkenyl thioethers possess central nervous system activity and are useful as tranquilizers.

  描述了一种甘醇的烯基硫醚。这些烯基硫醚具有中枢神经系统活性，可用作镇静剂。
• Titanium tetrachloride, an efficient and convenient reagent for thioacetalization1,1
  作者：Vijay Kumar、Sukh Dev

  DOI：10.1016/s0040-4039(00)81637-8

  日期：1983.1
• Microwave Thermolysis Vi : A Rapid and General Method for Dethioacetalization Using “Clayan” in Dry Media
  作者：H. M. Meshram、Gondi Sudershan Reddy、G. Sumitra、J. S. Yadav

  DOI：10.1080/00397919908086080

  日期：1999.4

  A variety of thioacetals, dithiolanes and dithianes are deprotected into their carbonyl compounds using clay supported ammonium nitrate "Clayan" under microwave irradiation. The present method avoids the use of toxic oxidants and excess of solvent.
• Clay supported ammonium nitrate “Clayan”: A mild and eco-friendly reagent for dethioacetalization
  作者：H.M. Meshram、Gondi Sudershan Reddy、J.S. Yadav

  DOI：10.1016/s0040-4039(97)10349-5

  日期：1997.12

  A variety of thioacetals and dithianes are deprotected into their carbonyl compounds in mild conditions using clay supported ammonium nitrate. The fertilizing nature of ammonium nitrate makes the procedure environmentally safe. (C) 1997 Elsevier Science Ltd.
• Complex bases. XIV. Use of sodamide containing complex bases as versatile, inexpensive reagents to generate carbanions
  作者：M.C. Carre、G. Ndebeka、A. Riondel、P. Bourgasser、P. Caubere

  DOI：10.1016/s0040-4039(01)90007-3

  日期：1984.1