2,4,6-triisopropylphenyl tripropynyltin | 883970-29-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,4,6-triisopropylphenyl tripropynyltin
• 英文别名: 2,4,6-i-Pr3C6H2Sn(CCMe)3；2,4,6-iPr3C6H2Sn(CCMe)3
• CAS: 883970-29-4
• 化学式: C₂₄H₃₂Sn
• 分子量: 439.228
• InChiKey: FHIRJDGNQNEFQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.26
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  水 、 2,4,6-triisopropylphenyl tripropynyltin 以 四氢呋喃 为溶剂， 以20%的产率得到
  参考文献：
  名称：

  有机-无机Sn12和有机Sn6-氢氧化物簇。

  摘要：

  DOI：

  10.1002/anie.200503738
• 作为产物：
  描述：

  trichloro(2,4,6-triisopropylphenyl)stannane 、 丙炔 在 n-BuLi 作用下， 以 甲苯 为溶剂， 以90%的产率得到2,4,6-triisopropylphenyl tripropynyltin
  参考文献：
  名称：

  A discrete unsymmetrically substituted dihydrodioxadistannetane with both η1 and intramolecular η2μ2 sulfonate bondings

  摘要：

  Hydrolysis of the aryltripropynyltin (3) in the presence of an arylsulfonic acid resulted in the formation of a new tetrasulfonato 1,3-dihydro-1,3-dioxa-2,4-diaryl-2,4-distannetane (4). Its crystal structure revealed that the molecule is the smallest discrete tin sulfonate cluster reported up to now with absence of intermolecular interactions. Molecule 4 also exhibits unusual eta(1) and intramolecular eta(2)mu(2) bonding modes for the sulfonate groups. Moreover, while only symmetrical 1,3-dihydro-1,3-dioxa-distannetanes have been described so far, the tin atoms in 4 are differently substituted. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.07.036

文献信息

• Sn₃and Sn₁₀sulfonate–oxide–hydroxide clusters with two different sulfonate binding modes
  作者：Ganesan Prabusankar、Bernard Jousseaume、Thierry Toupance、Hassan Allouchi

  DOI：10.1039/b706377f

  日期：——

  A tin sulfonate–oxide–hydroxide tetracation with two different sulfonate bindings, an electrostatic and a monohapto covalent one, and a tin sulfonate–oxide–hydroxide monocation with two other kinds of sulfonate bindings, an electrostatic and a dihapto bridging one are described here.

  这里描述了一种具有两种不同磺酸盐结合（静电结合和单价共价结合）的磺酸氧化氢锡四价化合物，以及一种具有两种不同磺酸盐结合（静电结合和双价桥接结合）的磺酸氧化氢锡一价化合物。
• Organic–Inorganic Sn12 and Organic Sn6 Oxide–Hydroxide Clusters
  作者：Ganesan Prabusankar、Bernard Jousseaume、Thierry Toupance、Hassan Allouchi

  DOI：10.1002/anie.200503738

  日期：2006.2.13
• A discrete unsymmetrically substituted dihydrodioxadistannetane with both η1 and intramolecular η2μ2 sulfonate bondings
  作者：Ganesan Prabusankar、Bernard Jousseaume、Thierry Toupance、Hassan Allouchi

  DOI：10.1016/j.jorganchem.2008.07.036

  日期：2008.10

  Hydrolysis of the aryltripropynyltin (3) in the presence of an arylsulfonic acid resulted in the formation of a new tetrasulfonato 1,3-dihydro-1,3-dioxa-2,4-diaryl-2,4-distannetane (4). Its crystal structure revealed that the molecule is the smallest discrete tin sulfonate cluster reported up to now with absence of intermolecular interactions. Molecule 4 also exhibits unusual eta(1) and intramolecular eta(2)mu(2) bonding modes for the sulfonate groups. Moreover, while only symmetrical 1,3-dihydro-1,3-dioxa-distannetanes have been described so far, the tin atoms in 4 are differently substituted. (C) 2008 Elsevier B.V. All rights reserved.