pyrrole-2-carboxaldehyde phenylhydrazone | 81280-72-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pyrrole-2-carboxaldehyde phenylhydrazone
• 英文别名: 2-Phenylhydrazonmethyl-pyrrol；pyrrole-2-carbaldehyde phenylhydrazone；Pyrrol-2-carbaldehyd-phenylhydrazon；N-[(E)-1H-pyrrol-2-ylmethylideneamino]aniline
• CAS: 81280-72-0
• 化学式: C₁₁H₁₁N₃
• 分子量: 185.228
• InChiKey: CKXVOVJLHCFQAZ-UKTHLTGXSA-N

物化性质

• 沸点：
  368.9±24.0 °C(Predicted)
• 密度：
  1.11±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-吡咯甲醛 、 苯肼 生成 pyrrole-2-carboxaldehyde phenylhydrazone
  参考文献：
  名称：

  Determination of the Apparent Molar Refraction and Partial Molar Volume at Infinite Dilution of Thiophene-, Pyrrole- and Furan-2-Carboxaldehyde Phenylhydrazone Derivatives in Acetonitrile at 293.15 K

  摘要：

  在 293.15 K 的温度下，对噻吩-2-（TCPH）、吡咯-2-（PCPH）和呋喃-2-甲醛苯腙（FCPH）化合物在乙腈中的极稀释溶液进行了高精度密度测量和高精度折射测量。根据 Kohner-Geffcken-Grunwald-Haley 近似法，实验测定了这些溶质在 293.15 K 时无限稀释时的表观摩尔折射率。根据杂原子的鲍林电负性和固有摩尔体积以及杂环的芳香性解释了体积测定法和折射测定法的结果。实验结果表明，在所研究的浓度范围内，溶质与溶质之间的相互作用可以忽略不计。DFT-B3LYP/6-311++G(3d,3p) 级别的分子体积理论计算支持这样的解释，即溶质-溶剂相互作用对溶质极限部分摩尔体积的体积贡献非常小，因此溶质分子在这种介质中是孤立的。

  DOI：

  10.1007/s10953-006-9093-2

文献信息

• Non-toxic corrosion-protection pigments based on manganese
  申请人：——

  公开号：US20040011252A1

  公开（公告）日：2004-01-22

  Corrosion-inhibiting pigments based on manganese are described that contain a trivalent or tetravalent manganese/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent manganese ion to form a compound that is sparingly soluble, exhibits low solubility, or is insoluble in water, depending upon the intended usage. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent manganese during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Manganese/valence stabilizer combinations are chosen based on the well-founded principles of manganese coordination chemistry. Many manganese-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium or tetravalent lead systems. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.

  以锰为基础的缓蚀颜料含有三价或四价锰/价稳定剂复合物。一种无机或有机材料可用于稳定三价或四价锰离子，从而形成一种可少量溶解、溶解度低或不溶于水的化合物，具体取决于预期用途。选择特定的稳定剂是为了控制三价锰或四价锰在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。锰/价稳定剂组合的选择是基于锰配位化学的基本原理。文中介绍了许多锰价稳定剂组合，其性能与传统的六价铬或四价铅体系相当。需要强调的是，提供本摘要是为了符合要求提供摘要的规则，以便检索者或其他读者快速确定技术公开的主题。提交本摘要的前提是，本摘要不用于解释或限制权利要求的范围或含义。
• Bamberger; Djierdjian, Chemische Berichte, 1900, vol. 33, p. 538
  作者：Bamberger、Djierdjian

  DOI：——

  日期：——
• Nguyn Dinh Trieu, Dng Nhu Tai, Nguyn Thi Ha, Tap chi hoa hoc (J. Chem), 31 (1993) N 4, S 26-29
  作者：Nguyn Dinh Trieu, Dng Nhu Tai, Nguyn Thi Ha

  DOI：——

  日期：——
• NON-TOXIC CORROSION PROTECTION PIGMENTS BASED ON COBALT
  申请人：UNIVERSITY OF DAYTON

  公开号：EP1472319A1

  公开（公告）日：2004-11-03
• Non-toxic corrosion-protection rinses and seals based on rare earth elements
  申请人：——

  公开号：US20040016910A1

  公开（公告）日：2004-01-29

  Rinsing or sealing solutions comprising a rare earth element and a valence stabilizer for barrier films. The treated films contain a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, praseodymium, terbium, or combinations thereof, and at least one rare earth element is in the tetravalent oxidation state. The rinsing or sealing solution may also contain an optional preparative or solubility control agent. The oxidized rare earth element is present in the coating in a “sparingly soluble” form. The valence stabilizers can be either inorganic or organic in nature. A number of rare earth/valence stabilizer combinations that match the performance of conventional hexavalent chromium systems are presented.