2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine | 5606-30-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine
• 英文别名: N,N-dibutyl-1,3,5-triazine-2,4,6-triamine；DABT；N²,N²-dibutyl-[1,3,5]triazine-2,4,6-triyltriamine；N²,N²-Dibutyl-[1,3,5]triazin-2,4,6-triyltriamin；1,3,5-Triazine-2,4,6-triamine, N,N-dibutyl-；2-N,2-N-dibutyl-1,3,5-triazine-2,4,6-triamine
• CAS: 5606-30-4
• 化学式: C₁₁H₂₂N₆
• 分子量: 238.336
• InChiKey: GZHZSPALBMFGRS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  94
• 氢给体数：
  2
• 氢受体数：
  6

安全信息

• 海关编码：
  2933699090

反应信息

• 作为反应物：
  描述：

  2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine 、 2-di-n-butylamino-4,6-dichloro-1,3,5-triazine 在 cesium fluoride 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 12.0h， 以36%的产率得到N2,N2-dibutyl-N4-(4-chloro-6-(dibutylamino)-1,3,5-triazin-2-yl)-1,3,5-triazine-2,4,6-triamine
  参考文献：
  名称：

  Synthesis of polyguanamines from 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine with aromatic diamines

  摘要：

  Solution polycondensation of 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine (BDCT) with various aromatic diamines, including 4,4'-oxydianiline (ODA), p-phenylenediamine (pPDA), m-phenylenediamine (mPDA), o-tolidine (oTh), 4,4'-(9-fluorenylidene)dianiline (BAFL), and 2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine (DABT), was investigated. High molecular weight (>10,000) polyguanamines (PGs) were obtained via the polymerization of BDCT with ODA, pPDA, oTD, and BAFL at 150-180 C in N-methylpyrrolidone (NMP) for 6 h. The polymerizability with BDCT was determined on the basis of the molecular weights of the polymers and the chemical shifts of the NMR data as follows: ODA > oTD > BAFL > pPDA > mPDA >> DABT. PGs were obtained from the reaction of BDCT with ODA and mPDA in only 55-77% yield, which may be attributed to the formation of cyclic oligomers. All of the polymers showed high thermostability (5% weight-loss temperature in N-2 greater than 444 degrees C), and the polymers generated from reaction of BDCT with ODA, mPDA, and BAFL exhibited good solubility in tetrahydrofuran and polar aprotic solvents such as NMP. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2013.03.005
• 作为产物：
  描述：

  2-氯-4,6-二氨基-1,3,5-三嗪 、 二正丁胺 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以54%的产率得到2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine
  参考文献：
  名称：

  Synthesis of polyguanamines from 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine with aromatic diamines

  摘要：

  Solution polycondensation of 2-N,N-dibutylamino-4,6-dichloro-1,3,5-triazine (BDCT) with various aromatic diamines, including 4,4'-oxydianiline (ODA), p-phenylenediamine (pPDA), m-phenylenediamine (mPDA), o-tolidine (oTh), 4,4'-(9-fluorenylidene)dianiline (BAFL), and 2,4-diamino-6-(N,N-dibutylamino)-1,3,5-triazine (DABT), was investigated. High molecular weight (>10,000) polyguanamines (PGs) were obtained via the polymerization of BDCT with ODA, pPDA, oTD, and BAFL at 150-180 C in N-methylpyrrolidone (NMP) for 6 h. The polymerizability with BDCT was determined on the basis of the molecular weights of the polymers and the chemical shifts of the NMR data as follows: ODA > oTD > BAFL > pPDA > mPDA >> DABT. PGs were obtained from the reaction of BDCT with ODA and mPDA in only 55-77% yield, which may be attributed to the formation of cyclic oligomers. All of the polymers showed high thermostability (5% weight-loss temperature in N-2 greater than 444 degrees C), and the polymers generated from reaction of BDCT with ODA, mPDA, and BAFL exhibited good solubility in tetrahydrofuran and polar aprotic solvents such as NMP. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.reactfunctpolym.2013.03.005

文献信息

• [EN] METHOD FOR ALKYLATING AN AMINO COMPOUND<br/>[FR] PROCÉDÉ D'ALKYLATION D'UN COMPOSÉ AMINÉ
  申请人：BOREALIS AGROLINZ MELAMINE

  公开号：WO2018096011A1

  公开（公告）日：2018-05-31

  The invention relates to a method for alkylating an amino compound, characterized in that at least one triazine derivative of general formula (I) or at least one urea or urea derivative of the general formula (II), (II), wherein • R4 and R5 mean independently from each other Q1 or a moiety of the formula R6-N-R7 or R8-N-R9 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q1 means a linear or branched C1-C30-alkyl or a cyclic substituent in form of a C5-C20-cycloalkyl, a C5-C20-aryl, a C1-C20-alkylsubstituted C5-C20-aryl or an amide of a cyclic unsaturated carboxylic acid, whereat the C1-C30-alkyl or the cyclic substituent can be interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-,-OC(O)-,-C(O)- and/or –OC(O)O-, • R1, R2, R3, R6, R7, R8 and R9 mean independently from each other H, linear or branched C1-C20-alkyl, C5-C20-cyclo alkyl, C5-C20-aryl, C1-C20-alkylsubstituted C5-C20-aryl, which in each case can be interrupted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, - OC(O)-, -C(O)- and/or –OC(O) O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, and • X means O or S, is reacted with at least one alcohol of the general formula (III) R10-OH wherein R10 means a linear or branched C1-C20-alkyl, C5-C20-cycloalkyl, or C1-C20- alkylsubstituted C5-C20-aryl, which can be in each case interrupted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type –C(O)O-, -OC(O)-, -C(O)- and/or –OC(O)O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups, wherein the reaction is carried out in the presence of at least one Ruthenate of the general formula (IV) Mn(RuO4) and/or at least one Perruthenate of the general formula (V) M(RuO4)n wherein the cation M is selected from a group comprising an alkali, earth alkali or substituted or non-substituted ammonium cation.

  本发明涉及一种烷基化氨基化合物的方法，其特征在于至少使用一种通式(I)的三嗪衍生物或至少使用一种通式(II)的脲或脲衍生物，其中•R4和R5分别独立地表示Q1或式R6-N-R7或R8-N-R9的基团，其中心氮原子与通式(I)的三嗪环结构相连，其中-Q1表示线性或支链的C1-C30烷基或形式为C5-C20环烷基，C5-C20芳基，C1-C20烷基取代的C5-C20芳基或环状不饱和羧酸酰胺的取代基，其中C1-C30烷基或环状取代基可以被一个或多个氧原子，硫原子，取代的氮原子和/或一个或多个-C(O)O-，-OC(O)-，-C(O)-和/或-OC(O)O-类型的基团所中断，•R1，R2，R3，R6，R7，R8和R9分别独立地表示H，线性或支链的C1-C20烷基，C5-C20环烷基，C5-C20芳基，C1-C20烷基取代的C5-C20芳基，其中每种情况都可以被一个或多个氧原子，硫原子和/或取代的氮原子和/或一个或多个-C(O)O-，-OC(O)-，-C(O)-和/或-OC(O)O-类型的基团所中断，并且可以通过一个或多个羟基和/或巯基进行官能化，•X表示O或S，与至少一种通式(III)的醇反应，通式(III)为R10-OH，其中R10表示线性或支链的C1-C20烷基，C5-C20环烷基或C1-C20烷基取代的C5-C20芳基，每种情况都可以被一个或多个氧原子，硫原子，取代的氮原子和/或一个或多个-C(O)O-，-OC(O)-，-C(O)-和/或-OC(O)O-类型的基团所中断，并且可以通过一个或多个羟基和/或巯基进行官能化，其中在至少一种Mn（RuO4）的通式（IV）钌酸盐和/或至少一种M（RuO4）n的通式（V）高钒酸盐的存在下进行反应，其中阳离子M选择自碱金属，碱土金属或取代或未取代的铵阳离子组成的群。
• 用基于氨基-三嗪的曼尼希化合物来稳定有机材 料
  申请人：博里利斯股份有限公司

  公开号：CN103857737B

  公开（公告）日：2016-05-25

  包括特定的新的基于氨基-三嗪的曼尼希化合物的一种或更多种基于氨基-三嗪的曼尼希化合物和／或其二聚体或三聚体和／或一种或更多种来自其的预缩合物作为用于有机材料、优选用于聚合物的抗氧化剂和/或UV稳定剂的用途；经稳定的材料以及所述经稳定的材料的用途。
• Expoxy/acid anhydride composition
  申请人：Nissan Chemical Industries, Ltd.

  公开号：US06124381A1

  公开（公告）日：2000-09-26

  An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [I] ##STR1## (wherein X is an amino group, C.sub.1-18 monoalkylamino group, di C.sub.1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R.sup.1 and R.sup.2 independently each represent C.sub.1-12 alkyl group, C.sub.1-12 hydroxyalkyl group, C.sub.4-8 cycloalkyl group, C.sub.5-9 cycloalkylmethyl group or C.sub.5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  一种环氧树脂/酸酐组合物，其特征在于其含有一种取代三嗪的固化促进剂，该取代三嗪的化学式为[I] ##STR1## （其中X为氨基，C.sub.1-18单烷基氨基，二C.sub.1-18烷基氨基，吗啉基，哌啶基，甲基或苯基；R.sup.1和R.sup.2各自独立地表示C.sub.1-12烷基，C.sub.1-12羟基烷基，C.sub.4-8环烷基，C.sub.5-9环烷基甲基或C.sub.5-9甲基环烷基）在环氧树脂/酸酐组合物中，该组合物中含有环氧化合物和酸酐固化剂，并通过热固化制备的环氧树脂/酸酐组合物。
• PROCESS FOR ALKYLATING TRIAZINE DERIVATIVE
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0760369A1

  公开（公告）日：1997-03-05

  The object of the present invention is to provide a method for producing substituted-1,3,5-triazine derivatives at high yield, in which at least one of carbon atoms in the ring thereof is substituted by a secondary amine group having at leat one of alkyl groups. The method of the present invention is a method for alkylation of 1,3,5-triazine derivatives, characterized by reacting 1,3,5-triazine derivatives (melamines, melamine derivatives, various kinds of guanaminde derivatives, etc.) which has at least one or more amino groups or mono-substituted amino groups on carbon atom of the ring thereof, with aldehydes or ketones alcohols in the presence of a catalyst of a metal of group VII and/or group VIII in the periodic table and a hydrogen-containing gas to alkylate said at least one of amino groups or mono-substituted amino groups. These derivatives are widely used as intermediates of fine chemicals such as agricultural chemicals, medications, dyestuffs, paints and the like and are widely used resin materials and as flame-retardant materials.

  本发明的目的是提供一种高产率生产取代的-1,3,5-三嗪衍生物的方法，在这种衍生物中，其环上至少有一个碳原子被至少有一个烷基的仲胺基取代。 本发明的方法是 1,3,5-三嗪衍生物的烷基化方法，其特征是将 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）与至少具有一个或多个烷基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种胍衍生物等）反应。其特征是：在元素周期表中第 VII 族和/或 VIII 族金属和含氢气体催化剂的存在下，将环的碳原子上至少有一个或多个氨基或单取代氨基的 1,3,5-三嗪衍生物（三聚氰胺、三聚氰胺衍生物、各种鸟苷酸衍生物等）与醛或酮醇反应，使上述至少一个氨基或单取代氨基烷基化。 这些衍生物被广泛用作精细化工产品的中间体，如农药、药物、染料、油漆等，也被广泛用作树脂材料和阻燃材料。
• EPOXY/ACID ANHYDRIDE COMPOSITION
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0834523A1

  公开（公告）日：1998-04-08

  (Object) It is to provide an epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure is employed as a curing accelerator to thereby impart a long pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin. (Constitution of the invention) An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [] (wherein X is an amino group, C1-18 monoalkylamino group, di C1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R1 and R2 independently each represent C1-12 alkyl group, C1-12 hydroxyalkyl group, C4-8 cycloalkyl group, C5-9 cycloalkylmethyl group or C5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  目的 提供一种环氧/酸酐组合物，该组合物由环氧化合物和用作固化剂的酸酐组成，其中使用了特定结构的取代三嗪作为固化促进剂，从而使该组合物具有较长的固化寿命、较高的储存稳定性和良好的工作特性，并且不会导致固化树脂出现气泡或开裂等缺陷。 (本发明的结构） 一种环氧树脂/酸酐组合物，其特征在于含有式[]的取代三嗪作为固化促进剂。 (其中 X 是氨基、C1-18 单烷基氨基、二 C1-18 烷基氨基、吗啉基、哌啶基、甲基或苯基；R1 和 R2 各自独立地代表环氧化合物和酸酐固化剂的环氧/酸酐组合物中的 C1-12 烷基、C1-12 羟基烷基、C4-8 环烷基、C5-9 环烷基甲基或 C5-9 甲基环烷基），以及通过热固化该环氧/酸酐组合物制备的环氧/酸酐树脂组合物。