Methyl-phenyl-phosphoramidous acid diphenyl ester | 31860-16-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Methyl-phenyl-phosphoramidous acid diphenyl ester
• 英文别名: N-diphenoxyphosphanyl-N-methylaniline
• CAS: 31860-16-9
• 化学式: C₁₉H₁₈NO₂P
• 分子量: 323.331
• InChiKey: IAJMLWAIVJRHHY-UHFFFAOYSA-N

物化性质

• 沸点：
  413.2±28.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  23
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  21.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  Methyl-phenyl-phosphoramidous acid diphenyl ester 在 sulfur 作用下， 以 二氯甲烷 为溶剂， 反应 40.0h， 生成 Methyl-phenyl-thiophosphoramidic acid O,O'-diphenyl ester
  参考文献：
  名称：

  Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use

  摘要：

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.

  DOI：

  10.1134/s1070363206020046
• 作为产物：
  描述：

  N-methyl-N-[(N-methylanilino)-phenoxyphosphanyl]aniline 生成 N,N',N''-trimethyl-N,N',N''-triphenylphosphorous triamide 、 Methyl-phenyl-phosphoramidous acid diphenyl ester
  参考文献：
  名称：

  Dismutation of Diamidoarylphosphites

  摘要：

  Some examples of spontaneous dismutation of diamidoarylphosphites in different solvents were studied, and features of the process were revealed.

  DOI：

  10.1080/714040960